Examples

Notebooks

In the folder notebooks several notebooks, using Pluto.jl, for the simulation of GC-systems are available.

To use these notebooks Julia, v1.6 or above, must be installed and Pluto must be added:

julia> ]
(v1.7) pkg> add Pluto

To run Pluto, use the following commands:

julia> using Pluto
julia> Pluto.run()

Pluto will open your browser. In the field Open from file the URL of a notebook or the path to a locally downloaded notebook can be insert and the notebook will open and load the necessary packages.

Overview of notebooks

• simulation_conventional_GC.jl - simulation of a conventional GC-system (constant temperature, constant diameter and constant film thickness along the column) and outlet pressure as "vacuum" or "atmospheric", now with option of flow or pressure control and temperature program notation in the typical form used in commercial GC software (temperature levels, holding times and heating ramps)
• simulation_conventional_GC_load_2dbs.jl - simulation of a conventional GC-system (constant temperature, constant diameter and constant film thickness along the column) and loading of up to two different substance databases and simulation of the common substances with the same GC-system and comparing the result. Also, an option is given, to load measured retention times and compare these to the simulations. Same setting for programs as in simulation_conventional_GC.jl
• simulation_example.jl - general example of simulation of a GC-system with optional thermal gradient (exponential/linear model of temperature change along the column) and constant diameter and constant film thickness along the column.
• simulation_example_input_gradient_function.jl - simulation of a GC-system with optional thermal gradient where the temperature change along the column is defined by a user-defined equation (cosine-function as example)

Simulation of measurements

Two measurements from [8] will be simulated and compared to the measured chromatograms. The n-alkanes from n-nonane (C9) to n-triacontane (C30) are separated in a conventional GC and a thermal gradient GC . The database with the thermodynamic parameters is Database_Leppert2020b.csv.

Conventional GC

The conventional GC program simulated here is Prog. D from [8], a temperature program with two heating ramps, constant inlet pressure and a flame ionization detector (FID, atmospheric outlet pressure).

The standard options are used, beside the option ng (non-gradient) is changed to true. Because the conventional GC does not use non-uniform temperature, diameter or film thickness, the model can be simplified and the calculation of the separation is faster.

opt = GasChromatographySimulator.Options(ng=true)

GasChromatographySimulator.Options(OwrenZen5(), 1.0e-6, 0.001, "inlet", true, true, "Blumberg", "Pressure")

The column has a length of 11.18 m, a diameter of 0.104 mm and a film thickness of 0.104 µm. The stationary phase is labeled as FS5ms and the mobile phase gas is helium:

col = GasChromatographySimulator.Column(11.18, 0.104e-3, 0.104e-6, "FS5ms", "H2");

GasChromatographySimulator.Column(11.18, 0.000104, [0.000104], 1.04e-7, [1.04e-7], "FS5ms", "H2")

The temperature program starts at 40°C, which is hold for 1 min. The column is heated up to 180°C in 28 min (5°C/min heating ramp), where the temperature is also hold for 1min. Than the column is heated to 300°C in 6 min (20°C/min heating ramp), where the temperature again is kept for 1 min. The inlet pressure is at constant 411564 Pa (absolute) and the outlet pressure is at constant 101300 Pa (absolute) during the program.

prog_D = GasChromatographySimulator.Program([0.0, 60.0, 1680.0, 60.0, 360.0, 60.0], [40.0, 40.0, 180.0, 180.0, 300.0, 300.0], 411564.0*ones(6), 101300.0.*ones(6), col.L);

GasChromatographySimulator.Program{GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}}([0.0, 60.0, 1680.0, 60.0, 360.0, 60.0], [40.0, 40.0, 180.0, 180.0, 300.0, 300.0], [411564.0, 411564.0, 411564.0, 411564.0, 411564.0, 411564.0], [101300.0, 101300.0, 101300.0, 101300.0, 101300.0, 101300.0], GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}([0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0]), [0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0], 11181×6 extrapolate(interpolate((0.0:0.001:11.18,::Vector{Float64}), ::Matrix{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
   ⋮                                       ⋮
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0)

We want to use all solutes for the stationary phase FS5ms, which are in the database Database_Leppert2020b.csv. We load the database into a dataframe:

db_dataframe = DataFrame(CSV.File("../../data/Leppert2020b/Database_Leppert2020b.csv", header=1, silencewarnings=true));

and extract all the names of the substances with:

solutes = GasChromatographySimulator.all_solutes(col.sp, db_dataframe);

22-element Vector{String}:
 "C9"
 "C10"
 "C11"
 "C12"
 "C13"
 "C14"
 "C15"
 "C16"
 "C17"
 "C18"
 ⋮
 "C22"
 "C23"
 "C24"
 "C25"
 "C26"
 "C27"
 "C28"
 "C29"
 "C30"

The injection is assumed to be ideal with initial peak widths τ₀ of 0 seconds and occuring at the beginning of the temperature program (t₀ of 0 seconds). The data for all solutes is finally loaded with:

t₀ = zeros(length(solutes))
τ₀ = zeros(length(solutes))
sub = GasChromatographySimulator.load_solute_database(db_dataframe, col.sp, col.gas, solutes, t₀, τ₀)

22-element Vector{GasChromatographySimulator.Substance}:
 GasChromatographySimulator.Substance("C9", "111-84-2", 371.19, 30.17, 89.34, 0.001, "Leppert2020b, alkane, alkanes", 0.0001253206335721764, 0.0, 0.0)
 GasChromatographySimulator.Substance("C10", "124-18-5", 391.24, 32.24, 112.49, 0.001, "Leppert2020b, alkane, Grob, alkanes", 0.00011884991852543487, 0.0, 0.0)
 GasChromatographySimulator.Substance("C11", "1120-21-4", 410.21999999999997, 33.71, 116.04, 0.001, "Leppert2020b, alkane, Grob, alkanes", 0.00011323854999018596, 0.0, 0.0)
 GasChromatographySimulator.Substance("C12", "112-40-3", 427.92999999999995, 34.92, 121.44, 0.001, "Leppert2020b, alkane, alkanes", 0.00010831148421185742, 0.0, 0.0)
 GasChromatographySimulator.Substance("C13", "629-50-5", 444.46999999999997, 35.93, 125.62, 0.001, "Leppert2020b, alkane, alkanes", 0.00010393999972322901, 0.0, 0.0)
 GasChromatographySimulator.Substance("C14", "629-59-4", 459.98, 36.76, 126.76, 0.001, "Leppert2020b, alkane, alkanes", 0.00010002700149772162, 0.0, 0.0)
 GasChromatographySimulator.Substance("C15", "629-62-9", 474.4, 37.39, 129.62, 0.001, "Leppert2020b, alkane, alkanes", 9.64976601701651e-5, 0.0, 0.0)
 GasChromatographySimulator.Substance("C16", "544-76-3", 488.25, 38.46, 142.18, 0.001, "Leppert2020b, alkane, alkanes", 9.329323536538124e-5, 0.0, 0.0)
 GasChromatographySimulator.Substance("C17", "629-78-7", 501.05999999999995, 38.95, 145.36, 0.001, "Leppert2020b, alkane, alkanes", 9.036687565381776e-5, 0.0, 0.0)
 GasChromatographySimulator.Substance("C18", "593-45-3", 513.25, 39.58, 153.29, 0.001, "Leppert2020b, alkane, alkanes", 8.768068754143736e-5, 0.0, 0.0)
 ⋮
 GasChromatographySimulator.Substance("C22", "629-97-0", 556.7, 41.89, 183.35, 0.001, "Leppert2020b, alkane, alkanes", 7.879073502414208e-5, 0.0, 0.0)
 GasChromatographySimulator.Substance("C23", "638-67-5", 566.26, 42.25, 188.99, 0.001, "Leppert2020b, alkane, alkanes", 7.693149436827684e-5, 0.0, 0.0)
 GasChromatographySimulator.Substance("C24", "646-31-1", 575.2, 42.21, 188.53, 0.001, "Leppert2020b, alkane, alkanes", 7.518755251713027e-5, 0.0, 0.0)
 GasChromatographySimulator.Substance("C25", "629-99-2", 583.8199999999999, 42.26, 189.51, 0.001, "Leppert2020b, alkane, alkanes", 7.354754525382887e-5, 0.0, 0.0)
 GasChromatographySimulator.Substance("C26", "630-1-3", 593.5699999999999, 44.16, 216.77, 0.001, "Leppert2020b, alkane", 7.200161658208628e-5, 0.0, 0.0)
 GasChromatographySimulator.Substance("C27", "593-49-7", 599.77, 41.9, 184.17, 0.001, "Leppert2020b, alkane, alkanes", 7.054117055654164e-5, 0.0, 0.0)
 GasChromatographySimulator.Substance("C28", "630-2-4", 607.3399999999999, 41.82, 183.91, 0.001, "Leppert2020b, alkane", 6.915867131183108e-5, 0.0, 0.0)
 GasChromatographySimulator.Substance("C29", "630-3-5", 614.55, 41.67, 183.07, 0.001, "Leppert2020b, alkane", 6.784748059430345e-5, 0.0, 0.0)
 GasChromatographySimulator.Substance("C30", "638-68-6", 621.54, 41.57, 183.28, 0.001, "Leppert2020b, alkane, alkanes", 6.660172475097402e-5, 0.0, 0.0)

The parameters are combined:

par = GasChromatographySimulator.Parameters(col, prog_D, sub, opt);

GasChromatographySimulator.Parameters(GasChromatographySimulator.Column(11.18, 0.000104, [0.000104], 1.04e-7, [1.04e-7], "FS5ms", "H2"), GasChromatographySimulator.Program{GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}}([0.0, 60.0, 1680.0, 60.0, 360.0, 60.0], [40.0, 40.0, 180.0, 180.0, 300.0, 300.0], [411564.0, 411564.0, 411564.0, 411564.0, 411564.0, 411564.0], [101300.0, 101300.0, 101300.0, 101300.0, 101300.0, 101300.0], GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}([0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0]), [0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0], 11181×6 extrapolate(interpolate((0.0:0.001:11.18,::Vector{Float64}), ::Matrix{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
   ⋮                                       ⋮
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0), GasChromatographySimulator.Substance[GasChromatographySimulator.Substance("C9", "111-84-2", 371.19, 30.17, 89.34, 0.001, "Leppert2020b, alkane, alkanes", 0.0001253206335721764, 0.0, 0.0), GasChromatographySimulator.Substance("C10", "124-18-5", 391.24, 32.24, 112.49, 0.001, "Leppert2020b, alkane, Grob, alkanes", 0.00011884991852543487, 0.0, 0.0), GasChromatographySimulator.Substance("C11", "1120-21-4", 410.21999999999997, 33.71, 116.04, 0.001, "Leppert2020b, alkane, Grob, alkanes", 0.00011323854999018596, 0.0, 0.0), GasChromatographySimulator.Substance("C12", "112-40-3", 427.92999999999995, 34.92, 121.44, 0.001, "Leppert2020b, alkane, alkanes", 0.00010831148421185742, 0.0, 0.0), GasChromatographySimulator.Substance("C13", "629-50-5", 444.46999999999997, 35.93, 125.62, 0.001, "Leppert2020b, alkane, alkanes", 0.00010393999972322901, 0.0, 0.0), GasChromatographySimulator.Substance("C14", "629-59-4", 459.98, 36.76, 126.76, 0.001, "Leppert2020b, alkane, alkanes", 0.00010002700149772162, 0.0, 0.0), GasChromatographySimulator.Substance("C15", "629-62-9", 474.4, 37.39, 129.62, 0.001, "Leppert2020b, alkane, alkanes", 9.64976601701651e-5, 0.0, 0.0), GasChromatographySimulator.Substance("C16", "544-76-3", 488.25, 38.46, 142.18, 0.001, "Leppert2020b, alkane, alkanes", 9.329323536538124e-5, 0.0, 0.0), GasChromatographySimulator.Substance("C17", "629-78-7", 501.05999999999995, 38.95, 145.36, 0.001, "Leppert2020b, alkane, alkanes", 9.036687565381776e-5, 0.0, 0.0), GasChromatographySimulator.Substance("C18", "593-45-3", 513.25, 39.58, 153.29, 0.001, "Leppert2020b, alkane, alkanes", 8.768068754143736e-5, 0.0, 0.0)  …  GasChromatographySimulator.Substance("C21", "629-94-7", 546.54, 41.43, 179.47, 0.001, "Leppert2020b, alkane, alkanes", 8.077845767414391e-5, 0.0, 0.0), GasChromatographySimulator.Substance("C22", "629-97-0", 556.7, 41.89, 183.35, 0.001, "Leppert2020b, alkane, alkanes", 7.879073502414208e-5, 0.0, 0.0), GasChromatographySimulator.Substance("C23", "638-67-5", 566.26, 42.25, 188.99, 0.001, "Leppert2020b, alkane, alkanes", 7.693149436827684e-5, 0.0, 0.0), GasChromatographySimulator.Substance("C24", "646-31-1", 575.2, 42.21, 188.53, 0.001, "Leppert2020b, alkane, alkanes", 7.518755251713027e-5, 0.0, 0.0), GasChromatographySimulator.Substance("C25", "629-99-2", 583.8199999999999, 42.26, 189.51, 0.001, "Leppert2020b, alkane, alkanes", 7.354754525382887e-5, 0.0, 0.0), GasChromatographySimulator.Substance("C26", "630-1-3", 593.5699999999999, 44.16, 216.77, 0.001, "Leppert2020b, alkane", 7.200161658208628e-5, 0.0, 0.0), GasChromatographySimulator.Substance("C27", "593-49-7", 599.77, 41.9, 184.17, 0.001, "Leppert2020b, alkane, alkanes", 7.054117055654164e-5, 0.0, 0.0), GasChromatographySimulator.Substance("C28", "630-2-4", 607.3399999999999, 41.82, 183.91, 0.001, "Leppert2020b, alkane", 6.915867131183108e-5, 0.0, 0.0), GasChromatographySimulator.Substance("C29", "630-3-5", 614.55, 41.67, 183.07, 0.001, "Leppert2020b, alkane", 6.784748059430345e-5, 0.0, 0.0), GasChromatographySimulator.Substance("C30", "638-68-6", 621.54, 41.57, 183.28, 0.001, "Leppert2020b, alkane, alkanes", 6.660172475097402e-5, 0.0, 0.0)], GasChromatographySimulator.Options(OwrenZen5(), 1.0e-6, 0.001, "inlet", true, true, "Blumberg", "Pressure"))

The temperature program and the pressure/flow program can be plotted:

p_flow = GasChromatographySimulator.plot_flow(par)
p_press = GasChromatographySimulator.plot_pressure(par)
p_temp = GasChromatographySimulator.plot_temperature(par)
l = @layout([a{0.65w} [b; c]])
p_TpF = plot(p_temp, p_press, p_flow, layout=l)

The temperatures at the column inlet and outlet are identical, the temperature along the colum is uniform. With the temperature program and the constant pressures, the flow decreases during the temperature program.

Finally, the simulation is executed:

peaklist, sol = GasChromatographySimulator.simulate(par);

(22×9 DataFrame
 Row │ Name    tR        τR        TR        σR         uR        kR        Re ⋯
     │ String  Float64   Float64   Float64   Float64    Float64   Float64   Fl ⋯
─────┼──────────────────────────────────────────────────────────────────────────
   1 │ C9       140.736  0.389365   46.728   0.108043   0.277485   8.15494   6 ⋯
   2 │ C10      260.067  0.572035   56.6723  0.111085   0.194193  11.8077    6
   3 │ C11      412.8    0.694334   69.4     0.111529   0.160628  14.0838    5
   4 │ C12      580.176  0.756106   83.348   0.110697   0.146405  15.0983    5
   5 │ C13      747.111  0.786098   97.2593  0.1094     0.139168  15.4922    5 ⋯
   6 │ C14      907.119  0.804631  110.593   0.108069   0.134309  15.6749    4
   7 │ C15     1061.4    0.815528  123.45    0.106795   0.130952  15.7157    4
   8 │ C16     1208.71   0.820451  135.726   0.105629   0.128745  15.6462    4
  ⋮  │   ⋮        ⋮         ⋮         ⋮          ⋮         ⋮         ⋮         ⋱
  16 │ C24     1998.01   0.324749  246.002   0.0994335  0.306186   4.92608   2 ⋯
  17 │ C25     2029.76   0.305047  256.588   0.0978042  0.32062    4.57987   2
  18 │ C26     2058.46   0.295771  266.153   0.0971876  0.328591   4.3767    2
  19 │ C27     2084.51   0.291112  274.838   0.0969698  0.333102   4.24481   2
  20 │ C28     2109.06   0.287879  283.02    0.0965487  0.335379   4.15533   2 ⋯
  21 │ C29     2132.24   0.286462  290.747   0.0963638  0.336393   4.09026   1
  22 │ C30     2154.34   0.285686  298.112   0.0961542  0.336573   4.04139  Na
                                                    2 columns and 7 rows omitted, Any[SciMLBase.ODESolution{Float64, 2, Vector{Vector{Float64}}, Nothing, Nothing, Vector{Float64}, Vector{Vector{Vector{Float64}}}, SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}, OwrenZen5, OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}, DiffEqBase.DEStats}([[0.0, 0.0], [0.0019745074463568824, 4.7234558495803895e-6], [0.021719125645382444, 5.195583140731696e-5], [0.21911967408608163, 0.0005240612931779568], [2.1885546833476504, 0.005223286530211924], [16.194217778868616, 0.038056727381830455], [47.405695587499196, 0.10724279451009826], [57.80404832541345, 0.12894449073346168], [59.962445415260085, 0.13335703622161135], [60.850575532240924, 0.13431971445984373], [61.233544912009016, 0.13469429698101534], [65.00444359915613, 0.13820539800319437], [74.35116617835061, 0.14558136250641276], [86.29393921942575, 0.15246190536650484], [99.75978106850997, 0.15710970960081136], [114.50801468563853, 0.15869777593940151], [129.04601743142106, 0.15665670389241473], [140.48518839859463, 0.15176841109892455], [140.73550490371096, 0.15160473875643016]], nothing, nothing, [0.0, 9.999999999999999e-5, 0.0010999999999999998, 0.011099999999999997, 0.11109999999999996, 0.8349849907189201, 2.541874627159661, 3.1455701087661643, 3.2734840163835144, 3.3264776407435916, 3.349435682787362, 3.579016103225064, 4.177527739163219, 5.012166343675181, 6.070397238317557, 7.427825774489995, 9.11156488984434, 11.11214399520834, 11.18], [[[0.0, 0.0]], [[19.745115941524645, 0.04723475694471891], [19.745102115553884, 0.047234690795080525], [19.745095202564936, 0.047234657720261655], [19.745074463583382, 0.04723455849580407], [19.745074463583382, 0.04723455849580407], [19.74506261272693, 0.04723450179611366], [19.74504335507013, 0.0472344096591173], [19.745032985554843, 0.047234360046888496]], [[19.745032985554843, 0.047234360046888496], [19.74489472483068, 0.04723369855050451], [19.744825594105528, 0.04723336780231249], [19.74461820047784, 0.047232375557736475], [19.74461820047784, 0.047232375557736475], [19.74449968885537, 0.047231808560835885], [19.744307105951773, 0.04723088719087282], [19.744203406687117, 0.04723039106858477]], [[19.744203406687117, 0.04723039106858477], [19.742820697777837, 0.04722377610474431], [19.74212930700712, 0.04722046862282398], [19.740054989400356, 0.04721054617706406], [19.740054989400356, 0.04721054617706405], [19.73886956718242, 0.0472048762080582], [19.73694310422685, 0.04719566250842373], [19.735905700131045, 0.047190701285543375]], [[19.735905700131045, 0.047190701285543375], [19.722068431181143, 0.04712455164714235], [19.715146154772828, 0.04709147682794167], [19.694364727089848, 0.04699225237033972], [19.69436472708984, 0.046992252370339695], [19.682479774168378, 0.046935552680281434], [19.663151404416862, 0.04684341568393676], [19.652735947007837, 0.04679380345513576]], [[19.652735947007837, 0.04679380345513576], [19.55192282607215, 0.04631495615133354], [19.501320832026167, 0.04607553249943281], [19.348720841038094, 0.0453572615437299], [19.348720841038087, 0.04535726154372988], [19.260978032036572, 0.04494682099761392], [19.117537084327246, 0.044279855110175466], [19.03985205210454, 0.043920719632324016]], [[19.03985205210454, 0.043920719632324016], [18.793523064981343, 0.04279161830990894], [18.669139795608256, 0.042227067648701405], [18.29091564820904, 0.040533415665078815], [18.29091564820904, 0.040533415665078815], [18.071233750739342, 0.03956561453158017], [17.7084391481237, 0.037992937689644915], [17.509974995235346, 0.0371461116978336]], [[17.509974995235346, 0.0371461116978336], [17.41559943699634, 0.0367467693197058], [17.36821935196518, 0.036547098130641956], [17.225297169633624, 0.03594808456345027], [17.225297169633624, 0.03594808456345027], [17.143092380531915, 0.03560579109648362], [17.008662242178367, 0.035049564212662775], [16.935834813513306, 0.034750057429066936]], [[16.935834813513306, 0.034750057429066936], [16.91520330704226, 0.034665442841713065], [16.904878111437405, 0.03462313554803613], [16.873864616456473, 0.03449621366700533], [16.873864616456473, 0.03449621366700533], [16.85611699985369, 0.034423686877844854], [16.827237200218605, 0.03430583084545911], [16.811665989972383, 0.034242369904943726]], [[16.811665989972383, 0.034242369904943726], [16.795837557561164, 0.01677888979403646], [16.786714942440543, 0.01675351145953154], [16.75937009070615, 0.016617663137844563], [16.759361737376842, 0.016737641698130034], [16.743766933021742, 0.01655093423317187], [16.718444909615602, 0.01648238517441698], [16.704830639455906, 0.016412404738346074]], [[16.704830639455906, 0.016412404738346074], [16.696970918000066, 0.016380163828876446], [16.693044115116205, 0.016364080446767734], [16.681267179299702, 0.016315879240461552], [16.6812671857911, 0.01631587940798628], [16.67454180118038, 0.016288390857165977], [16.663619720011855, 0.01624380758715534], [16.657742007917307, 0.016219844854995443]], [[16.657742007917307, 0.016219844854995443], [16.57950345325853, 0.01590216494092454], [16.54068556249053, 0.015746944846907803], [16.424562792098246, 0.015285855210730982], [16.42456916019306, 0.015286018782482584], [16.358620748853124, 0.015027584886450136], [16.252096509436438, 0.014615781454333145], [16.195055495640155, 0.014397967499833794]], [[16.195055495640155, 0.014397967499833794], [15.997881372369884, 0.01365545203707235], [15.901177579723402, 0.01330552861195389], [15.612977983489799, 0.012280994622992925], [15.613078670154975, 0.01228342392477292], [15.450756720609004, 0.011724709268619446], [15.190810181047112, 0.010863330641484273], [15.052629710936415, 0.010419714655108419]], [[15.052629710936415, 0.010419714655108419], [14.79793983872663, 0.00962255635191946], [14.673620675052142, 0.00925406539409667], [14.30340398172931, 0.008184305798704009], [14.30361568362779, 0.008188622372108358], [14.095604016281111, 0.0076135737975109655], [13.763393613345674, 0.006744286912219552], [13.587120658396994, 0.006303124449359316]], [[13.587120658396994, 0.006303124449359316], [13.291804088138015, 0.0055897011866883565], [13.147881850877853, 0.005264721731819747], [12.718741871989028, 0.004329201097530062], [12.719051401353832, 0.004334162305369569], [12.477710391872506, 0.003837581573238647], [12.091925355090881, 0.0030995094624011402], [11.886894972391774, 0.002729820502143449]], [[11.886894972391774, 0.002729820502143449], [11.538586157983538, 0.0021322755354804424], [11.368698009302923, 0.0018649997641725195], [10.85986334157048, 0.0011061230960404938], [10.860302980908328, 0.0011111872964083037], [10.572593253379512, 0.0007161237008657152], [10.109943969934195, 0.0001435095261315307], [9.862321908518526, -0.0001371398887918939]], [[9.862321908518526, -0.0001371398887918939], [9.452299893453551, -0.000566719267834576], [9.250571147540853, -0.0007547888371354072], [8.638315677174786, -0.0012730206313508203], [8.638846122180578, -0.0012694455914351102], [8.28625527460347, -0.0015278149416650625], [7.707022001909615, -0.0018822631094775888], [7.38951017662296, -0.0020446783921965047]], [[7.38951017662296, -0.0020446783921965047], [6.872965052996178, -0.002263462294670375], [6.611047261624376, -0.0023503696975950743], [5.780118045924209, -0.002539180765959005], [5.780746867753759, -0.0025384338516442214], [5.26872079641903, -0.002587103467638894], [4.345437527122609, -0.0025442484301804965], [3.772907250190737, -0.002433937532671877]], [[3.772907250190737, -0.002433937532671877], [3.7451994504565995, -0.002426948905293309], [3.731279301251635, -0.002423382440953272], [3.6892286693708596, -0.002412369462323459], [3.6892286805108405, -0.0024123694899648006], [3.665004147653412, -0.0024058648928768278], [3.625326706979611, -0.002394957698358521], [3.6037976813749593, -0.0023889076370050564]]], SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [0.0, 0.0], (0.0, 11.18), Any[GasChromatographySimulator.Column(11.18, 0.000104, [0.000104], 1.04e-7, [1.04e-7], "FS5ms", "H2"), GasChromatographySimulator.Program{GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}}([0.0, 60.0, 1680.0, 60.0, 360.0, 60.0], [40.0, 40.0, 180.0, 180.0, 300.0, 300.0], [411564.0, 411564.0, 411564.0, 411564.0, 411564.0, 411564.0], [101300.0, 101300.0, 101300.0, 101300.0, 101300.0, 101300.0], GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}([0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0]), [0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0], 11181×6 extrapolate(interpolate((0.0:0.001:11.18,::Vector{Float64}), ::Matrix{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
   ⋮                                       ⋮
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0), GasChromatographySimulator.Substance("C9", "111-84-2", 371.19, 30.17, 89.34, 0.001, "Leppert2020b, alkane, alkanes", 0.0001253206335721764, 0.0, 0.0), GasChromatographySimulator.Options(OwrenZen5(), 1.0e-6, 0.001, "inlet", true, true, "Blumberg", "Pressure")], Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}(), SciMLBase.StandardODEProblem()), OwrenZen5(), OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [[0.0, 0.0], [0.0019745074463568824, 4.7234558495803895e-6], [0.021719125645382444, 5.195583140731696e-5], [0.21911967408608163, 0.0005240612931779568], [2.1885546833476504, 0.005223286530211924], [16.194217778868616, 0.038056727381830455], [47.405695587499196, 0.10724279451009826], [57.80404832541345, 0.12894449073346168], [59.962445415260085, 0.13335703622161135], [60.850575532240924, 0.13431971445984373], [61.233544912009016, 0.13469429698101534], [65.00444359915613, 0.13820539800319437], [74.35116617835061, 0.14558136250641276], [86.29393921942575, 0.15246190536650484], [99.75978106850997, 0.15710970960081136], [114.50801468563853, 0.15869777593940151], [129.04601743142106, 0.15665670389241473], [140.48518839859463, 0.15176841109892455], [140.73550490371096, 0.15160473875643016]], [0.0, 9.999999999999999e-5, 0.0010999999999999998, 0.011099999999999997, 0.11109999999999996, 0.8349849907189201, 2.541874627159661, 3.1455701087661643, 3.2734840163835144, 3.3264776407435916, 3.349435682787362, 3.579016103225064, 4.177527739163219, 5.012166343675181, 6.070397238317557, 7.427825774489995, 9.11156488984434, 11.11214399520834, 11.18], [[[0.0, 0.0]], [[19.745115941524645, 0.04723475694471891], [19.745102115553884, 0.047234690795080525], [19.745095202564936, 0.047234657720261655], [19.745074463583382, 0.04723455849580407], [19.745074463583382, 0.04723455849580407], [19.74506261272693, 0.04723450179611366], [19.74504335507013, 0.0472344096591173], [19.745032985554843, 0.047234360046888496]], [[19.745032985554843, 0.047234360046888496], [19.74489472483068, 0.04723369855050451], [19.744825594105528, 0.04723336780231249], [19.74461820047784, 0.047232375557736475], [19.74461820047784, 0.047232375557736475], [19.74449968885537, 0.047231808560835885], [19.744307105951773, 0.04723088719087282], [19.744203406687117, 0.04723039106858477]], [[19.744203406687117, 0.04723039106858477], [19.742820697777837, 0.04722377610474431], [19.74212930700712, 0.04722046862282398], [19.740054989400356, 0.04721054617706406], [19.740054989400356, 0.04721054617706405], [19.73886956718242, 0.0472048762080582], [19.73694310422685, 0.04719566250842373], [19.735905700131045, 0.047190701285543375]], [[19.735905700131045, 0.047190701285543375], [19.722068431181143, 0.04712455164714235], [19.715146154772828, 0.04709147682794167], [19.694364727089848, 0.04699225237033972], [19.69436472708984, 0.046992252370339695], [19.682479774168378, 0.046935552680281434], [19.663151404416862, 0.04684341568393676], [19.652735947007837, 0.04679380345513576]], [[19.652735947007837, 0.04679380345513576], [19.55192282607215, 0.04631495615133354], [19.501320832026167, 0.04607553249943281], [19.348720841038094, 0.0453572615437299], [19.348720841038087, 0.04535726154372988], [19.260978032036572, 0.04494682099761392], [19.117537084327246, 0.044279855110175466], [19.03985205210454, 0.043920719632324016]], [[19.03985205210454, 0.043920719632324016], [18.793523064981343, 0.04279161830990894], [18.669139795608256, 0.042227067648701405], [18.29091564820904, 0.040533415665078815], [18.29091564820904, 0.040533415665078815], [18.071233750739342, 0.03956561453158017], [17.7084391481237, 0.037992937689644915], [17.509974995235346, 0.0371461116978336]], [[17.509974995235346, 0.0371461116978336], [17.41559943699634, 0.0367467693197058], [17.36821935196518, 0.036547098130641956], [17.225297169633624, 0.03594808456345027], [17.225297169633624, 0.03594808456345027], [17.143092380531915, 0.03560579109648362], [17.008662242178367, 0.035049564212662775], [16.935834813513306, 0.034750057429066936]], [[16.935834813513306, 0.034750057429066936], [16.91520330704226, 0.034665442841713065], [16.904878111437405, 0.03462313554803613], [16.873864616456473, 0.03449621366700533], [16.873864616456473, 0.03449621366700533], [16.85611699985369, 0.034423686877844854], [16.827237200218605, 0.03430583084545911], [16.811665989972383, 0.034242369904943726]], [[16.811665989972383, 0.034242369904943726], [16.795837557561164, 0.01677888979403646], [16.786714942440543, 0.01675351145953154], [16.75937009070615, 0.016617663137844563], [16.759361737376842, 0.016737641698130034], [16.743766933021742, 0.01655093423317187], [16.718444909615602, 0.01648238517441698], [16.704830639455906, 0.016412404738346074]], [[16.704830639455906, 0.016412404738346074], [16.696970918000066, 0.016380163828876446], [16.693044115116205, 0.016364080446767734], [16.681267179299702, 0.016315879240461552], [16.6812671857911, 0.01631587940798628], [16.67454180118038, 0.016288390857165977], [16.663619720011855, 0.01624380758715534], [16.657742007917307, 0.016219844854995443]], [[16.657742007917307, 0.016219844854995443], [16.57950345325853, 0.01590216494092454], [16.54068556249053, 0.015746944846907803], [16.424562792098246, 0.015285855210730982], [16.42456916019306, 0.015286018782482584], [16.358620748853124, 0.015027584886450136], [16.252096509436438, 0.014615781454333145], [16.195055495640155, 0.014397967499833794]], [[16.195055495640155, 0.014397967499833794], [15.997881372369884, 0.01365545203707235], [15.901177579723402, 0.01330552861195389], [15.612977983489799, 0.012280994622992925], [15.613078670154975, 0.01228342392477292], [15.450756720609004, 0.011724709268619446], [15.190810181047112, 0.010863330641484273], [15.052629710936415, 0.010419714655108419]], [[15.052629710936415, 0.010419714655108419], [14.79793983872663, 0.00962255635191946], [14.673620675052142, 0.00925406539409667], [14.30340398172931, 0.008184305798704009], [14.30361568362779, 0.008188622372108358], [14.095604016281111, 0.0076135737975109655], [13.763393613345674, 0.006744286912219552], [13.587120658396994, 0.006303124449359316]], [[13.587120658396994, 0.006303124449359316], [13.291804088138015, 0.0055897011866883565], [13.147881850877853, 0.005264721731819747], [12.718741871989028, 0.004329201097530062], [12.719051401353832, 0.004334162305369569], [12.477710391872506, 0.003837581573238647], [12.091925355090881, 0.0030995094624011402], [11.886894972391774, 0.002729820502143449]], [[11.886894972391774, 0.002729820502143449], [11.538586157983538, 0.0021322755354804424], [11.368698009302923, 0.0018649997641725195], [10.85986334157048, 0.0011061230960404938], [10.860302980908328, 0.0011111872964083037], [10.572593253379512, 0.0007161237008657152], [10.109943969934195, 0.0001435095261315307], [9.862321908518526, -0.0001371398887918939]], [[9.862321908518526, -0.0001371398887918939], [9.452299893453551, -0.000566719267834576], [9.250571147540853, -0.0007547888371354072], [8.638315677174786, -0.0012730206313508203], [8.638846122180578, -0.0012694455914351102], [8.28625527460347, -0.0015278149416650625], [7.707022001909615, -0.0018822631094775888], [7.38951017662296, -0.0020446783921965047]], [[7.38951017662296, -0.0020446783921965047], [6.872965052996178, -0.002263462294670375], [6.611047261624376, -0.0023503696975950743], [5.780118045924209, -0.002539180765959005], [5.780746867753759, -0.0025384338516442214], [5.26872079641903, -0.002587103467638894], [4.345437527122609, -0.0025442484301804965], [3.772907250190737, -0.002433937532671877]], [[3.772907250190737, -0.002433937532671877], [3.7451994504565995, -0.002426948905293309], [3.731279301251635, -0.002423382440953272], [3.6892286693708596, -0.002412369462323459], [3.6892286805108405, -0.0024123694899648006], [3.665004147653412, -0.0024058648928768278], [3.625326706979611, -0.002394957698358521], [3.6037976813749593, -0.0023889076370050564]]], true, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}([140.73550490371096, 0.15160473875643016], [140.48518839859463, 0.15176841109892455], [3.772907250190737, -0.002433937532671877], [3.7451994504565995, -0.002426948905293309], [3.731279301251635, -0.002423382440953272], [3.6892286693708596, -0.002412369462323459], [3.6892286805108405, -0.0024123694899648006], [3.665004147653412, -0.0024058648928768278], [3.625326706979611, -0.002394957698358521], [3.6037976813749593, -0.0023889076370050564], [8.703481395865448e-9, -9.087029634304437e-12], [140.70484605361966, 0.15162502726823027], [6.184238696150792e-8, -5.9482386240308336e-8], OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}(0.16666666666666666, 0.0625, 0.1875, 0.25, -0.75, -0.75, 3.75, -3.0, 0.5, 0.26895043731778423, -0.7084548104956269, 0.8658892128279884, 0.15462307371928363, 0.06184922948771345, -0.02947695035460993, 0.18500664893617022, 0.4802345261121857, -0.5337849069148937, -0.013090093085106383, 0.7861107753062541, 0.08783068783068783, 0.3006060606060606, 0.22777777777777777, 0.027777777777777776, 0.06218596218596219, 0.2938217338217338, 0.16666666666666666, 0.25, 0.5, 0.5, 0.6428571428571429, 0.875, -0.19894179894179895, 0.9115151515151515, -1.9777777777777779, -0.1111111111111111, 1.67013727013727, -0.2938217338217338, 1.892063492063492, -6.067155067155067, 7.282458282458283, -4.0195360195360195, -7.214545454545455, 20.676923076923078, -20.31142191142191, 7.14965034965035, 7.866666666666666, -18.78205128205128, 13.508547008547009, -2.3653846153846154, 2.0, -5.294871794871795, 4.534188034188034, -1.2115384615384615, -1.4924630924630924, 1.5785667324128863, 1.1958838881915805, -1.219801565955412, -7.051721611721612, 16.273203719357564, -11.978886071193763, 3.0512256973795435, 4.0, -8.384615384615385, 5.769230769230769, -1.3846153846153846))), true, 0, DiffEqBase.DEStats
Number of function 1 evaluations:                  255
Number of function 2 evaluations:                  0
Number of W matrix evaluations:                    0
Number of linear solves:                           0
Number of Jacobians created:                       0
Number of nonlinear solver iterations:             0
Number of nonlinear solver convergence failures:   0
Number of rootfind condition calls:                0
Number of accepted steps:                          18
Number of rejected steps:                          18, :Success), SciMLBase.ODESolution{Float64, 2, Vector{Vector{Float64}}, Nothing, Nothing, Vector{Float64}, Vector{Vector{Vector{Float64}}}, SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}, OwrenZen5, OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}, DiffEqBase.DEStats}([[0.0, 0.0], [0.004822669065209952, 3.087876177685592e-5], [0.05304824530626859, 0.0003396521089717704], [0.535192549282912, 0.0034259585235565933], [5.34547235482715, 0.03414631693297235], [39.54141241372222, 0.24871242625193676], [54.9414428371616, 0.34307712507497223], [59.04268779050093, 0.36796228591367053], [60.122582256358626, 0.37449735814202056], [70.59431013333138, 0.39875029162611697], [83.31354096508814, 0.4207739970108184], [98.52258152048765, 0.4381113231268197], [115.85341588715168, 0.4481514397231827], [135.19961279446267, 0.4497337533766557], [156.21510313605512, 0.4426454302336088], [178.64110302788632, 0.42749772913305606], [201.97173126255097, 0.4055020026523152], [225.43338165050096, 0.3782578421365638], [247.30930403827728, 0.34819911642017964], [260.06723655405875, 0.32722433280414565]], nothing, nothing, [0.0, 9.999999999999999e-5, 0.0010999999999999998, 0.011099999999999997, 0.11109999999999996, 0.8347177402027082, 1.16839532552501, 1.2581333610542251, 1.2818251163532415, 1.5187426693434056, 1.8260865780252582, 2.224307194767151, 2.72345009777049, 3.345767731265788, 4.113424130277604, 5.0618766750576425, 6.234035871945446, 7.691391969078953, 9.511938287303153, 11.18], [[[0.0, 0.0]], [[48.226791960633314, 0.3087889150934343], [48.22675819115749, 0.3087884826518089], [48.226741306410695, 0.30878826643099594], [48.22669065213519, 0.3087876177685619], [48.22669065213519, 0.3087876177685619], [48.22666170681052, 0.3087872471043072], [48.226614670621515, 0.30878664477490203], [48.226589343423605, 0.30878632044368093]], [[48.226589343423605, 0.30878632044368093], [48.226251646182405, 0.30878199602742545], [48.22608279667502, 0.30877983381929763], [48.22557624460584, 0.30877334719491456], [48.22557624460584, 0.30877334719491456], [48.225286783891804, 0.30876964055241135], [48.22481640652551, 0.3087636172583394], [48.224563124504925, 0.30876037394614775]], [[48.224563124504925, 0.30876037394614775], [48.221185903773126, 0.3087171297835905], [48.219497204706656, 0.30869550770231496], [48.214430752629085, 0.30863064145848207], [48.214430752629085, 0.30863064145848207], [48.21153539810891, 0.3085935750334325], [48.20683007612205, 0.3085333420927344], [48.204296250964525, 0.30850090897081395]], [[48.204296250964525, 0.30850090897081395], [48.170499179682395, 0.3080684673452634], [48.15359174873966, 0.307852246532487], [48.102833799660836, 0.30720358409415577], [48.102833799660985, 0.3072035840941577], [48.07380519564049, 0.30683291984368405], [48.02659629245133, 0.3062305904366658], [48.00115688256739, 0.3059062592174995]], [[48.00115688256739, 0.3059062592174995], [47.75501531316324, 0.3027770348989785], [47.631467543088156, 0.30121242273971804], [47.258886344810044, 0.29651858626193667], [47.258886344810044, 0.29651858626193667], [47.04465799768703, 0.29383639398891875], [46.69444073888018, 0.2894778315452645], [46.504769809542125, 0.28713091330637386]], [[46.504769809542125, 0.28713091330637386], [46.38776903460871, 0.28568795253230084], [46.32915784355521, 0.28496647214526427], [46.15287767786108, 0.2828020309841547], [46.15287767786108, 0.2828020309841547], [46.05184319477261, 0.28156520746352076], [45.8871877012466, 0.27955536924249036], [45.79828185485472, 0.27847314866193557]], [[45.79828185485472, 0.27847314866193557], [45.766359766519024, 0.278085084042354], [45.75039036980252, 0.277891051732563], [45.70244869940695, 0.27730895480319057], [45.70244869940695, 0.27730895480319057], [45.67503086617753, 0.27697632798640637], [45.63044175022669, 0.27643580940913187], [45.606414169359255, 0.27614476094444557]], [[45.606414169359255, 0.27614476094444557], [45.59795312171832, 0.27604230793270856], [45.59372200908877, 0.27599108142684], [45.58102631465199, 0.27583740190923445], [45.58102631465199, 0.27583740190923445], [45.57377004421155, 0.2757495850420313], [45.56197613997221, 0.2756068826328261], [45.530015088164426, 0.11877593474059447]], [[45.530015088164426, 0.11877593474059447], [45.072369400809784, 0.11285665090456856], [44.849556791784835, 0.11009654310883629], [44.187810373214035, 0.10199966710272054], [44.18822492078715, 0.10203246312237316], [43.81785311430543, 0.09762430515906531], [43.228910833575526, 0.09087976577749818], [42.917783421935155, 0.08741763834854305]], [[42.917783421935155, 0.08741763834854305], [42.38673907438439, 0.0816270597512248], [42.12965019724548, 0.07897170720804364], [41.367630759825936, 0.07122209853164257], [41.36833374478905, 0.07126981209587518], [40.94354650265526, 0.06709152015336184], [40.27126103016033, 0.0608061780101615], [39.91743237924775, 0.05761495172159847]], [[39.91743237924775, 0.05761495172159847], [39.315827129247616, 0.052329154487093826], [39.02638132377312, 0.04995285644223815], [38.1702839269217, 0.043061025239525874], [38.171408325371246, 0.04312397733330159], [37.696186039700414, 0.03944856610098649], [36.94799476465078, 0.03403803884951845], [36.55577169093644, 0.03132675331639623]], [[36.55577169093644, 0.03132675331639623], [35.91224934205083, 0.027025349874293142], [35.60421157565673, 0.02512866440336975], [34.69467180749164, 0.01966623504162482], [34.696204535535905, 0.01973362209099], [34.19298026320684, 0.016852343496734035], [33.40408151668095, 0.01270759613338815], [32.991791722714325, 0.010658990398083185]], [[32.991791722714325, 0.010658990398083185], [32.32035257719971, 0.007463945263192662], [32.00043881324034, 0.006086350894188311], [31.05720223751847, 0.002156778328793796], [31.05914998740604, 0.0022205135098835316], [30.53874175294163, 0.00017633438946643154], [29.725990028270406, -0.0026787632097229758], [29.302322562766737, -0.004064716551576003]], [[29.302322562766737, -0.004064716551576003], [28.62079186713181, -0.006168918267411214], [28.2971930586516, -0.007051644050249425], [27.343940089568274, -0.009531921492493503], [27.34621015005478, -0.00948040920927136], [26.821209788458493, -0.010744043104077436], [26.003370009270828, -0.012437172274957595], [25.577681810515216, -0.013236223846670878]], [[25.577681810515216, -0.013236223846670878], [24.892421670208613, -0.014417801094699742], [24.56782616646399, -0.014891620070602421], [23.611765589519063, -0.016180865150781223], [23.614288812492592, -0.016145063663307938], [23.088038293726058, -0.01677289613986996], [22.26910853056632, -0.01754380621777938], [21.84288999583587, -0.017882720795927752]], [[21.84288999583587, -0.017882720795927752], [21.156334884835108, -0.018345784547307127], [20.831223339968243, -0.01850856332313737], [19.872209121835542, -0.0188964400858367], [19.874865075347426, -0.018877223021188383], [19.345970948097666, -0.01902743703105738], [18.521205386210394, -0.01912350666034328], [18.09072486316453, -0.019129149103698513]], [[18.09072486316453, -0.019129149103698513], [17.390978510249635, -0.019075182885257003], [17.058466927260504, -0.01901809678265811], [16.072433799440944, -0.018767700532820918], [16.075115278142746, -0.01876309923257709], [15.527228561787394, -0.018574044788813127], [14.665108042839753, -0.018194870918124387], [14.210679415729235, -0.017963681790730327]], [[14.210679415729235, -0.017963681790730327], [13.460841740951489, -0.017532723861679762], [13.09980656457531, -0.0173131021217776], [12.011115841314401, -0.016569247340887317], [12.013693928484853, -0.01657622164205451], [11.393645318481195, -0.016105990617878457], [10.38729099434146, -0.01528994383890542], [9.838307102538602, -0.014812116064381691]], [[9.838307102538602, -0.014812116064381691], [9.152261136680975, -0.014176317599052534], [8.807097762669601, -0.013851682431558028], [7.71879334138072, -0.012738941760064543], [7.719872367962244, -0.012745803726334787], [7.055585664601815, -0.012005598917505807], [5.872324282735631, -0.010575151658251337], [5.149509411143692, -0.009610802858193738]]], SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [0.0, 0.0], (0.0, 11.18), Any[GasChromatographySimulator.Column(11.18, 0.000104, [0.000104], 1.04e-7, [1.04e-7], "FS5ms", "H2"), GasChromatographySimulator.Program{GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}}([0.0, 60.0, 1680.0, 60.0, 360.0, 60.0], [40.0, 40.0, 180.0, 180.0, 300.0, 300.0], [411564.0, 411564.0, 411564.0, 411564.0, 411564.0, 411564.0], [101300.0, 101300.0, 101300.0, 101300.0, 101300.0, 101300.0], GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}([0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0]), [0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0], 11181×6 extrapolate(interpolate((0.0:0.001:11.18,::Vector{Float64}), ::Matrix{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
   ⋮                                       ⋮
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0), GasChromatographySimulator.Substance("C10", "124-18-5", 391.24, 32.24, 112.49, 0.001, "Leppert2020b, alkane, Grob, alkanes", 0.00011884991852543487, 0.0, 0.0), GasChromatographySimulator.Options(OwrenZen5(), 1.0e-6, 0.001, "inlet", true, true, "Blumberg", "Pressure")], Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}(), SciMLBase.StandardODEProblem()), OwrenZen5(), OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [[0.0, 0.0], [0.004822669065209952, 3.087876177685592e-5], [0.05304824530626859, 0.0003396521089717704], [0.535192549282912, 0.0034259585235565933], [5.34547235482715, 0.03414631693297235], [39.54141241372222, 0.24871242625193676], [54.9414428371616, 0.34307712507497223], [59.04268779050093, 0.36796228591367053], [60.122582256358626, 0.37449735814202056], [70.59431013333138, 0.39875029162611697], [83.31354096508814, 0.4207739970108184], [98.52258152048765, 0.4381113231268197], [115.85341588715168, 0.4481514397231827], [135.19961279446267, 0.4497337533766557], [156.21510313605512, 0.4426454302336088], [178.64110302788632, 0.42749772913305606], [201.97173126255097, 0.4055020026523152], [225.43338165050096, 0.3782578421365638], [247.30930403827728, 0.34819911642017964], [260.06723655405875, 0.32722433280414565]], [0.0, 9.999999999999999e-5, 0.0010999999999999998, 0.011099999999999997, 0.11109999999999996, 0.8347177402027082, 1.16839532552501, 1.2581333610542251, 1.2818251163532415, 1.5187426693434056, 1.8260865780252582, 2.224307194767151, 2.72345009777049, 3.345767731265788, 4.113424130277604, 5.0618766750576425, 6.234035871945446, 7.691391969078953, 9.511938287303153, 11.18], [[[0.0, 0.0]], [[48.226791960633314, 0.3087889150934343], [48.22675819115749, 0.3087884826518089], [48.226741306410695, 0.30878826643099594], [48.22669065213519, 0.3087876177685619], [48.22669065213519, 0.3087876177685619], [48.22666170681052, 0.3087872471043072], [48.226614670621515, 0.30878664477490203], [48.226589343423605, 0.30878632044368093]], [[48.226589343423605, 0.30878632044368093], [48.226251646182405, 0.30878199602742545], [48.22608279667502, 0.30877983381929763], [48.22557624460584, 0.30877334719491456], [48.22557624460584, 0.30877334719491456], [48.225286783891804, 0.30876964055241135], [48.22481640652551, 0.3087636172583394], [48.224563124504925, 0.30876037394614775]], [[48.224563124504925, 0.30876037394614775], [48.221185903773126, 0.3087171297835905], [48.219497204706656, 0.30869550770231496], [48.214430752629085, 0.30863064145848207], [48.214430752629085, 0.30863064145848207], [48.21153539810891, 0.3085935750334325], [48.20683007612205, 0.3085333420927344], [48.204296250964525, 0.30850090897081395]], [[48.204296250964525, 0.30850090897081395], [48.170499179682395, 0.3080684673452634], [48.15359174873966, 0.307852246532487], [48.102833799660836, 0.30720358409415577], [48.102833799660985, 0.3072035840941577], [48.07380519564049, 0.30683291984368405], [48.02659629245133, 0.3062305904366658], [48.00115688256739, 0.3059062592174995]], [[48.00115688256739, 0.3059062592174995], [47.75501531316324, 0.3027770348989785], [47.631467543088156, 0.30121242273971804], [47.258886344810044, 0.29651858626193667], [47.258886344810044, 0.29651858626193667], [47.04465799768703, 0.29383639398891875], [46.69444073888018, 0.2894778315452645], [46.504769809542125, 0.28713091330637386]], [[46.504769809542125, 0.28713091330637386], [46.38776903460871, 0.28568795253230084], [46.32915784355521, 0.28496647214526427], [46.15287767786108, 0.2828020309841547], [46.15287767786108, 0.2828020309841547], [46.05184319477261, 0.28156520746352076], [45.8871877012466, 0.27955536924249036], [45.79828185485472, 0.27847314866193557]], [[45.79828185485472, 0.27847314866193557], [45.766359766519024, 0.278085084042354], [45.75039036980252, 0.277891051732563], [45.70244869940695, 0.27730895480319057], [45.70244869940695, 0.27730895480319057], [45.67503086617753, 0.27697632798640637], [45.63044175022669, 0.27643580940913187], [45.606414169359255, 0.27614476094444557]], [[45.606414169359255, 0.27614476094444557], [45.59795312171832, 0.27604230793270856], [45.59372200908877, 0.27599108142684], [45.58102631465199, 0.27583740190923445], [45.58102631465199, 0.27583740190923445], [45.57377004421155, 0.2757495850420313], [45.56197613997221, 0.2756068826328261], [45.530015088164426, 0.11877593474059447]], [[45.530015088164426, 0.11877593474059447], [45.072369400809784, 0.11285665090456856], [44.849556791784835, 0.11009654310883629], [44.187810373214035, 0.10199966710272054], [44.18822492078715, 0.10203246312237316], [43.81785311430543, 0.09762430515906531], [43.228910833575526, 0.09087976577749818], [42.917783421935155, 0.08741763834854305]], [[42.917783421935155, 0.08741763834854305], [42.38673907438439, 0.0816270597512248], [42.12965019724548, 0.07897170720804364], [41.367630759825936, 0.07122209853164257], [41.36833374478905, 0.07126981209587518], [40.94354650265526, 0.06709152015336184], [40.27126103016033, 0.0608061780101615], [39.91743237924775, 0.05761495172159847]], [[39.91743237924775, 0.05761495172159847], [39.315827129247616, 0.052329154487093826], [39.02638132377312, 0.04995285644223815], [38.1702839269217, 0.043061025239525874], [38.171408325371246, 0.04312397733330159], [37.696186039700414, 0.03944856610098649], [36.94799476465078, 0.03403803884951845], [36.55577169093644, 0.03132675331639623]], [[36.55577169093644, 0.03132675331639623], [35.91224934205083, 0.027025349874293142], [35.60421157565673, 0.02512866440336975], [34.69467180749164, 0.01966623504162482], [34.696204535535905, 0.01973362209099], [34.19298026320684, 0.016852343496734035], [33.40408151668095, 0.01270759613338815], [32.991791722714325, 0.010658990398083185]], [[32.991791722714325, 0.010658990398083185], [32.32035257719971, 0.007463945263192662], [32.00043881324034, 0.006086350894188311], [31.05720223751847, 0.002156778328793796], [31.05914998740604, 0.0022205135098835316], [30.53874175294163, 0.00017633438946643154], [29.725990028270406, -0.0026787632097229758], [29.302322562766737, -0.004064716551576003]], [[29.302322562766737, -0.004064716551576003], [28.62079186713181, -0.006168918267411214], [28.2971930586516, -0.007051644050249425], [27.343940089568274, -0.009531921492493503], [27.34621015005478, -0.00948040920927136], [26.821209788458493, -0.010744043104077436], [26.003370009270828, -0.012437172274957595], [25.577681810515216, -0.013236223846670878]], [[25.577681810515216, -0.013236223846670878], [24.892421670208613, -0.014417801094699742], [24.56782616646399, -0.014891620070602421], [23.611765589519063, -0.016180865150781223], [23.614288812492592, -0.016145063663307938], [23.088038293726058, -0.01677289613986996], [22.26910853056632, -0.01754380621777938], [21.84288999583587, -0.017882720795927752]], [[21.84288999583587, -0.017882720795927752], [21.156334884835108, -0.018345784547307127], [20.831223339968243, -0.01850856332313737], [19.872209121835542, -0.0188964400858367], [19.874865075347426, -0.018877223021188383], [19.345970948097666, -0.01902743703105738], [18.521205386210394, -0.01912350666034328], [18.09072486316453, -0.019129149103698513]], [[18.09072486316453, -0.019129149103698513], [17.390978510249635, -0.019075182885257003], [17.058466927260504, -0.01901809678265811], [16.072433799440944, -0.018767700532820918], [16.075115278142746, -0.01876309923257709], [15.527228561787394, -0.018574044788813127], [14.665108042839753, -0.018194870918124387], [14.210679415729235, -0.017963681790730327]], [[14.210679415729235, -0.017963681790730327], [13.460841740951489, -0.017532723861679762], [13.09980656457531, -0.0173131021217776], [12.011115841314401, -0.016569247340887317], [12.013693928484853, -0.01657622164205451], [11.393645318481195, -0.016105990617878457], [10.38729099434146, -0.01528994383890542], [9.838307102538602, -0.014812116064381691]], [[9.838307102538602, -0.014812116064381691], [9.152261136680975, -0.014176317599052534], [8.807097762669601, -0.013851682431558028], [7.71879334138072, -0.012738941760064543], [7.719872367962244, -0.012745803726334787], [7.055585664601815, -0.012005598917505807], [5.872324282735631, -0.010575151658251337], [5.149509411143692, -0.009610802858193738]]], true, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}([260.06723655405875, 0.32722433280414565], [247.30930403827728, 0.34819911642017964], [9.838307102538602, -0.014812116064381691], [9.152261136680975, -0.014176317599052534], [8.807097762669601, -0.013851682431558028], [7.71879334138072, -0.012738941760064543], [7.719872367962244, -0.012745803726334787], [7.055585664601815, -0.012005598917505807], [5.872324282735631, -0.010575151658251337], [5.149509411143692, -0.009610802858193738], [0.00852559440045434, -2.0119929604387464e-5], [258.9155789819566, 0.32933469754289435], [0.03278214407656884, -0.05761735542359684], OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}(0.16666666666666666, 0.0625, 0.1875, 0.25, -0.75, -0.75, 3.75, -3.0, 0.5, 0.26895043731778423, -0.7084548104956269, 0.8658892128279884, 0.15462307371928363, 0.06184922948771345, -0.02947695035460993, 0.18500664893617022, 0.4802345261121857, -0.5337849069148937, -0.013090093085106383, 0.7861107753062541, 0.08783068783068783, 0.3006060606060606, 0.22777777777777777, 0.027777777777777776, 0.06218596218596219, 0.2938217338217338, 0.16666666666666666, 0.25, 0.5, 0.5, 0.6428571428571429, 0.875, -0.19894179894179895, 0.9115151515151515, -1.9777777777777779, -0.1111111111111111, 1.67013727013727, -0.2938217338217338, 1.892063492063492, -6.067155067155067, 7.282458282458283, -4.0195360195360195, -7.214545454545455, 20.676923076923078, -20.31142191142191, 7.14965034965035, 7.866666666666666, -18.78205128205128, 13.508547008547009, -2.3653846153846154, 2.0, -5.294871794871795, 4.534188034188034, -1.2115384615384615, -1.4924630924630924, 1.5785667324128863, 1.1958838881915805, -1.219801565955412, -7.051721611721612, 16.273203719357564, -11.978886071193763, 3.0512256973795435, 4.0, -8.384615384615385, 5.769230769230769, -1.3846153846153846))), true, 0, DiffEqBase.DEStats
Number of function 1 evaluations:                  234
Number of function 2 evaluations:                  0
Number of W matrix evaluations:                    0
Number of linear solves:                           0
Number of Jacobians created:                       0
Number of nonlinear solver iterations:             0
Number of nonlinear solver convergence failures:   0
Number of rootfind condition calls:                0
Number of accepted steps:                          19
Number of rejected steps:                          14, :Success), SciMLBase.ODESolution{Float64, 2, Vector{Vector{Float64}}, Nothing, Nothing, Vector{Float64}, Vector{Vector{Vector{Float64}}}, SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}, OwrenZen5, OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}, DiffEqBase.DEStats}([[0.0, 0.0], [0.01212604423322558, 0.0002067499455912], [0.13338368450765992, 0.002274153852324587], [1.345679837895914, 0.022938638001797414], [13.440572708941787, 0.22862798771041795], [43.93810986747227, 0.743388318266301], [55.85386922753595, 0.9429782544765216], [59.80235601466705, 1.00892355806184], [60.0592447527859, 1.0124248713287154], [60.1795366273383, 1.0131786589470235]  …  [167.46629586563333, 1.1279562535378613], [191.45488582313556, 1.0768582254960142], [217.3303131740597, 1.0115746208641678], [245.1269870025268, 0.9354495334050005], [274.8926691199833, 0.8516847686285277], [306.8612978620087, 0.7625625612586252], [341.58394246859336, 0.6688546113072922], [375.0152312492648, 0.5818199447726602], [402.5130965618371, 0.5104756913360825], [412.8002973796307, 0.4820993586311031]], nothing, nothing, [0.0, 9.999999999999999e-5, 0.0010999999999999998, 0.011099999999999997, 0.11109999999999996, 0.36515975117766236, 0.4651856822358744, 0.49842749435781275, 0.5005919751365738, 0.5016061758545334  …  1.7319479494347247, 2.119992869431887, 2.600133121689281, 3.1995115307788837, 3.9572135949420186, 4.938979618943902, 6.27256051426141, 7.964194781746699, 9.973325021907373, 11.18], [[[0.0, 0.0]], [[121.26069706086078, 2.067508142200963], [121.26061215141499, 2.0675052467713093], [121.26056969666976, 2.067503799056481], [121.26044233234519, 2.0674994559120066], [121.26044233234519, 2.0674994559120066], [121.26036955267072, 2.067496974115152], [121.26025128560691, 2.0674929411952747], [121.26018760329362, 2.0674907696230194]], [[121.26018760329362, 2.0674907696230194], [121.25933850259294, 2.067461815326486], [121.25891395001271, 2.067447338178211], [121.25764028335338, 2.0674039067333885], [121.25764028335338, 2.0674039067333885], [121.25691246782709, 2.067379088764918], [121.25572975827959, 2.0673387595661548], [121.25509290989835, 2.067317043843727]], [[121.25509290989835, 2.067317043843727], [121.24660127851713, 2.0670275008782557], [121.24235523979839, 2.066882729395511], [121.22961623134344, 2.066448414947289], [121.22961623134321, 2.06644841494728], [121.2223361968839, 2.0662002352625772], [121.21050520832237, 2.0657969432749423], [121.20413419768046, 2.0655797860508196]], [[121.20413419768046, 2.0655797860508196], [121.11915536629454, 2.0626843563959487], [121.07664358439334, 2.061236641568513], [120.94901858516711, 2.0568934970862056], [120.94901858516711, 2.0568934970862056], [120.8760295138413, 2.054411700239174], [120.757328180506, 2.0503787803627462], [120.69336372320089, 2.048207208121593]], [[120.69336372320089, 2.048207208121593], [120.47643410119176, 2.040851086744903], [120.36782268196833, 2.0371730260565584], [120.04139880713933, 2.0261388439915233], [120.04139880713933, 2.0261388439915233], [119.85447172927815, 2.019833597097218], [119.55009185751399, 2.0095875708939723], [119.38587357107407, 2.0040704798614546]], [[119.38587357107407, 2.0040704798614546], [119.29957719350675, 2.001174299391033], [119.25640558754057, 1.9997262091558234], [119.12679689721988, 1.995381938450193], [119.12679689721988, 1.995381938450193], [119.05267143715743, 1.9928994980469754], [118.93211903009517, 1.9888655323917472], [118.86715555465467, 1.9866933970389316]], [[118.86715555465467, 1.9866933970389316], [118.83835828286965, 1.9857309037529356], [118.82395702981917, 1.9852496571099392], [118.78074279442, 1.9838059171809466], [118.78074279442, 1.9838059171809466], [118.75604188529792, 1.9829809229358073], [118.71589194648253, 1.9816403072874564], [118.69426712328543, 1.9809184373229602]], [[118.69426712328543, 1.9809184373229602], [118.69238952214651, 1.9808557663046187], [118.69145071043877, 1.980824430795448], [118.68863423076023, 1.9807304242679342], [118.68863423076023, 1.9807304242679342], [118.6870247837931, 1.980676706252212], [118.66785324360856, 0.7447798377219563], [118.64686962857178, 0.7446002423559517]], [[118.64686962857178, 0.7446002423559517], [118.6337619433285, 0.7441441079605169], [118.62721023241642, 0.7439162303056024], [118.60755754533831, 0.7432327916230821], [118.607557547218, 0.7432327920150621], [118.59633044977228, 0.742842512545417], [118.5780910883996, 0.7422087078448998], [118.56827228684067, 0.7418676326778217]]  …  [[74.44360713220257, -0.08542137747178535], [72.8876709277276, -0.09465416406035054], [72.15471641219618, -0.09835710442801393], [69.99948572175369, -0.10869837157431017], [70.00659707567986, -0.1083479643991897], [68.82489848772546, -0.11355357491713003], [66.99822148695377, -0.12003486277582254], [66.05249499614617, -0.12298265278869358]], [[66.05249499614617, -0.12298265278869358], [64.5339597346001, -0.12718816083838747], [63.822065024570264, -0.12870024654760115], [61.731928937039754, -0.13267627989389696], [61.73995915944346, -0.13243428113974287], [60.59708253211126, -0.13426076400867154], [58.8381315511036, -0.13594094903813575], [57.929962384935905, -0.13651769067771952]], [[57.929962384935905, -0.13651769067771952], [56.474516589090044, -0.137046594368954], [55.79512011000688, -0.13700529517783416], [53.80312476707659, -0.13650146205075736], [53.8117895671873, -0.1363715943447678], [52.725153088335624, -0.13584359760212544], [51.0592639594873, -0.13431631253456278], [50.2011616449872, -0.13333851002344305]], [[50.2011616449872, -0.13333851002344305], [48.81632749723221, -0.13148166761135088], [48.172594731459476, -0.13046815330560885], [46.287643657956096, -0.1271877468619551], [46.29682160208999, -0.1271547762396842], [45.270838239185466, -0.12518621292647975], [43.7038052026811, -0.12180360904319432], [42.89834067252884, -0.11995061739375384]], [[42.89834067252884, -0.11995061739375384], [41.584349306846626, -0.11674454890346858], [40.97603592692987, -0.1152138453578716], [39.19689916736723, -0.11048404929285699], [39.20650719700043, -0.11052772567757232], [38.23997610647972, -0.1078255553961667], [36.76880252700155, -0.10360183491303454], [36.01391930651036, -0.10137656311088583]], [[36.01391930651036, -0.10137656311088583], [34.75377504920593, -0.0975530362208768], [34.17294355296384, -0.09581915483672962], [32.47572510469019, -0.09054823052421632], [32.48594445327627, -0.09065010665966591], [31.56528377287658, -0.08769290760587146], [30.16827745764324, -0.08329352534159871], [29.452187502151965, -0.08102057890550637]], [[29.452187502151965, -0.08102057890550637], [28.200652754580858, -0.07699707973529568], [27.626779321875745, -0.07523871382242926], [25.949692008587014, -0.06993258240973113], [25.961254875811658, -0.07008553646131553], [25.051497243839297, -0.0671312818618122], [23.673556117911343, -0.06290915551241984], [22.96626778095351, -0.06075448913463305]], [[22.96626778095351, -0.06075448913463305], [21.808005775919888, -0.057231049097744596], [21.27257259573157, -0.055712153108088615], [19.69668658618171, -0.051141538830856384], [19.706233627475665, -0.05128219769562696], [18.84200392839898, -0.04874354746024256], [17.51176900006953, -0.04513605501832022], [16.818406826297323, -0.043289581890432215]], [[16.818406826297323, -0.043289581890432215], [15.737814942424219, -0.04044487770611053], [15.224579268344218, -0.03919506868972239], [13.676887091999484, -0.03537480108046473], [13.683040600079108, -0.03546644767786018], [12.801798847534736, -0.033293163720062], [11.371560869363247, -0.02999250617984344], [10.5840619652788, -0.028196792964103636]], [[10.5840619652788, -0.028196792964103636], [9.93598869237227, -0.026720135308233636], [9.608767642342517, -0.02599313558743742], [8.58183816261825, -0.02366847504494162], [8.582475676926563, -0.023677531400888553], [7.960761705795066, -0.02225056678042584], [6.871461863872013, -0.01971727277494369], [6.225576885629735, -0.01817165413688425]]], SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [0.0, 0.0], (0.0, 11.18), Any[GasChromatographySimulator.Column(11.18, 0.000104, [0.000104], 1.04e-7, [1.04e-7], "FS5ms", "H2"), GasChromatographySimulator.Program{GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}}([0.0, 60.0, 1680.0, 60.0, 360.0, 60.0], [40.0, 40.0, 180.0, 180.0, 300.0, 300.0], [411564.0, 411564.0, 411564.0, 411564.0, 411564.0, 411564.0], [101300.0, 101300.0, 101300.0, 101300.0, 101300.0, 101300.0], GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}([0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0]), [0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0], 11181×6 extrapolate(interpolate((0.0:0.001:11.18,::Vector{Float64}), ::Matrix{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
   ⋮                                       ⋮
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0), GasChromatographySimulator.Substance("C11", "1120-21-4", 410.21999999999997, 33.71, 116.04, 0.001, "Leppert2020b, alkane, Grob, alkanes", 0.00011323854999018596, 0.0, 0.0), GasChromatographySimulator.Options(OwrenZen5(), 1.0e-6, 0.001, "inlet", true, true, "Blumberg", "Pressure")], Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}(), SciMLBase.StandardODEProblem()), OwrenZen5(), OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [[0.0, 0.0], [0.01212604423322558, 0.0002067499455912], [0.13338368450765992, 0.002274153852324587], [1.345679837895914, 0.022938638001797414], [13.440572708941787, 0.22862798771041795], [43.93810986747227, 0.743388318266301], [55.85386922753595, 0.9429782544765216], [59.80235601466705, 1.00892355806184], [60.0592447527859, 1.0124248713287154], [60.1795366273383, 1.0131786589470235]  …  [167.46629586563333, 1.1279562535378613], [191.45488582313556, 1.0768582254960142], [217.3303131740597, 1.0115746208641678], [245.1269870025268, 0.9354495334050005], [274.8926691199833, 0.8516847686285277], [306.8612978620087, 0.7625625612586252], [341.58394246859336, 0.6688546113072922], [375.0152312492648, 0.5818199447726602], [402.5130965618371, 0.5104756913360825], [412.8002973796307, 0.4820993586311031]], [0.0, 9.999999999999999e-5, 0.0010999999999999998, 0.011099999999999997, 0.11109999999999996, 0.36515975117766236, 0.4651856822358744, 0.49842749435781275, 0.5005919751365738, 0.5016061758545334  …  1.7319479494347247, 2.119992869431887, 2.600133121689281, 3.1995115307788837, 3.9572135949420186, 4.938979618943902, 6.27256051426141, 7.964194781746699, 9.973325021907373, 11.18], [[[0.0, 0.0]], [[121.26069706086078, 2.067508142200963], [121.26061215141499, 2.0675052467713093], [121.26056969666976, 2.067503799056481], [121.26044233234519, 2.0674994559120066], [121.26044233234519, 2.0674994559120066], [121.26036955267072, 2.067496974115152], [121.26025128560691, 2.0674929411952747], [121.26018760329362, 2.0674907696230194]], [[121.26018760329362, 2.0674907696230194], [121.25933850259294, 2.067461815326486], [121.25891395001271, 2.067447338178211], [121.25764028335338, 2.0674039067333885], [121.25764028335338, 2.0674039067333885], [121.25691246782709, 2.067379088764918], [121.25572975827959, 2.0673387595661548], [121.25509290989835, 2.067317043843727]], [[121.25509290989835, 2.067317043843727], [121.24660127851713, 2.0670275008782557], [121.24235523979839, 2.066882729395511], [121.22961623134344, 2.066448414947289], [121.22961623134321, 2.06644841494728], [121.2223361968839, 2.0662002352625772], [121.21050520832237, 2.0657969432749423], [121.20413419768046, 2.0655797860508196]], [[121.20413419768046, 2.0655797860508196], [121.11915536629454, 2.0626843563959487], [121.07664358439334, 2.061236641568513], [120.94901858516711, 2.0568934970862056], [120.94901858516711, 2.0568934970862056], [120.8760295138413, 2.054411700239174], [120.757328180506, 2.0503787803627462], [120.69336372320089, 2.048207208121593]], [[120.69336372320089, 2.048207208121593], [120.47643410119176, 2.040851086744903], [120.36782268196833, 2.0371730260565584], [120.04139880713933, 2.0261388439915233], [120.04139880713933, 2.0261388439915233], [119.85447172927815, 2.019833597097218], [119.55009185751399, 2.0095875708939723], [119.38587357107407, 2.0040704798614546]], [[119.38587357107407, 2.0040704798614546], [119.29957719350675, 2.001174299391033], [119.25640558754057, 1.9997262091558234], [119.12679689721988, 1.995381938450193], [119.12679689721988, 1.995381938450193], [119.05267143715743, 1.9928994980469754], [118.93211903009517, 1.9888655323917472], [118.86715555465467, 1.9866933970389316]], [[118.86715555465467, 1.9866933970389316], [118.83835828286965, 1.9857309037529356], [118.82395702981917, 1.9852496571099392], [118.78074279442, 1.9838059171809466], [118.78074279442, 1.9838059171809466], [118.75604188529792, 1.9829809229358073], [118.71589194648253, 1.9816403072874564], [118.69426712328543, 1.9809184373229602]], [[118.69426712328543, 1.9809184373229602], [118.69238952214651, 1.9808557663046187], [118.69145071043877, 1.980824430795448], [118.68863423076023, 1.9807304242679342], [118.68863423076023, 1.9807304242679342], [118.6870247837931, 1.980676706252212], [118.66785324360856, 0.7447798377219563], [118.64686962857178, 0.7446002423559517]], [[118.64686962857178, 0.7446002423559517], [118.6337619433285, 0.7441441079605169], [118.62721023241642, 0.7439162303056024], [118.60755754533831, 0.7432327916230821], [118.607557547218, 0.7432327920150621], [118.59633044977228, 0.742842512545417], [118.5780910883996, 0.7422087078448998], [118.56827228684067, 0.7418676326778217]]  …  [[74.44360713220257, -0.08542137747178535], [72.8876709277276, -0.09465416406035054], [72.15471641219618, -0.09835710442801393], [69.99948572175369, -0.10869837157431017], [70.00659707567986, -0.1083479643991897], [68.82489848772546, -0.11355357491713003], [66.99822148695377, -0.12003486277582254], [66.05249499614617, -0.12298265278869358]], [[66.05249499614617, -0.12298265278869358], [64.5339597346001, -0.12718816083838747], [63.822065024570264, -0.12870024654760115], [61.731928937039754, -0.13267627989389696], [61.73995915944346, -0.13243428113974287], [60.59708253211126, -0.13426076400867154], [58.8381315511036, -0.13594094903813575], [57.929962384935905, -0.13651769067771952]], [[57.929962384935905, -0.13651769067771952], [56.474516589090044, -0.137046594368954], [55.79512011000688, -0.13700529517783416], [53.80312476707659, -0.13650146205075736], [53.8117895671873, -0.1363715943447678], [52.725153088335624, -0.13584359760212544], [51.0592639594873, -0.13431631253456278], [50.2011616449872, -0.13333851002344305]], [[50.2011616449872, -0.13333851002344305], [48.81632749723221, -0.13148166761135088], [48.172594731459476, -0.13046815330560885], [46.287643657956096, -0.1271877468619551], [46.29682160208999, -0.1271547762396842], [45.270838239185466, -0.12518621292647975], [43.7038052026811, -0.12180360904319432], [42.89834067252884, -0.11995061739375384]], [[42.89834067252884, -0.11995061739375384], [41.584349306846626, -0.11674454890346858], [40.97603592692987, -0.1152138453578716], [39.19689916736723, -0.11048404929285699], [39.20650719700043, -0.11052772567757232], [38.23997610647972, -0.1078255553961667], [36.76880252700155, -0.10360183491303454], [36.01391930651036, -0.10137656311088583]], [[36.01391930651036, -0.10137656311088583], [34.75377504920593, -0.0975530362208768], [34.17294355296384, -0.09581915483672962], [32.47572510469019, -0.09054823052421632], [32.48594445327627, -0.09065010665966591], [31.56528377287658, -0.08769290760587146], [30.16827745764324, -0.08329352534159871], [29.452187502151965, -0.08102057890550637]], [[29.452187502151965, -0.08102057890550637], [28.200652754580858, -0.07699707973529568], [27.626779321875745, -0.07523871382242926], [25.949692008587014, -0.06993258240973113], [25.961254875811658, -0.07008553646131553], [25.051497243839297, -0.0671312818618122], [23.673556117911343, -0.06290915551241984], [22.96626778095351, -0.06075448913463305]], [[22.96626778095351, -0.06075448913463305], [21.808005775919888, -0.057231049097744596], [21.27257259573157, -0.055712153108088615], [19.69668658618171, -0.051141538830856384], [19.706233627475665, -0.05128219769562696], [18.84200392839898, -0.04874354746024256], [17.51176900006953, -0.04513605501832022], [16.818406826297323, -0.043289581890432215]], [[16.818406826297323, -0.043289581890432215], [15.737814942424219, -0.04044487770611053], [15.224579268344218, -0.03919506868972239], [13.676887091999484, -0.03537480108046473], [13.683040600079108, -0.03546644767786018], [12.801798847534736, -0.033293163720062], [11.371560869363247, -0.02999250617984344], [10.5840619652788, -0.028196792964103636]], [[10.5840619652788, -0.028196792964103636], [9.93598869237227, -0.026720135308233636], [9.608767642342517, -0.02599313558743742], [8.58183816261825, -0.02366847504494162], [8.582475676926563, -0.023677531400888553], [7.960761705795066, -0.02225056678042584], [6.871461863872013, -0.01971727277494369], [6.225576885629735, -0.01817165413688425]]], true, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}([412.8002973796307, 0.4820993586311031], [402.5130965618371, 0.5104756913360825], [10.5840619652788, -0.028196792964103636], [9.93598869237227, -0.026720135308233636], [9.608767642342517, -0.02599313558743742], [8.58183816261825, -0.02366847504494162], [8.582475676926563, -0.023677531400888553], [7.960761705795066, -0.02225056678042584], [6.871461863872013, -0.01971727277494369], [6.225576885629735, -0.01817165413688425], [0.003532820509822202, -1.1985896851871156e-5], [411.8111783225901, 0.4849633932489087], [0.008558162322278897, -0.023433952101538712], OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}(0.16666666666666666, 0.0625, 0.1875, 0.25, -0.75, -0.75, 3.75, -3.0, 0.5, 0.26895043731778423, -0.7084548104956269, 0.8658892128279884, 0.15462307371928363, 0.06184922948771345, -0.02947695035460993, 0.18500664893617022, 0.4802345261121857, -0.5337849069148937, -0.013090093085106383, 0.7861107753062541, 0.08783068783068783, 0.3006060606060606, 0.22777777777777777, 0.027777777777777776, 0.06218596218596219, 0.2938217338217338, 0.16666666666666666, 0.25, 0.5, 0.5, 0.6428571428571429, 0.875, -0.19894179894179895, 0.9115151515151515, -1.9777777777777779, -0.1111111111111111, 1.67013727013727, -0.2938217338217338, 1.892063492063492, -6.067155067155067, 7.282458282458283, -4.0195360195360195, -7.214545454545455, 20.676923076923078, -20.31142191142191, 7.14965034965035, 7.866666666666666, -18.78205128205128, 13.508547008547009, -2.3653846153846154, 2.0, -5.294871794871795, 4.534188034188034, -1.2115384615384615, -1.4924630924630924, 1.5785667324128863, 1.1958838881915805, -1.219801565955412, -7.051721611721612, 16.273203719357564, -11.978886071193763, 3.0512256973795435, 4.0, -8.384615384615385, 5.769230769230769, -1.3846153846153846))), true, 0, DiffEqBase.DEStats
Number of function 1 evaluations:                  360
Number of function 2 evaluations:                  0
Number of W matrix evaluations:                    0
Number of linear solves:                           0
Number of Jacobians created:                       0
Number of nonlinear solver iterations:             0
Number of nonlinear solver convergence failures:   0
Number of rootfind condition calls:                0
Number of accepted steps:                          26
Number of rejected steps:                          25, :Success), SciMLBase.ODESolution{Float64, 2, Vector{Vector{Float64}}, Nothing, Nothing, Vector{Float64}, Vector{Vector{Vector{Float64}}}, SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}, OwrenZen5, OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}, DiffEqBase.DEStats}([[0.0, 0.0], [0.031234858582652274, 0.0014304308334663128], [0.34357622673141347, 0.015734078096655807], [3.466268028203005, 0.15870444358119157], [34.620885406582325, 1.5817973836906158], [49.79083179629882, 2.2725545395762117], [56.92538725951205, 2.5969270997681857], [59.455960276777425, 2.711903126158041], [60.015087748277146, 2.737301552790204], [65.51695724342629, 2.8102150770981584]  …  [294.5969225949649, 1.9125053300844777], [331.9752139225331, 1.6632148479457487], [367.14351418343324, 1.451735126115357], [402.1337552680033, 1.2637004142252113], [436.37680431565116, 1.099974641616828], [470.0421101047756, 0.9565834411976775], [502.601296897343, 0.8321959021203299], [533.4476733742906, 0.7248493100643213], [561.1493266049126, 0.63425586409754], [580.175860002369, 0.5716958903006855]], nothing, nothing, [0.0, 9.999999999999999e-5, 0.0010999999999999998, 0.011099999999999997, 0.11109999999999996, 0.15994618277717132, 0.18295411228298886, 0.19112027877497884, 0.19292496882088475, 0.21097186927994396  …  1.7521505765761227, 2.2365633880238596, 2.789603878035511, 3.45507277393434, 4.245293826538488, 5.194450396383983, 6.331657489824366, 7.702383623869318, 9.365616634552813, 11.18], [[[0.0, 0.0]], [[312.3492419689374, 14.304368432069733], [312.34902325502867, 14.304348399600842], [312.34891389801675, 14.304338383366385], [312.34858582675326, 14.304308334663201], [312.34858582675326, 14.304308334663201], [312.3483983573025, 14.30429116397542], [312.3480937192093, 14.304263261608183], [312.3479296831873, 14.30424823725635]], [[312.3479296831873, 14.30424823725635], [312.3457425280186, 14.304047912567382], [312.34464894469096, 14.303947750222902], [312.34136817173476, 14.303647263189449], [312.34136817173476, 14.303647263189449], [312.339493428859, 14.30347555631319], [312.3364469476875, 14.303196532639442], [312.3348065224382, 14.303046289122543]], [[312.3348065224382, 14.303046289122543], [312.31293336246625, 14.301043042232875], [312.3019962079958, 14.300041418788203], [312.26918244614984, 14.297036548453521], [312.26918244614984, 14.297036548453521], [312.2504301768673, 14.295319479691104], [312.21995533713124, 14.29252924295175], [312.20354457591367, 14.291026807784467]], [[312.20354457591367, 14.291026807784467], [311.9846519403779, 14.270994338887911], [311.8751480106328, 14.260978104439374], [311.5464052874684, 14.230929401094247], [311.5464052874684, 14.230929401094247], [311.358396463066, 14.213758713468465], [311.05263975552066, 14.185856346076568], [310.88787697387363, 14.170831994404004]], [[310.88787697387363, 14.170831994404004], [310.78052289741584, 14.161046898031918], [310.72683195038945, 14.15615434984587], [310.5657034164088, 14.141476705287738], [310.5657034164088, 14.141476705287738], [310.47359242387716, 14.133089479825955], [310.32385374868244, 14.11946023845055], [310.2431952964243, 14.112121416171483]], [[310.2431952964243, 14.112121416171483], [310.19252803343284, 14.107512359849446], [310.16719129816164, 14.105207831688427], [310.0911686711596, 14.098294247205368], [310.0911686711596, 14.098294247205368], [310.0477188008184, 14.094343627500761], [309.9770997717865, 14.087923870480747], [309.93906747610225, 14.084467078239252]], [[309.93906747610225, 14.084467078239252], [309.92106752912736, 14.082831193476684], [309.9120671635956, 14.082013251095407], [309.88506449855106, 14.079559423951713], [309.88506449855106, 14.079559423951713], [309.8696333477583, 14.078157237012215], [309.8445560886226, 14.075878683235759], [309.8310521083779, 14.074651769663863]], [[309.8310521083779, 14.074651769663863], [309.8270728954717, 14.074290245691733], [309.8250832698537, 14.074109483705671], [309.8191143163364, 14.073567197747474], [309.8191143163364, 14.073567197747474], [309.8157034341231, 14.073257320057078], [309.81016067043424, 14.072753768810191], [309.7806854358767, 4.458284109700463]], [[309.7806854358767, 4.458284109700463], [308.11009955288876, 4.312016919683993], [307.2884455204805, 4.24195588198109], [304.83781939123315, 4.03448442783152], [304.8384450906457, 4.03481858295155], [303.45588500642776, 3.919823798504302], [301.2382133526692, 3.739308837627334], [300.05803340290305, 3.64491236271739]]  …  [[101.43921260223385, -0.7526151286161931], [98.3037279062643, -0.7228287831973668], [96.87267449181047, -0.7094155496599732], [92.69580618610506, -0.6688049866210428], [92.72921383725509, -0.6696798320672748], [90.47169848896368, -0.646960561040413], [87.08442948922958, -0.613520874060726], [85.35891158931848, -0.5963185092686353]], [[85.35891158931848, -0.5963185092686353], [82.29755181735958, -0.5653753416514224], [80.9182774238946, -0.5520126495376828], [76.90484742925169, -0.5117551894860543], [76.94663065721502, -0.5131871203952935], [74.78799632985773, -0.49072267637914846], [71.59109676805825, -0.45937008962534764], [69.9722444049113, -0.4434602301833591]], [[69.9722444049113, -0.4434602301833591], [67.6098939408175, -0.42019321099869866], [66.53573371853012, -0.41016720227489756], [63.40554352091409, -0.38016810934780465], [63.43219539395, -0.3811653047229765], [61.74391171855904, -0.36455644223919603], [59.219869332046486, -0.34134444161809985], [57.93655108492993, -0.32960011164793823]], [[57.93655108492993, -0.32960011164793823], [55.95849921543267, -0.31155267441958945], [55.056657562633475, -0.3038176980545551], [52.42801072333443, -0.28075912744576353], [52.44887249465464, -0.2815342838012653], [51.0300206178807, -0.2688213980823401], [48.90263701228525, -0.25114983658682216], [47.819534053929665, -0.24223796485067972]], [[47.819534053929665, -0.24223796485067972], [46.169981978523005, -0.22876166362416622], [45.41472951815257, -0.22298801456844625], [43.21168799334734, -0.2058291358678843], [43.22740301595097, -0.20638148083363042], [42.03631999945016, -0.19696033244030456], [40.24225263300838, -0.18384641825891201], [39.32664908912446, -0.17724462473671818]], [[39.32664908912446, -0.17724462473671818], [37.91378161945373, -0.16716110027263736], [37.2645050925174, -0.16284388388862683], [35.36863362087022, -0.15004381564108493], [35.380945038594106, -0.15044166490978542], [34.353868160951876, -0.14343743721624347], [32.799853932567714, -0.13367791929958353], [32.004477494265856, -0.12877171775943097]], [[32.004477494265856, -0.12877171775943097], [30.77720576695863, -0.12130325163461002], [30.21016820775815, -0.11810087498839886], [28.550509689880048, -0.10862307378776014], [28.56000006817365, -0.10889954483379101], [27.657276547556773, -0.10372849050242829], [26.281578955913677, -0.09648889699769807], [25.57372231312399, -0.09284909641332387]], [[25.57372231312399, -0.09284909641332387], [24.469837037947244, -0.08727084245150354], [23.955694197300332, -0.08487112580215983], [22.442756732023547, -0.07776855853621245], [22.450096534686523, -0.07795873080875663], [21.62024833750733, -0.07408624832283492], [20.33968081946702, -0.068610647212], [19.673563218583258, -0.06584572445081614]], [[19.673563218583258, -0.06584572445081614], [18.617011475194975, -0.06155563085036737], [18.11724118692736, -0.05969064618745137], [16.625280908669577, -0.05412550256395697], [16.63090990649627, -0.054253716688370944], [15.794493692119689, -0.051185664739651957], [14.465148294646598, -0.04670509952101016], [13.752784048149614, -0.04438161928830228]], [[13.752784048149614, -0.04438161928830228], [12.706119077145445, -0.04103540144159791], [12.189291972809812, -0.03949298116723981], [10.572850949194152, -0.03464626903954164], [10.576144718235637, -0.03470942411134387], [9.600671766290475, -0.03180388122590169], [7.88008557059758, -0.026807295531296974], [6.830383351432274, -0.02370709067020727]]], SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [0.0, 0.0], (0.0, 11.18), Any[GasChromatographySimulator.Column(11.18, 0.000104, [0.000104], 1.04e-7, [1.04e-7], "FS5ms", "H2"), GasChromatographySimulator.Program{GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}}([0.0, 60.0, 1680.0, 60.0, 360.0, 60.0], [40.0, 40.0, 180.0, 180.0, 300.0, 300.0], [411564.0, 411564.0, 411564.0, 411564.0, 411564.0, 411564.0], [101300.0, 101300.0, 101300.0, 101300.0, 101300.0, 101300.0], GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}([0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0]), [0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0], 11181×6 extrapolate(interpolate((0.0:0.001:11.18,::Vector{Float64}), ::Matrix{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
   ⋮                                       ⋮
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0), GasChromatographySimulator.Substance("C12", "112-40-3", 427.92999999999995, 34.92, 121.44, 0.001, "Leppert2020b, alkane, alkanes", 0.00010831148421185742, 0.0, 0.0), GasChromatographySimulator.Options(OwrenZen5(), 1.0e-6, 0.001, "inlet", true, true, "Blumberg", "Pressure")], Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}(), SciMLBase.StandardODEProblem()), OwrenZen5(), OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [[0.0, 0.0], [0.031234858582652274, 0.0014304308334663128], [0.34357622673141347, 0.015734078096655807], [3.466268028203005, 0.15870444358119157], [34.620885406582325, 1.5817973836906158], [49.79083179629882, 2.2725545395762117], [56.92538725951205, 2.5969270997681857], [59.455960276777425, 2.711903126158041], [60.015087748277146, 2.737301552790204], [65.51695724342629, 2.8102150770981584]  …  [294.5969225949649, 1.9125053300844777], [331.9752139225331, 1.6632148479457487], [367.14351418343324, 1.451735126115357], [402.1337552680033, 1.2637004142252113], [436.37680431565116, 1.099974641616828], [470.0421101047756, 0.9565834411976775], [502.601296897343, 0.8321959021203299], [533.4476733742906, 0.7248493100643213], [561.1493266049126, 0.63425586409754], [580.175860002369, 0.5716958903006855]], [0.0, 9.999999999999999e-5, 0.0010999999999999998, 0.011099999999999997, 0.11109999999999996, 0.15994618277717132, 0.18295411228298886, 0.19112027877497884, 0.19292496882088475, 0.21097186927994396  …  1.7521505765761227, 2.2365633880238596, 2.789603878035511, 3.45507277393434, 4.245293826538488, 5.194450396383983, 6.331657489824366, 7.702383623869318, 9.365616634552813, 11.18], [[[0.0, 0.0]], [[312.3492419689374, 14.304368432069733], [312.34902325502867, 14.304348399600842], [312.34891389801675, 14.304338383366385], [312.34858582675326, 14.304308334663201], [312.34858582675326, 14.304308334663201], [312.3483983573025, 14.30429116397542], [312.3480937192093, 14.304263261608183], [312.3479296831873, 14.30424823725635]], [[312.3479296831873, 14.30424823725635], [312.3457425280186, 14.304047912567382], [312.34464894469096, 14.303947750222902], [312.34136817173476, 14.303647263189449], [312.34136817173476, 14.303647263189449], [312.339493428859, 14.30347555631319], [312.3364469476875, 14.303196532639442], [312.3348065224382, 14.303046289122543]], [[312.3348065224382, 14.303046289122543], [312.31293336246625, 14.301043042232875], [312.3019962079958, 14.300041418788203], [312.26918244614984, 14.297036548453521], [312.26918244614984, 14.297036548453521], [312.2504301768673, 14.295319479691104], [312.21995533713124, 14.29252924295175], [312.20354457591367, 14.291026807784467]], [[312.20354457591367, 14.291026807784467], [311.9846519403779, 14.270994338887911], [311.8751480106328, 14.260978104439374], [311.5464052874684, 14.230929401094247], [311.5464052874684, 14.230929401094247], [311.358396463066, 14.213758713468465], [311.05263975552066, 14.185856346076568], [310.88787697387363, 14.170831994404004]], [[310.88787697387363, 14.170831994404004], [310.78052289741584, 14.161046898031918], [310.72683195038945, 14.15615434984587], [310.5657034164088, 14.141476705287738], [310.5657034164088, 14.141476705287738], [310.47359242387716, 14.133089479825955], [310.32385374868244, 14.11946023845055], [310.2431952964243, 14.112121416171483]], [[310.2431952964243, 14.112121416171483], [310.19252803343284, 14.107512359849446], [310.16719129816164, 14.105207831688427], [310.0911686711596, 14.098294247205368], [310.0911686711596, 14.098294247205368], [310.0477188008184, 14.094343627500761], [309.9770997717865, 14.087923870480747], [309.93906747610225, 14.084467078239252]], [[309.93906747610225, 14.084467078239252], [309.92106752912736, 14.082831193476684], [309.9120671635956, 14.082013251095407], [309.88506449855106, 14.079559423951713], [309.88506449855106, 14.079559423951713], [309.8696333477583, 14.078157237012215], [309.8445560886226, 14.075878683235759], [309.8310521083779, 14.074651769663863]], [[309.8310521083779, 14.074651769663863], [309.8270728954717, 14.074290245691733], [309.8250832698537, 14.074109483705671], [309.8191143163364, 14.073567197747474], [309.8191143163364, 14.073567197747474], [309.8157034341231, 14.073257320057078], [309.81016067043424, 14.072753768810191], [309.7806854358767, 4.458284109700463]], [[309.7806854358767, 4.458284109700463], [308.11009955288876, 4.312016919683993], [307.2884455204805, 4.24195588198109], [304.83781939123315, 4.03448442783152], [304.8384450906457, 4.03481858295155], [303.45588500642776, 3.919823798504302], [301.2382133526692, 3.739308837627334], [300.05803340290305, 3.64491236271739]]  …  [[101.43921260223385, -0.7526151286161931], [98.3037279062643, -0.7228287831973668], [96.87267449181047, -0.7094155496599732], [92.69580618610506, -0.6688049866210428], [92.72921383725509, -0.6696798320672748], [90.47169848896368, -0.646960561040413], [87.08442948922958, -0.613520874060726], [85.35891158931848, -0.5963185092686353]], [[85.35891158931848, -0.5963185092686353], [82.29755181735958, -0.5653753416514224], [80.9182774238946, -0.5520126495376828], [76.90484742925169, -0.5117551894860543], [76.94663065721502, -0.5131871203952935], [74.78799632985773, -0.49072267637914846], [71.59109676805825, -0.45937008962534764], [69.9722444049113, -0.4434602301833591]], [[69.9722444049113, -0.4434602301833591], [67.6098939408175, -0.42019321099869866], [66.53573371853012, -0.41016720227489756], [63.40554352091409, -0.38016810934780465], [63.43219539395, -0.3811653047229765], [61.74391171855904, -0.36455644223919603], [59.219869332046486, -0.34134444161809985], [57.93655108492993, -0.32960011164793823]], [[57.93655108492993, -0.32960011164793823], [55.95849921543267, -0.31155267441958945], [55.056657562633475, -0.3038176980545551], [52.42801072333443, -0.28075912744576353], [52.44887249465464, -0.2815342838012653], [51.0300206178807, -0.2688213980823401], [48.90263701228525, -0.25114983658682216], [47.819534053929665, -0.24223796485067972]], [[47.819534053929665, -0.24223796485067972], [46.169981978523005, -0.22876166362416622], [45.41472951815257, -0.22298801456844625], [43.21168799334734, -0.2058291358678843], [43.22740301595097, -0.20638148083363042], [42.03631999945016, -0.19696033244030456], [40.24225263300838, -0.18384641825891201], [39.32664908912446, -0.17724462473671818]], [[39.32664908912446, -0.17724462473671818], [37.91378161945373, -0.16716110027263736], [37.2645050925174, -0.16284388388862683], [35.36863362087022, -0.15004381564108493], [35.380945038594106, -0.15044166490978542], [34.353868160951876, -0.14343743721624347], [32.799853932567714, -0.13367791929958353], [32.004477494265856, -0.12877171775943097]], [[32.004477494265856, -0.12877171775943097], [30.77720576695863, -0.12130325163461002], [30.21016820775815, -0.11810087498839886], [28.550509689880048, -0.10862307378776014], [28.56000006817365, -0.10889954483379101], [27.657276547556773, -0.10372849050242829], [26.281578955913677, -0.09648889699769807], [25.57372231312399, -0.09284909641332387]], [[25.57372231312399, -0.09284909641332387], [24.469837037947244, -0.08727084245150354], [23.955694197300332, -0.08487112580215983], [22.442756732023547, -0.07776855853621245], [22.450096534686523, -0.07795873080875663], [21.62024833750733, -0.07408624832283492], [20.33968081946702, -0.068610647212], [19.673563218583258, -0.06584572445081614]], [[19.673563218583258, -0.06584572445081614], [18.617011475194975, -0.06155563085036737], [18.11724118692736, -0.05969064618745137], [16.625280908669577, -0.05412550256395697], [16.63090990649627, -0.054253716688370944], [15.794493692119689, -0.051185664739651957], [14.465148294646598, -0.04670509952101016], [13.752784048149614, -0.04438161928830228]], [[13.752784048149614, -0.04438161928830228], [12.706119077145445, -0.04103540144159791], [12.189291972809812, -0.03949298116723981], [10.572850949194152, -0.03464626903954164], [10.576144718235637, -0.03470942411134387], [9.600671766290475, -0.03180388122590169], [7.88008557059758, -0.026807295531296974], [6.830383351432274, -0.02370709067020727]]], true, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}([580.175860002369, 0.5716958903006855], [561.1493266049126, 0.63425586409754], [13.752784048149614, -0.04438161928830228], [12.706119077145445, -0.04103540144159791], [12.189291972809812, -0.03949298116723981], [10.572850949194152, -0.03464626903954164], [10.576144718235637, -0.03470942411134387], [9.600671766290475, -0.03180388122590169], [7.88008557059758, -0.026807295531296974], [6.830383351432274, -0.02370709067020727], [0.014412018463275344, -5.470217292907539e-5], [578.50238990071, 0.5774604954771928], [0.024840732984794493, -0.08611045725140473], OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}(0.16666666666666666, 0.0625, 0.1875, 0.25, -0.75, -0.75, 3.75, -3.0, 0.5, 0.26895043731778423, -0.7084548104956269, 0.8658892128279884, 0.15462307371928363, 0.06184922948771345, -0.02947695035460993, 0.18500664893617022, 0.4802345261121857, -0.5337849069148937, -0.013090093085106383, 0.7861107753062541, 0.08783068783068783, 0.3006060606060606, 0.22777777777777777, 0.027777777777777776, 0.06218596218596219, 0.2938217338217338, 0.16666666666666666, 0.25, 0.5, 0.5, 0.6428571428571429, 0.875, -0.19894179894179895, 0.9115151515151515, -1.9777777777777779, -0.1111111111111111, 1.67013727013727, -0.2938217338217338, 1.892063492063492, -6.067155067155067, 7.282458282458283, -4.0195360195360195, -7.214545454545455, 20.676923076923078, -20.31142191142191, 7.14965034965035, 7.866666666666666, -18.78205128205128, 13.508547008547009, -2.3653846153846154, 2.0, -5.294871794871795, 4.534188034188034, -1.2115384615384615, -1.4924630924630924, 1.5785667324128863, 1.1958838881915805, -1.219801565955412, -7.051721611721612, 16.273203719357564, -11.978886071193763, 3.0512256973795435, 4.0, -8.384615384615385, 5.769230769230769, -1.3846153846153846))), true, 0, DiffEqBase.DEStats
Number of function 1 evaluations:                  360
Number of function 2 evaluations:                  0
Number of W matrix evaluations:                    0
Number of linear solves:                           0
Number of Jacobians created:                       0
Number of nonlinear solver iterations:             0
Number of nonlinear solver convergence failures:   0
Number of rootfind condition calls:                0
Number of accepted steps:                          29
Number of rejected steps:                          22, :Success), SciMLBase.ODESolution{Float64, 2, Vector{Vector{Float64}}, Nothing, Nothing, Vector{Float64}, Vector{Vector{Vector{Float64}}}, SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}, OwrenZen5, OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}, DiffEqBase.DEStats}([[0.0, 0.0], [0.08036770851061478, 0.00980244154799904], [0.8840262224354364, 0.10782232684426611], [8.918753954756268, 1.0875681614346162], [36.999518174347244, 4.508467095161535], [52.33091991242127, 6.374063999338755], [58.81947686585102, 7.163168343026875], [59.98999209252361, 7.305491526870946], [60.54401773902316, 7.327167896044106], [60.78336590674299, 7.334525644468636]  …  [469.91579641584644, 2.11254186537435], [503.2359610255594, 1.8335967951737626], [536.6058502505356, 1.5916149732520797], [569.9775952020642, 1.3816692834740107], [603.1979901726918, 1.1997201873883818], [636.039015000472, 1.042157286543399], [668.0982419055304, 0.9060413851266205], [698.6769695090934, 0.7891662446270232], [726.4233978028291, 0.6907102397075681], [747.1111897111397, 0.6179497677878985]], nothing, nothing, [0.0, 9.999999999999999e-5, 0.0010999999999999998, 0.011099999999999997, 0.04608233309856543, 0.06520361608459696, 0.07330077946319441, 0.07476177730611676, 0.07545446772268995, 0.0757544580703042  …  2.106207372140701, 2.5489957951813196, 3.076750145094716, 3.7068773144393017, 4.459814578394186, 5.361116788539318, 6.442245972154582, 7.743531246919073, 9.320929530095485, 11.18], [[[0.0, 0.0]], [[803.6787733693504, 98.02482731487422], [803.6782106155406, 98.02469003657959], [803.6779292384878, 98.02462139743224], [803.6770851067406, 98.02441547999082], [803.6770851067406, 98.02441547999082], [803.6766027453409, 98.02429781288059], [803.675818907452, 98.0241066038273], [803.6753968405799, 98.02400364510632]], [[803.6753968405799, 98.02400364510632], [803.669769261105, 98.02263086215994], [803.66695545659, 98.02194447068672], [803.6585139839341, 98.01988529626712], [803.6585139839341, 98.01988529626712], [803.6536902454632, 98.01870862517012], [803.6458516086958, 98.01679653463765], [803.6416307726137, 98.01576694742779]], [[803.6416307726137, 98.01576694742779], [803.58535083972, 98.00203911796248], [803.557209395119, 97.9951752032314], [803.4727791474185, 97.97458345903502], [803.4727791474185, 97.97458345903502], [803.4245293079745, 97.9628167480662], [803.3461171381136, 97.9436958427404], [803.3038920302076, 97.93339997064113]], [[803.3038920302076, 97.93339997064113], [803.1069116642334, 97.88537682033831], [803.0084033612914, 97.86136524518633], [802.7128059192869, 97.78933051973047], [802.7128059192869, 97.78933051973047], [802.5438442121365, 97.74816781946996], [802.2692055437258, 97.68127843154669], [802.1212842349606, 97.64526106881868]], [[802.1212842349606, 97.64526106881868], [802.0134623379837, 97.61901169762172], [801.9595459533288, 97.60588701202322], [801.7977750459249, 97.56651295522767], [801.7977750459249, 97.56651295522767], [801.7053198715024, 97.54401349420166], [801.5550574682846, 97.50745187003436], [801.4741352747752, 97.48776484163666]], [[801.4741352747752, 97.48776484163666], [801.4284415500889, 97.47664919383604], [801.4055937107514, 97.47109136993573], [801.3370462840937, 97.45441789823492], [801.3370462840937, 97.45441789823492], [801.2978736932214, 97.44489020012014], [801.2342141483763, 97.42940769068363], [801.1999338368564, 97.42107095483323]], [[801.1999338368564, 97.42107095483323], [801.1916865387079, 97.41906532190967], [801.1875628577977, 97.41806250544796], [801.1751916877182, 97.41505405606266], [801.1751916877182, 97.41505405606266], [801.1681223619048, 97.41333494212817], [801.1566345744156, 97.41054138198473], [801.1504487744614, 97.40903715729209]], [[801.1504487744614, 97.40903715729209], [800.7394476499769, 25.10335399737285], [800.5096165294475, 25.10554966772402], [799.8206477169527, 24.86535690599706], [799.8204807237645, 25.359814624870808], [799.4274973489482, 24.772035753223776], [798.7894405924369, 24.783532431145545], [798.4463624301756, 24.65255667739642]], [[798.4463624301756, 24.65255667739642], [798.2483610526788, 24.610479175986754], [798.149435661869, 24.589482416794766], [797.8527414437075, 24.526533662057957], [797.8527416053035, 24.5265338728734], [797.6833062326737, 24.490619237549282], [797.4081357002492, 24.432345449787178], [797.2600497625308, 24.401011832225308]]  …  [[97.53664409541709, -1.0114152189305134], [94.54151459391868, -0.9545457714627279], [93.17258500089105, -0.9302505531996883], [89.17633457205214, -0.858087586391048], [89.2071818049789, -0.8605286652260706], [87.04636323568589, -0.8208767989647054], [83.79962333342766, -0.7659868561327903], [82.14465789787408, -0.738374387001616]], [[82.14465789787408, -0.738374387001616], [79.61018341536895, -0.6965326349008785], [78.45002057852444, -0.678659911813724], [75.06321879748545, -0.6256441589506646], [75.08822385988343, -0.6274044517262234], [73.25637734648504, -0.5983277531031077], [70.49971807171404, -0.5580566852536634], [69.0936682133708, -0.537816676722618]], [[69.0936682133708, -0.537816676722618], [66.94125242466271, -0.507192405446977], [65.95427925343769, -0.49410566074857554], [63.07290447072744, -0.45533577755209365], [63.093131186348785, -0.4565905130002091], [61.533991084022624, -0.4353668683726429], [59.183577578685764, -0.40593359428574943], [57.983774739719934, -0.3911514556796634]], [[57.983774739719934, -0.3911514556796634], [56.14290236930333, -0.36875722302470015], [55.29726041936174, -0.3591826913686658], [52.82816850935914, -0.33085290701011555], [52.84459710402018, -0.33174486207686776], [51.50779143779337, -0.3162655575385767], [49.488636761868925, -0.29476690793686894], [48.45690812262996, -0.28397725322124345]], [[48.45690812262996, -0.28397725322124345], [46.8715721195563, -0.2676259927593464], [46.14170777220305, -0.26062946662102054], [44.00986146964108, -0.23995348536423897], [44.023174701892465, -0.2405827118176112], [42.86784681234456, -0.22930779693929979], [41.11837778536207, -0.21361603392590492], [40.22311510433781, -0.2057452895895932]], [[40.22311510433781, -0.2057452895895932], [38.84342503265327, -0.193799616410734], [38.20640221307067, -0.18868254104019955], [36.344060388784236, -0.1735791024467128], [36.35482175057128, -0.17401993381805506], [35.34376962898223, -0.16580066021875106], [33.807215671118016, -0.1543291506651314], [33.01895749653353, -0.14857711518682862]], [[33.01895749653353, -0.14857711518682862], [31.79917258524955, -0.13982889415284896], [31.23357874290183, -0.13607471846857083], [29.57659593105183, -0.12500439573257824], [29.58523518693531, -0.1253099173080358], [28.682492781305665, -0.11929646179938319], [27.30238076053091, -0.11086474561853948], [26.591078414828658, -0.10663438543749558]], [[26.591078414828658, -0.10663438543749558], [25.482063479481653, -0.10017128295799026], [24.964174413352385, -0.09738783215771157], [23.43939149377477, -0.08917616003283002], [23.446256513030242, -0.0893849367938098], [22.6090872878902, -0.08492468895525257], [21.314779177657627, -0.07861102088663707], [20.64102326597665, -0.07542964355241472]], [[20.64102326597665, -0.07542964355241472], [19.573097102048735, -0.0705082776525808], [19.067386344201605, -0.06836817092270747], [17.55869729866369, -0.06200762173477855], [17.564099574114806, -0.06214812296163], [16.719089184411384, -0.058658703974845156], [15.377496626769037, -0.05357581560876886], [14.660153552835247, -0.05095435443877107]], [[14.660153552835247, -0.05095435443877107], [13.523734799560911, -0.046899229249339244], [12.964624244088816, -0.04505196667387745], [11.218219773591564, -0.039281120377892276], [11.22223273992484, -0.03936658029274125], [10.17019498000164, -0.03593339847253327], [8.317086452164471, -0.030101268291913202], [7.1855563961949125, -0.026502303954291675]]], SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [0.0, 0.0], (0.0, 11.18), Any[GasChromatographySimulator.Column(11.18, 0.000104, [0.000104], 1.04e-7, [1.04e-7], "FS5ms", "H2"), GasChromatographySimulator.Program{GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}}([0.0, 60.0, 1680.0, 60.0, 360.0, 60.0], [40.0, 40.0, 180.0, 180.0, 300.0, 300.0], [411564.0, 411564.0, 411564.0, 411564.0, 411564.0, 411564.0], [101300.0, 101300.0, 101300.0, 101300.0, 101300.0, 101300.0], GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}([0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0]), [0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0], 11181×6 extrapolate(interpolate((0.0:0.001:11.18,::Vector{Float64}), ::Matrix{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
   ⋮                                       ⋮
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0), GasChromatographySimulator.Substance("C13", "629-50-5", 444.46999999999997, 35.93, 125.62, 0.001, "Leppert2020b, alkane, alkanes", 0.00010393999972322901, 0.0, 0.0), GasChromatographySimulator.Options(OwrenZen5(), 1.0e-6, 0.001, "inlet", true, true, "Blumberg", "Pressure")], Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}(), SciMLBase.StandardODEProblem()), OwrenZen5(), OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [[0.0, 0.0], [0.08036770851061478, 0.00980244154799904], [0.8840262224354364, 0.10782232684426611], [8.918753954756268, 1.0875681614346162], [36.999518174347244, 4.508467095161535], [52.33091991242127, 6.374063999338755], [58.81947686585102, 7.163168343026875], [59.98999209252361, 7.305491526870946], [60.54401773902316, 7.327167896044106], [60.78336590674299, 7.334525644468636]  …  [469.91579641584644, 2.11254186537435], [503.2359610255594, 1.8335967951737626], [536.6058502505356, 1.5916149732520797], [569.9775952020642, 1.3816692834740107], [603.1979901726918, 1.1997201873883818], [636.039015000472, 1.042157286543399], [668.0982419055304, 0.9060413851266205], [698.6769695090934, 0.7891662446270232], [726.4233978028291, 0.6907102397075681], [747.1111897111397, 0.6179497677878985]], [0.0, 9.999999999999999e-5, 0.0010999999999999998, 0.011099999999999997, 0.04608233309856543, 0.06520361608459696, 0.07330077946319441, 0.07476177730611676, 0.07545446772268995, 0.0757544580703042  …  2.106207372140701, 2.5489957951813196, 3.076750145094716, 3.7068773144393017, 4.459814578394186, 5.361116788539318, 6.442245972154582, 7.743531246919073, 9.320929530095485, 11.18], [[[0.0, 0.0]], [[803.6787733693504, 98.02482731487422], [803.6782106155406, 98.02469003657959], [803.6779292384878, 98.02462139743224], [803.6770851067406, 98.02441547999082], [803.6770851067406, 98.02441547999082], [803.6766027453409, 98.02429781288059], [803.675818907452, 98.0241066038273], [803.6753968405799, 98.02400364510632]], [[803.6753968405799, 98.02400364510632], [803.669769261105, 98.02263086215994], [803.66695545659, 98.02194447068672], [803.6585139839341, 98.01988529626712], [803.6585139839341, 98.01988529626712], [803.6536902454632, 98.01870862517012], [803.6458516086958, 98.01679653463765], [803.6416307726137, 98.01576694742779]], [[803.6416307726137, 98.01576694742779], [803.58535083972, 98.00203911796248], [803.557209395119, 97.9951752032314], [803.4727791474185, 97.97458345903502], [803.4727791474185, 97.97458345903502], [803.4245293079745, 97.9628167480662], [803.3461171381136, 97.9436958427404], [803.3038920302076, 97.93339997064113]], [[803.3038920302076, 97.93339997064113], [803.1069116642334, 97.88537682033831], [803.0084033612914, 97.86136524518633], [802.7128059192869, 97.78933051973047], [802.7128059192869, 97.78933051973047], [802.5438442121365, 97.74816781946996], [802.2692055437258, 97.68127843154669], [802.1212842349606, 97.64526106881868]], [[802.1212842349606, 97.64526106881868], [802.0134623379837, 97.61901169762172], [801.9595459533288, 97.60588701202322], [801.7977750459249, 97.56651295522767], [801.7977750459249, 97.56651295522767], [801.7053198715024, 97.54401349420166], [801.5550574682846, 97.50745187003436], [801.4741352747752, 97.48776484163666]], [[801.4741352747752, 97.48776484163666], [801.4284415500889, 97.47664919383604], [801.4055937107514, 97.47109136993573], [801.3370462840937, 97.45441789823492], [801.3370462840937, 97.45441789823492], [801.2978736932214, 97.44489020012014], [801.2342141483763, 97.42940769068363], [801.1999338368564, 97.42107095483323]], [[801.1999338368564, 97.42107095483323], [801.1916865387079, 97.41906532190967], [801.1875628577977, 97.41806250544796], [801.1751916877182, 97.41505405606266], [801.1751916877182, 97.41505405606266], [801.1681223619048, 97.41333494212817], [801.1566345744156, 97.41054138198473], [801.1504487744614, 97.40903715729209]], [[801.1504487744614, 97.40903715729209], [800.7394476499769, 25.10335399737285], [800.5096165294475, 25.10554966772402], [799.8206477169527, 24.86535690599706], [799.8204807237645, 25.359814624870808], [799.4274973489482, 24.772035753223776], [798.7894405924369, 24.783532431145545], [798.4463624301756, 24.65255667739642]], [[798.4463624301756, 24.65255667739642], [798.2483610526788, 24.610479175986754], [798.149435661869, 24.589482416794766], [797.8527414437075, 24.526533662057957], [797.8527416053035, 24.5265338728734], [797.6833062326737, 24.490619237549282], [797.4081357002492, 24.432345449787178], [797.2600497625308, 24.401011832225308]]  …  [[97.53664409541709, -1.0114152189305134], [94.54151459391868, -0.9545457714627279], [93.17258500089105, -0.9302505531996883], [89.17633457205214, -0.858087586391048], [89.2071818049789, -0.8605286652260706], [87.04636323568589, -0.8208767989647054], [83.79962333342766, -0.7659868561327903], [82.14465789787408, -0.738374387001616]], [[82.14465789787408, -0.738374387001616], [79.61018341536895, -0.6965326349008785], [78.45002057852444, -0.678659911813724], [75.06321879748545, -0.6256441589506646], [75.08822385988343, -0.6274044517262234], [73.25637734648504, -0.5983277531031077], [70.49971807171404, -0.5580566852536634], [69.0936682133708, -0.537816676722618]], [[69.0936682133708, -0.537816676722618], [66.94125242466271, -0.507192405446977], [65.95427925343769, -0.49410566074857554], [63.07290447072744, -0.45533577755209365], [63.093131186348785, -0.4565905130002091], [61.533991084022624, -0.4353668683726429], [59.183577578685764, -0.40593359428574943], [57.983774739719934, -0.3911514556796634]], [[57.983774739719934, -0.3911514556796634], [56.14290236930333, -0.36875722302470015], [55.29726041936174, -0.3591826913686658], [52.82816850935914, -0.33085290701011555], [52.84459710402018, -0.33174486207686776], [51.50779143779337, -0.3162655575385767], [49.488636761868925, -0.29476690793686894], [48.45690812262996, -0.28397725322124345]], [[48.45690812262996, -0.28397725322124345], [46.8715721195563, -0.2676259927593464], [46.14170777220305, -0.26062946662102054], [44.00986146964108, -0.23995348536423897], [44.023174701892465, -0.2405827118176112], [42.86784681234456, -0.22930779693929979], [41.11837778536207, -0.21361603392590492], [40.22311510433781, -0.2057452895895932]], [[40.22311510433781, -0.2057452895895932], [38.84342503265327, -0.193799616410734], [38.20640221307067, -0.18868254104019955], [36.344060388784236, -0.1735791024467128], [36.35482175057128, -0.17401993381805506], [35.34376962898223, -0.16580066021875106], [33.807215671118016, -0.1543291506651314], [33.01895749653353, -0.14857711518682862]], [[33.01895749653353, -0.14857711518682862], [31.79917258524955, -0.13982889415284896], [31.23357874290183, -0.13607471846857083], [29.57659593105183, -0.12500439573257824], [29.58523518693531, -0.1253099173080358], [28.682492781305665, -0.11929646179938319], [27.30238076053091, -0.11086474561853948], [26.591078414828658, -0.10663438543749558]], [[26.591078414828658, -0.10663438543749558], [25.482063479481653, -0.10017128295799026], [24.964174413352385, -0.09738783215771157], [23.43939149377477, -0.08917616003283002], [23.446256513030242, -0.0893849367938098], [22.6090872878902, -0.08492468895525257], [21.314779177657627, -0.07861102088663707], [20.64102326597665, -0.07542964355241472]], [[20.64102326597665, -0.07542964355241472], [19.573097102048735, -0.0705082776525808], [19.067386344201605, -0.06836817092270747], [17.55869729866369, -0.06200762173477855], [17.564099574114806, -0.06214812296163], [16.719089184411384, -0.058658703974845156], [15.377496626769037, -0.05357581560876886], [14.660153552835247, -0.05095435443877107]], [[14.660153552835247, -0.05095435443877107], [13.523734799560911, -0.046899229249339244], [12.964624244088816, -0.04505196667387745], [11.218219773591564, -0.039281120377892276], [11.22223273992484, -0.03936658029274125], [10.17019498000164, -0.03593339847253327], [8.317086452164471, -0.030101268291913202], [7.1855563961949125, -0.026502303954291675]]], true, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}([747.1111897111397, 0.6179497677878985], [726.4233978028291, 0.6907102397075681], [14.660153552835247, -0.05095435443877107], [13.523734799560911, -0.046899229249339244], [12.964624244088816, -0.04505196667387745], [11.218219773591564, -0.039281120377892276], [11.22223273992484, -0.03936658029274125], [10.17019498000164, -0.03593339847253327], [8.317086452164471, -0.030101268291913202], [7.1855563961949125, -0.026502303954291675], [0.016275245906806853, -6.415473378013062e-5], [745.3037230189085, 0.6245740857112563], [0.021784206081685596, -0.09274798911066157], OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}(0.16666666666666666, 0.0625, 0.1875, 0.25, -0.75, -0.75, 3.75, -3.0, 0.5, 0.26895043731778423, -0.7084548104956269, 0.8658892128279884, 0.15462307371928363, 0.06184922948771345, -0.02947695035460993, 0.18500664893617022, 0.4802345261121857, -0.5337849069148937, -0.013090093085106383, 0.7861107753062541, 0.08783068783068783, 0.3006060606060606, 0.22777777777777777, 0.027777777777777776, 0.06218596218596219, 0.2938217338217338, 0.16666666666666666, 0.25, 0.5, 0.5, 0.6428571428571429, 0.875, -0.19894179894179895, 0.9115151515151515, -1.9777777777777779, -0.1111111111111111, 1.67013727013727, -0.2938217338217338, 1.892063492063492, -6.067155067155067, 7.282458282458283, -4.0195360195360195, -7.214545454545455, 20.676923076923078, -20.31142191142191, 7.14965034965035, 7.866666666666666, -18.78205128205128, 13.508547008547009, -2.3653846153846154, 2.0, -5.294871794871795, 4.534188034188034, -1.2115384615384615, -1.4924630924630924, 1.5785667324128863, 1.1958838881915805, -1.219801565955412, -7.051721611721612, 16.273203719357564, -11.978886071193763, 3.0512256973795435, 4.0, -8.384615384615385, 5.769230769230769, -1.3846153846153846))), true, 0, DiffEqBase.DEStats
Number of function 1 evaluations:                  437
Number of function 2 evaluations:                  0
Number of W matrix evaluations:                    0
Number of linear solves:                           0
Number of Jacobians created:                       0
Number of nonlinear solver iterations:             0
Number of nonlinear solver convergence failures:   0
Number of rootfind condition calls:                0
Number of accepted steps:                          36
Number of rejected steps:                          26, :Success), SciMLBase.ODESolution{Float64, 2, Vector{Vector{Float64}}, Nothing, Nothing, Vector{Float64}, Vector{Vector{Vector{Float64}}}, SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}, OwrenZen5, OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}, DiffEqBase.DEStats}([[0.0, 0.0], [0.20167300074609165, 0.063653972258059], [2.2183564060836614, 0.700164277250428], [22.380529522428837, 7.0623255683517705], [53.26591100077479, 16.80299962726043], [58.26734819909565, 18.379768576596092], [59.97627437388596, 18.918492269623027], [60.478128322693294, 18.961919396327648], [60.6958463322554, 18.97573744337489], [62.8559419051708, 19.105498082984575]  …  [640.5437390811994, 2.097547649154452], [673.8007068641675, 1.8191532328244597], [707.2468127805414, 1.578198264210008], [740.7623889011894, 1.3696378196995223], [774.1530889637656, 1.189176012880195], [807.1091600375646, 1.0331921318716113], [839.1147897892652, 0.8987905495776332], [869.251768572074, 0.7840545054512479], [895.6602989142884, 0.6891490964325981], [907.1189845962977, 0.6474308598301796]], nothing, nothing, [0.0, 9.999999999999999e-5, 0.0010999999999999998, 0.011099999999999997, 0.02642663918001458, 0.02890949540190982, 0.029757914658447546, 0.030007450181802252, 0.03011596228847866, 0.031201083355242767  …  2.3883116000803444, 2.855850777225353, 3.4135531477732344, 4.079552195000623, 4.875925340753915, 5.8298986658280025, 6.975534971092545, 8.357136982666773, 10.04274261170167, 11.18], [[[0.0, 0.0]], [[2016.7342439523236, 636.5423969067945], [2016.7328317900065, 636.5415054647273], [2016.732125708476, 636.5410597436933], [2016.7300074623895, 636.5397225805834], [2016.7300074623895, 636.5397225805834], [2016.7287970350778, 636.5389584873918], [2016.7268300891233, 636.5377168359406], [2016.725770963584, 636.5370482543901]], [[2016.725770963584, 636.5370482543901], [2016.7116492365783, 636.5281338337168], [2016.7045883359926, 636.5236766233796], [2016.6834054859057, 636.5103049923692], [2016.6834054859057, 636.5103049923692], [2016.6713009002426, 636.5026640603631], [2016.6516307935797, 636.4902475458534], [2016.641039118215, 636.4835617303479]], [[2016.641039118215, 636.4835617303479], [2016.4998114640002, 636.3944175236112], [2016.4291939276143, 636.3498454202338], [2016.2173264783373, 636.2161291101373], [2016.2173264783373, 636.2161291101373], [2016.0962493680524, 636.1397197900772], [2015.8994835539784, 636.0155546449789], [2015.7935247755545, 635.9486964899172]], [[2015.7935247755545, 635.9486964899172], [2015.576975191105, 635.812068380762], [2015.4686916737826, 635.7437543261797], [2015.143806210203, 635.5388121624327], [2015.143806210203, 635.5388121624327], [2014.9581338547484, 635.4217023545774], [2014.6563797810581, 635.2313989168127], [2014.493878096326, 635.128927834939]], [[2014.493878096326, 635.128927834939], [2014.458776849609, 635.1067946101049], [2014.441225996888, 635.0957279976877], [2014.3885725212288, 635.062528160436], [2014.3885725212288, 635.062528160436], [2014.3584842029156, 635.0435568248638], [2014.3095897270905, 635.0127284045591], [2014.2832614408171, 634.9961284859336]], [[2014.2832614408171, 634.9961284859336], [2014.271265773694, 634.988565319773], [2014.2652679133435, 634.984783736693], [2014.2472742251314, 634.9734389874523], [2014.2472742251314, 634.9734389874523], [2014.2369920454116, 634.9669562736005], [2014.2202833914191, 634.9564218635913], [2014.211286366474, 634.9507494889708]], [[2014.211286366474, 634.9507494889708], [2013.4091932490464, 130.6142629255532], [2012.8510826880438, 130.6800138882537], [2011.178298433632, 129.2056819830621], [2011.1772548671079, 132.5543847034943], [2010.2236422744572, 128.6603846843272], [2008.6740134388629, 128.8786803207165], [2007.8409282750245, 128.06697522091326]], [[2007.8409282750245, 128.06697522091326], [2007.3581023210077, 127.8244475428379], [2007.1168676968755, 127.70342297323663], [2006.3933560357, 127.34058667049874], [2006.3933564102483, 127.34058784520266], [2005.980167099297, 127.133572767322], [2005.3091167472128, 126.79767236610553], [2004.9479774288784, 126.61705723464206]], [[2004.9479774288784, 126.61705723464206], [2000.1400889435163, 124.2179233323281], [1997.753825538712, 123.04190506791952], [1990.6136664269322, 119.5360943234686], [1990.6140375286375, 119.53725613428037], [1986.5576682702747, 117.56360817270382], [1980.003683809619, 114.40528565693461], [1976.4933620454233, 112.72810834758855]]  …  [[91.4953312529707, -0.9624089461513261], [88.78546864889248, -0.9073773714937867], [87.54160078917057, -0.883861841440045], [83.90751912901892, -0.8142526184850452], [83.9327778720471, -0.8164953727579891], [81.9646748260533, -0.7784183918550001], [78.99503118842726, -0.7256268561413203], [77.47825578488944, -0.6991254730620279]], [[77.47825578488944, -0.6991254730620279], [75.1537545256588, -0.659060264259297], [74.08571131142422, -0.6419326524390331], [70.96560615393196, -0.5912710462542737], [70.98658262442322, -0.5928735711667203], [69.2965852276502, -0.5651937501567258], [66.74401874571055, -0.5267766513331544], [65.43972239513067, -0.5074993627073973]], [[65.43972239513067, -0.5074993627073973], [63.43882447714433, -0.4783409877334973], [62.518374511294724, -0.46586935745633523], [59.82950819347442, -0.4290101246861832], [59.8468944502554, -0.4301510528669386], [58.39007036488661, -0.4100387014596948], [56.18692177266777, -0.38208866670833036], [55.06048590926702, -0.36806974285067223]], [[55.06048590926702, -0.36806974285067223], [53.32982232472355, -0.34684688261256236], [52.53249037838102, -0.33776356440208366], [50.20298586762637, -0.3109427143150873], [50.21735637511593, -0.3117516144341548], [48.95454973343927, -0.2971382467783431], [47.041576680739176, -0.27679790395220033], [46.06257179452533, -0.2666002554817953]], [[46.06257179452533, -0.2666002554817953], [44.55540152600934, -0.25114566793385273], [43.85961478381969, -0.2445254379936359], [41.82583764284928, -0.22499671186005862], [41.837659257317966, -0.225566719857292], [40.73397494326923, -0.21494400380807185], [39.057873919888856, -0.20012672180730634], [38.1986998010175, -0.19270070087289076]], [[38.1986998010175, -0.19270070087289076], [36.87193700893277, -0.18142761350618086], [36.2575938708226, -0.17659245610791588], [34.459718453814574, -0.16234302037374915], [34.469377025892676, -0.1627413526717534], [33.49157885185383, -0.15500368141648754], [32.00068395449234, -0.1441762372076466], [31.23416487921308, -0.13874965721352606]], [[31.23416487921308, -0.13874965721352606], [30.04448914026921, -0.13048807718415406], [29.490952334518077, -0.12693670800244305], [27.8663809590052, -0.11647544684605132], [27.87419361041466, -0.11675051801503174], [26.98654900485639, -0.11107681315392734], [25.62336860078709, -0.10309200146135492], [24.918290623857587, -0.09908388301819357]], [[24.918290623857587, -0.09908388301819357], [23.813358932381853, -0.09294300003660685], [23.2947253747749, -0.09029005363998407], [21.76180517189295, -0.08245911598641285], [21.768040241275465, -0.0826460378355861], [20.92139244137227, -0.07838976931462928], [19.601686636639062, -0.07231763007864167], [18.909513783095306, -0.06924445907604396]], [[18.909513783095306, -0.06924445907604396], [17.797129228527144, -0.06443396560590635], [17.264910797140466, -0.06232276470277357], [15.65927497285462, -0.05599288114022659], [15.664261452919618, -0.05611899348154771], [14.749445591684362, -0.05259888941050287], [13.263665052660775, -0.04731900234803437], [12.448998005165429, -0.04451533184358608]], [[12.448998005165429, -0.04451533184358608], [11.698297168991473, -0.041970490083079806], [11.32012239245465, -0.040735191080551535], [10.136247133405096, -0.036852585187322616], [10.137024722258433, -0.03686865406059994], [9.423056012506807, -0.03453766556321298], [8.178563482492823, -0.030501664937160586], [7.4454965824389285, -0.028101608277525694]]], SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [0.0, 0.0], (0.0, 11.18), Any[GasChromatographySimulator.Column(11.18, 0.000104, [0.000104], 1.04e-7, [1.04e-7], "FS5ms", "H2"), GasChromatographySimulator.Program{GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}}([0.0, 60.0, 1680.0, 60.0, 360.0, 60.0], [40.0, 40.0, 180.0, 180.0, 300.0, 300.0], [411564.0, 411564.0, 411564.0, 411564.0, 411564.0, 411564.0], [101300.0, 101300.0, 101300.0, 101300.0, 101300.0, 101300.0], GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}([0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0]), [0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0], 11181×6 extrapolate(interpolate((0.0:0.001:11.18,::Vector{Float64}), ::Matrix{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
   ⋮                                       ⋮
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0), GasChromatographySimulator.Substance("C14", "629-59-4", 459.98, 36.76, 126.76, 0.001, "Leppert2020b, alkane, alkanes", 0.00010002700149772162, 0.0, 0.0), GasChromatographySimulator.Options(OwrenZen5(), 1.0e-6, 0.001, "inlet", true, true, "Blumberg", "Pressure")], Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}(), SciMLBase.StandardODEProblem()), OwrenZen5(), OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [[0.0, 0.0], [0.20167300074609165, 0.063653972258059], [2.2183564060836614, 0.700164277250428], [22.380529522428837, 7.0623255683517705], [53.26591100077479, 16.80299962726043], [58.26734819909565, 18.379768576596092], [59.97627437388596, 18.918492269623027], [60.478128322693294, 18.961919396327648], [60.6958463322554, 18.97573744337489], [62.8559419051708, 19.105498082984575]  …  [640.5437390811994, 2.097547649154452], [673.8007068641675, 1.8191532328244597], [707.2468127805414, 1.578198264210008], [740.7623889011894, 1.3696378196995223], [774.1530889637656, 1.189176012880195], [807.1091600375646, 1.0331921318716113], [839.1147897892652, 0.8987905495776332], [869.251768572074, 0.7840545054512479], [895.6602989142884, 0.6891490964325981], [907.1189845962977, 0.6474308598301796]], [0.0, 9.999999999999999e-5, 0.0010999999999999998, 0.011099999999999997, 0.02642663918001458, 0.02890949540190982, 0.029757914658447546, 0.030007450181802252, 0.03011596228847866, 0.031201083355242767  …  2.3883116000803444, 2.855850777225353, 3.4135531477732344, 4.079552195000623, 4.875925340753915, 5.8298986658280025, 6.975534971092545, 8.357136982666773, 10.04274261170167, 11.18], [[[0.0, 0.0]], [[2016.7342439523236, 636.5423969067945], [2016.7328317900065, 636.5415054647273], [2016.732125708476, 636.5410597436933], [2016.7300074623895, 636.5397225805834], [2016.7300074623895, 636.5397225805834], [2016.7287970350778, 636.5389584873918], [2016.7268300891233, 636.5377168359406], [2016.725770963584, 636.5370482543901]], [[2016.725770963584, 636.5370482543901], [2016.7116492365783, 636.5281338337168], [2016.7045883359926, 636.5236766233796], [2016.6834054859057, 636.5103049923692], [2016.6834054859057, 636.5103049923692], [2016.6713009002426, 636.5026640603631], [2016.6516307935797, 636.4902475458534], [2016.641039118215, 636.4835617303479]], [[2016.641039118215, 636.4835617303479], [2016.4998114640002, 636.3944175236112], [2016.4291939276143, 636.3498454202338], [2016.2173264783373, 636.2161291101373], [2016.2173264783373, 636.2161291101373], [2016.0962493680524, 636.1397197900772], [2015.8994835539784, 636.0155546449789], [2015.7935247755545, 635.9486964899172]], [[2015.7935247755545, 635.9486964899172], [2015.576975191105, 635.812068380762], [2015.4686916737826, 635.7437543261797], [2015.143806210203, 635.5388121624327], [2015.143806210203, 635.5388121624327], [2014.9581338547484, 635.4217023545774], [2014.6563797810581, 635.2313989168127], [2014.493878096326, 635.128927834939]], [[2014.493878096326, 635.128927834939], [2014.458776849609, 635.1067946101049], [2014.441225996888, 635.0957279976877], [2014.3885725212288, 635.062528160436], [2014.3885725212288, 635.062528160436], [2014.3584842029156, 635.0435568248638], [2014.3095897270905, 635.0127284045591], [2014.2832614408171, 634.9961284859336]], [[2014.2832614408171, 634.9961284859336], [2014.271265773694, 634.988565319773], [2014.2652679133435, 634.984783736693], [2014.2472742251314, 634.9734389874523], [2014.2472742251314, 634.9734389874523], [2014.2369920454116, 634.9669562736005], [2014.2202833914191, 634.9564218635913], [2014.211286366474, 634.9507494889708]], [[2014.211286366474, 634.9507494889708], [2013.4091932490464, 130.6142629255532], [2012.8510826880438, 130.6800138882537], [2011.178298433632, 129.2056819830621], [2011.1772548671079, 132.5543847034943], [2010.2236422744572, 128.6603846843272], [2008.6740134388629, 128.8786803207165], [2007.8409282750245, 128.06697522091326]], [[2007.8409282750245, 128.06697522091326], [2007.3581023210077, 127.8244475428379], [2007.1168676968755, 127.70342297323663], [2006.3933560357, 127.34058667049874], [2006.3933564102483, 127.34058784520266], [2005.980167099297, 127.133572767322], [2005.3091167472128, 126.79767236610553], [2004.9479774288784, 126.61705723464206]], [[2004.9479774288784, 126.61705723464206], [2000.1400889435163, 124.2179233323281], [1997.753825538712, 123.04190506791952], [1990.6136664269322, 119.5360943234686], [1990.6140375286375, 119.53725613428037], [1986.5576682702747, 117.56360817270382], [1980.003683809619, 114.40528565693461], [1976.4933620454233, 112.72810834758855]]  …  [[91.4953312529707, -0.9624089461513261], [88.78546864889248, -0.9073773714937867], [87.54160078917057, -0.883861841440045], [83.90751912901892, -0.8142526184850452], [83.9327778720471, -0.8164953727579891], [81.9646748260533, -0.7784183918550001], [78.99503118842726, -0.7256268561413203], [77.47825578488944, -0.6991254730620279]], [[77.47825578488944, -0.6991254730620279], [75.1537545256588, -0.659060264259297], [74.08571131142422, -0.6419326524390331], [70.96560615393196, -0.5912710462542737], [70.98658262442322, -0.5928735711667203], [69.2965852276502, -0.5651937501567258], [66.74401874571055, -0.5267766513331544], [65.43972239513067, -0.5074993627073973]], [[65.43972239513067, -0.5074993627073973], [63.43882447714433, -0.4783409877334973], [62.518374511294724, -0.46586935745633523], [59.82950819347442, -0.4290101246861832], [59.8468944502554, -0.4301510528669386], [58.39007036488661, -0.4100387014596948], [56.18692177266777, -0.38208866670833036], [55.06048590926702, -0.36806974285067223]], [[55.06048590926702, -0.36806974285067223], [53.32982232472355, -0.34684688261256236], [52.53249037838102, -0.33776356440208366], [50.20298586762637, -0.3109427143150873], [50.21735637511593, -0.3117516144341548], [48.95454973343927, -0.2971382467783431], [47.041576680739176, -0.27679790395220033], [46.06257179452533, -0.2666002554817953]], [[46.06257179452533, -0.2666002554817953], [44.55540152600934, -0.25114566793385273], [43.85961478381969, -0.2445254379936359], [41.82583764284928, -0.22499671186005862], [41.837659257317966, -0.225566719857292], [40.73397494326923, -0.21494400380807185], [39.057873919888856, -0.20012672180730634], [38.1986998010175, -0.19270070087289076]], [[38.1986998010175, -0.19270070087289076], [36.87193700893277, -0.18142761350618086], [36.2575938708226, -0.17659245610791588], [34.459718453814574, -0.16234302037374915], [34.469377025892676, -0.1627413526717534], [33.49157885185383, -0.15500368141648754], [32.00068395449234, -0.1441762372076466], [31.23416487921308, -0.13874965721352606]], [[31.23416487921308, -0.13874965721352606], [30.04448914026921, -0.13048807718415406], [29.490952334518077, -0.12693670800244305], [27.8663809590052, -0.11647544684605132], [27.87419361041466, -0.11675051801503174], [26.98654900485639, -0.11107681315392734], [25.62336860078709, -0.10309200146135492], [24.918290623857587, -0.09908388301819357]], [[24.918290623857587, -0.09908388301819357], [23.813358932381853, -0.09294300003660685], [23.2947253747749, -0.09029005363998407], [21.76180517189295, -0.08245911598641285], [21.768040241275465, -0.0826460378355861], [20.92139244137227, -0.07838976931462928], [19.601686636639062, -0.07231763007864167], [18.909513783095306, -0.06924445907604396]], [[18.909513783095306, -0.06924445907604396], [17.797129228527144, -0.06443396560590635], [17.264910797140466, -0.06232276470277357], [15.65927497285462, -0.05599288114022659], [15.664261452919618, -0.05611899348154771], [14.749445591684362, -0.05259888941050287], [13.263665052660775, -0.04731900234803437], [12.448998005165429, -0.04451533184358608]], [[12.448998005165429, -0.04451533184358608], [11.698297168991473, -0.041970490083079806], [11.32012239245465, -0.040735191080551535], [10.136247133405096, -0.036852585187322616], [10.137024722258433, -0.03686865406059994], [9.423056012506807, -0.03453766556321298], [8.178563482492823, -0.030501664937160586], [7.4454965824389285, -0.028101608277525694]]], true, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}([907.1189845962977, 0.6474308598301796], [895.6602989142884, 0.6891490964325981], [12.448998005165429, -0.04451533184358608], [11.698297168991473, -0.041970490083079806], [11.32012239245465, -0.040735191080551535], [10.136247133405096, -0.036852585187322616], [10.137024722258433, -0.03686865406059994], [9.423056012506807, -0.03453766556321298], [8.178563482492823, -0.030501664937160586], [7.4454965824389285, -0.028101608277525694], [0.0034276383568229655, -1.436688355301928e-5], [906.0069681601369, 0.6516064651713324], [0.0037785942488615686, -0.02081707217655162], OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}(0.16666666666666666, 0.0625, 0.1875, 0.25, -0.75, -0.75, 3.75, -3.0, 0.5, 0.26895043731778423, -0.7084548104956269, 0.8658892128279884, 0.15462307371928363, 0.06184922948771345, -0.02947695035460993, 0.18500664893617022, 0.4802345261121857, -0.5337849069148937, -0.013090093085106383, 0.7861107753062541, 0.08783068783068783, 0.3006060606060606, 0.22777777777777777, 0.027777777777777776, 0.06218596218596219, 0.2938217338217338, 0.16666666666666666, 0.25, 0.5, 0.5, 0.6428571428571429, 0.875, -0.19894179894179895, 0.9115151515151515, -1.9777777777777779, -0.1111111111111111, 1.67013727013727, -0.2938217338217338, 1.892063492063492, -6.067155067155067, 7.282458282458283, -4.0195360195360195, -7.214545454545455, 20.676923076923078, -20.31142191142191, 7.14965034965035, 7.866666666666666, -18.78205128205128, 13.508547008547009, -2.3653846153846154, 2.0, -5.294871794871795, 4.534188034188034, -1.2115384615384615, -1.4924630924630924, 1.5785667324128863, 1.1958838881915805, -1.219801565955412, -7.051721611721612, 16.273203719357564, -11.978886071193763, 3.0512256973795435, 4.0, -8.384615384615385, 5.769230769230769, -1.3846153846153846))), true, 0, DiffEqBase.DEStats
Number of function 1 evaluations:                  465
Number of function 2 evaluations:                  0
Number of W matrix evaluations:                    0
Number of linear solves:                           0
Number of Jacobians created:                       0
Number of nonlinear solver iterations:             0
Number of nonlinear solver convergence failures:   0
Number of rootfind condition calls:                0
Number of accepted steps:                          41
Number of rejected steps:                          25, :Success), SciMLBase.ODESolution{Float64, 2, Vector{Vector{Float64}}, Nothing, Nothing, Vector{Float64}, Vector{Vector{Vector{Float64}}}, SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}, OwrenZen5, OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}, DiffEqBase.DEStats}([[0.0, 0.0], [0.5118766854272803, 0.4219575619756654], [5.630525256437843, 4.641338174675174], [56.805180800932064, 46.81564359595516], [59.615807759047144, 49.13143747552918], [60.02721907677394, 49.47041209211274], [64.08188576665707, 49.91605812177886], [72.49442963807763, 50.48957592229632], [82.9002941253958, 50.643301853655736], [95.27754165053068, 50.19276577527522]  …  [779.0813321257494, 2.2604533714317525], [812.651455348656, 1.9600405936908976], [846.4977517608771, 1.700162907864467], [880.5064353658115, 1.4753155838233665], [914.5019585510814, 1.280789638371047], [948.2096971006372, 1.112602816651276], [981.1849899109388, 0.9674958600928868], [1012.6627035962109, 0.8430865570427569], [1041.1791037897399, 0.738552390690814], [1061.4025141274865, 0.6650853178014323]], nothing, nothing, [0.0, 9.999999999999999e-5, 0.0010999999999999998, 0.011099999999999997, 0.011649344257923317, 0.011729756721469595, 0.012533881356932368, 0.014277376254310326, 0.016581195024200013, 0.019547835138334132  …  2.2897888992674917, 2.7279576392312253, 3.2505077356979624, 3.8743074921087874, 4.619895315607754, 5.512478011968099, 6.583397667510214, 7.872689663721999, 9.436361436328305, 11.18], [[[0.0, 0.0]], [[5118.777607130979, 4219.5933476709215], [5118.774022848682, 4219.58743836616], [5118.772230706591, 4219.5844837137765], [5118.766854276601, 4219.575619756711], [5118.766854276631, 4219.57561975676], [5118.763782028287, 4219.570554638267], [5118.758789620914, 4219.562323820918], [5118.756101399543, 4219.557891842347]], [[5118.756101399543, 4219.557891842347], [5118.720258313036, 4219.498798794728], [5118.702336675659, 4219.469252270917], [5118.648571387048, 4219.380612699487], [5118.648571387048, 4219.380612699487], [5118.617848111424, 4219.32996151581], [5118.567922395269, 4219.247653342417], [5118.541039115565, 4219.203333556623]], [[5118.541039115565, 4219.203333556623], [5118.18258189391, 4218.612403080417], [5118.003343868406, 4218.316937842311], [5117.465592125278, 4217.430542128], [5117.465592125278, 4217.430542128], [5117.1582800425285, 4216.924030291252], [5116.6588585416785, 4216.100948556533], [5116.38991907984, 4215.657750699345]], [[5116.38991907984, 4215.657750699345], [5116.370219811, 4215.625288272984], [5116.360370148129, 4215.609057059787], [5116.330821045741, 4215.560363420196], [5116.330821045741, 4215.560363420196], [5116.313935767754, 4215.532538483288], [5116.28649707217, 4215.487322960811], [5116.271722328982, 4215.462976141015]], [[5116.271722328982, 4215.462976141015], [5116.268838707812, 4215.458224323476], [5116.267396896618, 4215.455848414709], [5116.263071460599, 4215.448720688402], [5116.263071460599, 4215.448720688402], [5116.2605997812325, 4215.444647701942], [5116.256583299713, 4215.438029098944], [5115.270622322609, 638.0445171232604]], [[5115.270622322609, 638.0445171232604], [5090.531941134906, 608.7644086747673], [5078.345641323613, 594.7136771295332], [5041.973389873998, 553.0908157176546], [5041.981191777612, 553.1502051699931], [5021.4344165321845, 530.0586392589285], [4988.431666727647, 493.7568150948159], [4970.84750467454, 474.75567900613623]], [[4970.84750467454, 474.75567900613623], [4920.484282469849, 421.1736449486143], [4896.080159789034, 396.6593646860756], [4823.616354408918, 324.92145694217925], [4823.6861024673835, 325.4105037705508], [4783.217455051228, 286.67576583518803], [4719.074359980207, 228.48758122214076], [4685.26691877315, 198.94459259318091]], [[4685.26691877315, 198.94459259318091], [4626.564115061071, 149.00707955004054], [4598.331372976059, 126.74936428860337], [4514.682166882483, 62.0431029625488], [4514.806484440916, 62.7692175801526], [4468.314241387242, 28.272663441616714], [4395.08347332831, -22.06197162099579], [4356.666099545187, -47.190192206637676]], [[4356.666099545187, -47.190192206637676], [4291.855283531501, -88.04603297426456], [4260.913712664463, -105.6938695153226], [4169.426329136597, -156.57234825561954], [4169.619774941961, -155.68041870293655], [4118.996103452337, -182.41870487977985], [4039.7577012877464, -219.92398983637213], [3998.372367287468, -238.24557895788166]]  …  [[98.15043335789173, -1.1090517200973316], [95.291646681216, -1.045511038366107], [93.97812463758433, -1.0183503277138033], [90.13925315618691, -0.9380020594519558], [90.16538251871326, -0.9405603529882542], [88.08532083697486, -0.8966452887158303], [84.94372998460285, -0.8357238492490994], [83.3382976730893, -0.8051510117580032]], [[83.3382976730893, -0.8051510117580032], [80.8775706776224, -0.7589522914994046], [79.74611727881795, -0.7391973386680608], [76.43983088642784, -0.6807919086442269], [76.46174181127171, -0.6826237102080156], [74.67018187047255, -0.6507315956565118], [71.96236116782966, -0.6064500818271277], [70.57821172954013, -0.5842351331439367]], [[70.57821172954013, -0.5842351331439367], [68.45463902570549, -0.5506457635444854], [67.47731199510292, -0.5362764123423317], [64.62167103696608, -0.4938223322053859], [64.63999399346109, -0.4951299457421977], [63.092385850244455, -0.47197315549000685], [60.751026901345895, -0.43978604216080974], [59.553673573974294, -0.42364443312262323]], [[59.553673573974294, -0.42364443312262323], [57.71437661384596, -0.3992193613787593], [56.86685255779144, -0.3887647293092498], [54.39040626888744, -0.357900686753474], [54.405670950761554, -0.358830325419444], [53.06306616698331, -0.3420166857801305], [51.02909692874271, -0.3186147368175331], [49.98817681501832, -0.3068833718599272]], [[49.98817681501832, -0.3068833718599272], [48.386391030335794, -0.2891137736231763], [47.64706109261358, -0.28150234064539964], [45.48611594396324, -0.2590516722499826], [45.49876772789417, -0.25970895730775956], [44.326270748046646, -0.24749657343724532], [42.54639154996151, -0.23046811462649394], [41.63434040115049, -0.2219348068886777]], [[41.63434040115049, -0.2219348068886777], [40.227222643663005, -0.2089905136815482], [39.57612232344887, -0.20344010130119256], [37.671416439470214, -0.1870835995956423], [37.681829825539516, -0.18754480314976202], [36.64663834977046, -0.17866185684616884], [35.07005612755109, -0.16624304937407808], [34.260279731850346, -0.16002051662975778]], [[34.260279731850346, -0.16002051662975778], [33.00573733872269, -0.15055914033043724], [32.42292911207209, -0.14649503980069506], [30.714396509259753, -0.1345265342450718], [30.722885695524493, -0.1348467177683773], [29.791038064481175, -0.12835615196092703], [28.36372145930141, -0.11924122108283368], [27.627213715474785, -0.11467036655111452]], [[27.627213715474785, -0.11467036655111452], [26.477551028069296, -0.10768768021038921], [25.93973596439509, -0.10467738907169735], [24.355007685754657, -0.09580523792956859], [24.361838094560976, -0.0960242427877599], [23.49063695525467, -0.0912109208917323], [22.141092141105258, -0.08438573254879866], [21.43758452049876, -0.0809467794769274]], [[21.43758452049876, -0.0809467794769274], [20.32055890099334, -0.07562358671587624], [19.790557059485057, -0.07330529401962298], [18.207199531913055, -0.06641641971807197], [18.212635150952156, -0.06656391761095777], [17.323910339516107, -0.06278433428388638], [15.908879307420918, -0.05726131423958301], [15.150249991272286, -0.054407521046642045]], [[15.150249991272286, -0.054407521046642045], [14.010866240336307, -0.05022205718151003], [13.448180638875156, -0.04829893878850064], [11.68962392790391, -0.04229338140279096], [11.693120394524563, -0.042370261714176544], [10.633322457063002, -0.03879925408194443], [8.768737145522165, -0.032718922499400685], [7.636379292948331, -0.028994322834972316]]], SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [0.0, 0.0], (0.0, 11.18), Any[GasChromatographySimulator.Column(11.18, 0.000104, [0.000104], 1.04e-7, [1.04e-7], "FS5ms", "H2"), GasChromatographySimulator.Program{GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}}([0.0, 60.0, 1680.0, 60.0, 360.0, 60.0], [40.0, 40.0, 180.0, 180.0, 300.0, 300.0], [411564.0, 411564.0, 411564.0, 411564.0, 411564.0, 411564.0], [101300.0, 101300.0, 101300.0, 101300.0, 101300.0, 101300.0], GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}([0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0]), [0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0], 11181×6 extrapolate(interpolate((0.0:0.001:11.18,::Vector{Float64}), ::Matrix{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
   ⋮                                       ⋮
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0), GasChromatographySimulator.Substance("C15", "629-62-9", 474.4, 37.39, 129.62, 0.001, "Leppert2020b, alkane, alkanes", 9.64976601701651e-5, 0.0, 0.0), GasChromatographySimulator.Options(OwrenZen5(), 1.0e-6, 0.001, "inlet", true, true, "Blumberg", "Pressure")], Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}(), SciMLBase.StandardODEProblem()), OwrenZen5(), OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [[0.0, 0.0], [0.5118766854272803, 0.4219575619756654], [5.630525256437843, 4.641338174675174], [56.805180800932064, 46.81564359595516], [59.615807759047144, 49.13143747552918], [60.02721907677394, 49.47041209211274], [64.08188576665707, 49.91605812177886], [72.49442963807763, 50.48957592229632], [82.9002941253958, 50.643301853655736], [95.27754165053068, 50.19276577527522]  …  [779.0813321257494, 2.2604533714317525], [812.651455348656, 1.9600405936908976], [846.4977517608771, 1.700162907864467], [880.5064353658115, 1.4753155838233665], [914.5019585510814, 1.280789638371047], [948.2096971006372, 1.112602816651276], [981.1849899109388, 0.9674958600928868], [1012.6627035962109, 0.8430865570427569], [1041.1791037897399, 0.738552390690814], [1061.4025141274865, 0.6650853178014323]], [0.0, 9.999999999999999e-5, 0.0010999999999999998, 0.011099999999999997, 0.011649344257923317, 0.011729756721469595, 0.012533881356932368, 0.014277376254310326, 0.016581195024200013, 0.019547835138334132  …  2.2897888992674917, 2.7279576392312253, 3.2505077356979624, 3.8743074921087874, 4.619895315607754, 5.512478011968099, 6.583397667510214, 7.872689663721999, 9.436361436328305, 11.18], [[[0.0, 0.0]], [[5118.777607130979, 4219.5933476709215], [5118.774022848682, 4219.58743836616], [5118.772230706591, 4219.5844837137765], [5118.766854276601, 4219.575619756711], [5118.766854276631, 4219.57561975676], [5118.763782028287, 4219.570554638267], [5118.758789620914, 4219.562323820918], [5118.756101399543, 4219.557891842347]], [[5118.756101399543, 4219.557891842347], [5118.720258313036, 4219.498798794728], [5118.702336675659, 4219.469252270917], [5118.648571387048, 4219.380612699487], [5118.648571387048, 4219.380612699487], [5118.617848111424, 4219.32996151581], [5118.567922395269, 4219.247653342417], [5118.541039115565, 4219.203333556623]], [[5118.541039115565, 4219.203333556623], [5118.18258189391, 4218.612403080417], [5118.003343868406, 4218.316937842311], [5117.465592125278, 4217.430542128], [5117.465592125278, 4217.430542128], [5117.1582800425285, 4216.924030291252], [5116.6588585416785, 4216.100948556533], [5116.38991907984, 4215.657750699345]], [[5116.38991907984, 4215.657750699345], [5116.370219811, 4215.625288272984], [5116.360370148129, 4215.609057059787], [5116.330821045741, 4215.560363420196], [5116.330821045741, 4215.560363420196], [5116.313935767754, 4215.532538483288], [5116.28649707217, 4215.487322960811], [5116.271722328982, 4215.462976141015]], [[5116.271722328982, 4215.462976141015], [5116.268838707812, 4215.458224323476], [5116.267396896618, 4215.455848414709], [5116.263071460599, 4215.448720688402], [5116.263071460599, 4215.448720688402], [5116.2605997812325, 4215.444647701942], [5116.256583299713, 4215.438029098944], [5115.270622322609, 638.0445171232604]], [[5115.270622322609, 638.0445171232604], [5090.531941134906, 608.7644086747673], [5078.345641323613, 594.7136771295332], [5041.973389873998, 553.0908157176546], [5041.981191777612, 553.1502051699931], [5021.4344165321845, 530.0586392589285], [4988.431666727647, 493.7568150948159], [4970.84750467454, 474.75567900613623]], [[4970.84750467454, 474.75567900613623], [4920.484282469849, 421.1736449486143], [4896.080159789034, 396.6593646860756], [4823.616354408918, 324.92145694217925], [4823.6861024673835, 325.4105037705508], [4783.217455051228, 286.67576583518803], [4719.074359980207, 228.48758122214076], [4685.26691877315, 198.94459259318091]], [[4685.26691877315, 198.94459259318091], [4626.564115061071, 149.00707955004054], [4598.331372976059, 126.74936428860337], [4514.682166882483, 62.0431029625488], [4514.806484440916, 62.7692175801526], [4468.314241387242, 28.272663441616714], [4395.08347332831, -22.06197162099579], [4356.666099545187, -47.190192206637676]], [[4356.666099545187, -47.190192206637676], [4291.855283531501, -88.04603297426456], [4260.913712664463, -105.6938695153226], [4169.426329136597, -156.57234825561954], [4169.619774941961, -155.68041870293655], [4118.996103452337, -182.41870487977985], [4039.7577012877464, -219.92398983637213], [3998.372367287468, -238.24557895788166]]  …  [[98.15043335789173, -1.1090517200973316], [95.291646681216, -1.045511038366107], [93.97812463758433, -1.0183503277138033], [90.13925315618691, -0.9380020594519558], [90.16538251871326, -0.9405603529882542], [88.08532083697486, -0.8966452887158303], [84.94372998460285, -0.8357238492490994], [83.3382976730893, -0.8051510117580032]], [[83.3382976730893, -0.8051510117580032], [80.8775706776224, -0.7589522914994046], [79.74611727881795, -0.7391973386680608], [76.43983088642784, -0.6807919086442269], [76.46174181127171, -0.6826237102080156], [74.67018187047255, -0.6507315956565118], [71.96236116782966, -0.6064500818271277], [70.57821172954013, -0.5842351331439367]], [[70.57821172954013, -0.5842351331439367], [68.45463902570549, -0.5506457635444854], [67.47731199510292, -0.5362764123423317], [64.62167103696608, -0.4938223322053859], [64.63999399346109, -0.4951299457421977], [63.092385850244455, -0.47197315549000685], [60.751026901345895, -0.43978604216080974], [59.553673573974294, -0.42364443312262323]], [[59.553673573974294, -0.42364443312262323], [57.71437661384596, -0.3992193613787593], [56.86685255779144, -0.3887647293092498], [54.39040626888744, -0.357900686753474], [54.405670950761554, -0.358830325419444], [53.06306616698331, -0.3420166857801305], [51.02909692874271, -0.3186147368175331], [49.98817681501832, -0.3068833718599272]], [[49.98817681501832, -0.3068833718599272], [48.386391030335794, -0.2891137736231763], [47.64706109261358, -0.28150234064539964], [45.48611594396324, -0.2590516722499826], [45.49876772789417, -0.25970895730775956], [44.326270748046646, -0.24749657343724532], [42.54639154996151, -0.23046811462649394], [41.63434040115049, -0.2219348068886777]], [[41.63434040115049, -0.2219348068886777], [40.227222643663005, -0.2089905136815482], [39.57612232344887, -0.20344010130119256], [37.671416439470214, -0.1870835995956423], [37.681829825539516, -0.18754480314976202], [36.64663834977046, -0.17866185684616884], [35.07005612755109, -0.16624304937407808], [34.260279731850346, -0.16002051662975778]], [[34.260279731850346, -0.16002051662975778], [33.00573733872269, -0.15055914033043724], [32.42292911207209, -0.14649503980069506], [30.714396509259753, -0.1345265342450718], [30.722885695524493, -0.1348467177683773], [29.791038064481175, -0.12835615196092703], [28.36372145930141, -0.11924122108283368], [27.627213715474785, -0.11467036655111452]], [[27.627213715474785, -0.11467036655111452], [26.477551028069296, -0.10768768021038921], [25.93973596439509, -0.10467738907169735], [24.355007685754657, -0.09580523792956859], [24.361838094560976, -0.0960242427877599], [23.49063695525467, -0.0912109208917323], [22.141092141105258, -0.08438573254879866], [21.43758452049876, -0.0809467794769274]], [[21.43758452049876, -0.0809467794769274], [20.32055890099334, -0.07562358671587624], [19.790557059485057, -0.07330529401962298], [18.207199531913055, -0.06641641971807197], [18.212635150952156, -0.06656391761095777], [17.323910339516107, -0.06278433428388638], [15.908879307420918, -0.05726131423958301], [15.150249991272286, -0.054407521046642045]], [[15.150249991272286, -0.054407521046642045], [14.010866240336307, -0.05022205718151003], [13.448180638875156, -0.04829893878850064], [11.68962392790391, -0.04229338140279096], [11.693120394524563, -0.042370261714176544], [10.633322457063002, -0.03879925408194443], [8.768737145522165, -0.032718922499400685], [7.636379292948331, -0.028994322834972316]]], true, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}([1061.4025141274865, 0.6650853178014323], [1041.1791037897399, 0.738552390690814], [15.150249991272286, -0.054407521046642045], [14.010866240336307, -0.05022205718151003], [13.448180638875156, -0.04829893878850064], [11.68962392790391, -0.04229338140279096], [11.693120394524563, -0.042370261714176544], [10.633322457063002, -0.03879925408194443], [8.768737145522165, -0.032718922499400685], [7.636379292948331, -0.028994322834972316], [0.014212362694510434, -5.774479393020655e-5], [1059.6092961160357, 0.6718533734267848], [0.013390159826438422, -0.0780807345863182], OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}(0.16666666666666666, 0.0625, 0.1875, 0.25, -0.75, -0.75, 3.75, -3.0, 0.5, 0.26895043731778423, -0.7084548104956269, 0.8658892128279884, 0.15462307371928363, 0.06184922948771345, -0.02947695035460993, 0.18500664893617022, 0.4802345261121857, -0.5337849069148937, -0.013090093085106383, 0.7861107753062541, 0.08783068783068783, 0.3006060606060606, 0.22777777777777777, 0.027777777777777776, 0.06218596218596219, 0.2938217338217338, 0.16666666666666666, 0.25, 0.5, 0.5, 0.6428571428571429, 0.875, -0.19894179894179895, 0.9115151515151515, -1.9777777777777779, -0.1111111111111111, 1.67013727013727, -0.2938217338217338, 1.892063492063492, -6.067155067155067, 7.282458282458283, -4.0195360195360195, -7.214545454545455, 20.676923076923078, -20.31142191142191, 7.14965034965035, 7.866666666666666, -18.78205128205128, 13.508547008547009, -2.3653846153846154, 2.0, -5.294871794871795, 4.534188034188034, -1.2115384615384615, -1.4924630924630924, 1.5785667324128863, 1.1958838881915805, -1.219801565955412, -7.051721611721612, 16.273203719357564, -11.978886071193763, 3.0512256973795435, 4.0, -8.384615384615385, 5.769230769230769, -1.3846153846153846))), true, 0, DiffEqBase.DEStats
Number of function 1 evaluations:                  423
Number of function 2 evaluations:                  0
Number of W matrix evaluations:                    0
Number of linear solves:                           0
Number of Jacobians created:                       0
Number of nonlinear solver iterations:             0
Number of nonlinear solver convergence failures:   0
Number of rootfind condition calls:                0
Number of accepted steps:                          43
Number of rejected steps:                          17, :Success), SciMLBase.ODESolution{Float64, 2, Vector{Vector{Float64}}, Nothing, Nothing, Vector{Float64}, Vector{Vector{Vector{Float64}}}, SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}, OwrenZen5, OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}, DiffEqBase.DEStats}([[0.0, 0.0], [1.3632874253856637, 3.0749596433097057], [14.995846653985922, 33.823134988399396], [55.93531587531197, 126.15415562330914], [59.00140139281977, 133.06864688225258], [60.03447609322315, 135.3983734349431], [69.9765922128378, 136.3724781509097], [80.36045222554588, 135.74238084068182], [93.32018340004988, 133.1684872501259], [107.4650187874269, 128.7389594827033]  …  [924.2435079066985, 2.2602417834589543], [958.232093653662, 1.9607744768825535], [992.52059449631, 1.7016605215306697], [1026.9884395580605, 1.477412167614483], [1061.4511671373486, 1.283339016615], [1095.6210362302616, 1.1154801068982887], [1129.0319981210923, 0.9706041226665136], [1160.8794141415683, 0.846378989251103], [1189.612695196167, 0.7421168417735724], [1208.7099556609892, 0.6731402015769693]], nothing, nothing, [0.0, 9.999999999999999e-5, 0.0010999999999999998, 0.00410331816109622, 0.004328261355452321, 0.0044040533026731095, 0.005161972774880993, 0.006016946471397991, 0.007182042598586932, 0.00858894829417847  …  2.3236023042070024, 2.7649373310743957, 3.291401351383909, 3.9200494360280747, 4.671660856117442, 5.571757157753472, 6.652108401581472, 7.95339410789575, 9.533134288529169, 11.18], [[[0.0, 0.0]], [[13632.902892075097, 30749.72562291578], [13632.893346012297, 30749.682559642846], [13632.888572978387, 30749.661028006354], [13632.874253866816, 30749.59643309774], [13632.874253866643, 30749.596433096955], [13632.866071510314, 30749.559521720123], [13632.852775170772, 30749.499540732595], [13632.845615598017, 30749.46724327809]], [[13632.845615598017, 30749.46724327809], [13632.750154268142, 30749.036610548625], [13632.702423352528, 30748.82129418389], [13632.559229602992, 30748.175345089698], [13632.559229602992, 30748.175345089705], [13632.477403927947, 30747.806231321567], [13632.344436158493, 30747.206421448398], [13632.272837591576, 30746.883446901273]], [[13632.272837591576, 30746.883446901273], [13631.986122788474, 30745.590119804096], [13631.842763125525, 30744.943456255507], [13631.41267509052, 30743.00346560975], [13631.41267509052, 30743.00346560975], [13631.166904406406, 30741.89489952643], [13630.767517593402, 30740.093479641084], [13630.552458308495, 30739.1234843182]], [[13630.552458308495, 30739.1234843182], [13630.530981377682, 30739.026616416435], [13630.520242899585, 30738.978182465555], [13630.488027414534, 30738.832880612918], [13630.488027414534, 30738.832880612918], [13630.469618531748, 30738.749850982837], [13630.439704044195, 30738.614927833965], [13630.423596216007, 30738.54227690763]], [[13630.423596216007, 30738.54227690763], [13630.41635975371, 30738.509638414533], [13630.412741521119, 30738.493319167977], [13630.401886817584, 30738.44436142832], [13630.401886817584, 30738.44436142832], [13630.395684125971, 30738.416385577093], [13630.385604746076, 30738.37092481884], [13626.796541540869, 2577.562377691087]], [[13626.796541540869, 2577.562377691087], [13449.10096102353, 2088.4587974705973], [13363.771964415691, 1871.0429836641815], [13111.04545725893, 1238.8032743339027], [13111.453838435804, 1246.394760205003], [12971.112743311844, 909.3049387514293], [12750.340068976566, 418.82278346993553], [12634.624765580622, 174.11295698777758]], [[12634.624765580622, 174.11295698777758], [12463.53516823539, -175.38057184115314], [12381.507525625611, -328.89083860008395], [12138.666319376902, -773.3658535384275], [12139.09029389682, -767.1753459206775], [12004.367734965683, -1002.4266901370138], [11792.717207821259, -1339.5932876453444], [11681.888812907406, -1506.176860807238]], [[11681.888812907406, -1506.176860807238], [11484.374737602058, -1789.7977936651587], [11390.674907388193, -1908.4403963149634], [11114.061465672932, -2247.6376853740912], [11114.824404726338, -2239.095710520014], [10962.298662937572, -2415.028159242447], [10724.864484074396, -2650.761255562702], [10601.303405252445, -2763.18610435554]], [[10601.303405252445, -2763.18610435554], [10406.788734959448, -2928.057592763398], [10314.930770217381, -2993.4323287277257], [10044.068887119283, -3176.643387746575], [10044.953529704017, -3169.7476297253215], [9895.96522053717, -3261.9031038650337], [9664.972574582684, -3374.223011535327], [9545.072234543106, -3424.613440130892]]  …  [[98.58177449912893, -1.0978356799525728], [95.72175000013968, -1.0349047655997445], [94.4070749709558, -1.0079999855249575], [90.56457697557556, -0.9284355520723778], [90.59042489149464, -0.9309517687361604], [88.50807682646436, -0.887485084793487], [85.36168775235944, -0.8271644531076078], [83.7534762034166, -0.796898349792215]], [[83.7534762034166, -0.796898349792215], [81.28753863146203, -0.7511572617792135], [80.15326350252212, -0.73159510917001], [76.83855834441538, -0.6737765319317518], [76.86030160738419, -0.6755792489291638], [75.0639483864948, -0.6440201264271288], [72.34790123543557, -0.6001877949355543], [70.95930601022252, -0.5782014739076775]], [[70.95930601022252, -0.5782014739076775], [68.82810094937277, -0.5449524731812204], [67.84694394738118, -0.5307269637798381], [64.97998880234564, -0.4887085467926967], [64.99821836576255, -0.4899960056338915], [63.44430383604946, -0.46708480984731465], [61.09266495294098, -0.4352307672093293], [59.88986875123841, -0.4192582661944064]], [[59.88986875123841, -0.4192582661944064], [58.04149839839142, -0.39508448926556583], [57.18954665954856, -0.3847363236659256], [54.700058879399684, -0.35419340487421735], [54.71527702555162, -0.355109037121823], [53.365455360608294, -0.3384754453463079], [51.31996131010609, -0.3153186827427273], [50.27298532228472, -0.3037115316533485]], [[50.27298532228472, -0.3037115316533485], [48.661221235491375, -0.28612609156052243], [47.91707862536021, -0.2785928337911662], [45.74194960911119, -0.25637707593033426], [45.754583004356675, -0.25702460549989053], [44.57424277059991, -0.2449433090469638], [42.781928971478514, -0.22809383985532491], [41.863348694340004, -0.21965099928898377]], [[41.863348694340004, -0.21965099928898377], [40.44550239282291, -0.20684038932004192], [39.78924087773992, -0.20134678140794598], [37.86925873036486, -0.18516028620616506], [37.8796691049457, -0.18561468011829685], [36.83598729542024, -0.17682614293052715], [35.24591397172238, -0.16453622225008646], [34.42901327875247, -0.15837859273792734]], [[34.42901327875247, -0.15837859273792734], [33.1627020902205, -0.1490124576330713], [32.57420145721133, -0.14498875362393598], [30.848650061251245, -0.13314035788252856], [30.857143013003164, -0.133455781040598], [29.915709509416374, -0.12703139714532047], [28.4729603998912, -0.11800600321887628], [27.728180978172542, -0.11347976876022707]], [[27.728180978172542, -0.11347976876022707], [26.56461016317612, -0.1065610815061886], [26.01996044981156, -0.10357754994658795], [24.41436275158216, -0.09478330705986919], [24.421198461745828, -0.09499899707690836], [23.537902092476223, -0.09022742571089469], [22.168277008514835, -0.08345558410785188], [21.453653827657373, -0.08004170867744635]], [[21.453653827657373, -0.08004170867744635], [20.316886104014284, -0.074748793039739], [19.776846992392425, -0.07244144583449302], [18.16137522144309, -0.06557767375011281], [18.166821977318683, -0.06572302378334602], [17.258249713734923, -0.06195124739030211], [15.80778286388561, -0.05642136679025752], [15.027926905923882, -0.0535546788936535]], [[15.027926905923882, -0.0535546788936535], [13.93058449914456, -0.04961066980979474], [13.38662391490271, -0.047780915430259564], [11.685359814483673, -0.042057959516986834], [11.688264959347523, -0.04212080333287549], [10.66223603743121, -0.03871060992306472], [8.85819674807623, -0.03287524223596462], [7.767317880062894, -0.02931361537153733]]], SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [0.0, 0.0], (0.0, 11.18), Any[GasChromatographySimulator.Column(11.18, 0.000104, [0.000104], 1.04e-7, [1.04e-7], "FS5ms", "H2"), GasChromatographySimulator.Program{GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}}([0.0, 60.0, 1680.0, 60.0, 360.0, 60.0], [40.0, 40.0, 180.0, 180.0, 300.0, 300.0], [411564.0, 411564.0, 411564.0, 411564.0, 411564.0, 411564.0], [101300.0, 101300.0, 101300.0, 101300.0, 101300.0, 101300.0], GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}([0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0]), [0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0], 11181×6 extrapolate(interpolate((0.0:0.001:11.18,::Vector{Float64}), ::Matrix{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
   ⋮                                       ⋮
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0), GasChromatographySimulator.Substance("C16", "544-76-3", 488.25, 38.46, 142.18, 0.001, "Leppert2020b, alkane, alkanes", 9.329323536538124e-5, 0.0, 0.0), GasChromatographySimulator.Options(OwrenZen5(), 1.0e-6, 0.001, "inlet", true, true, "Blumberg", "Pressure")], Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}(), SciMLBase.StandardODEProblem()), OwrenZen5(), OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [[0.0, 0.0], [1.3632874253856637, 3.0749596433097057], [14.995846653985922, 33.823134988399396], [55.93531587531197, 126.15415562330914], [59.00140139281977, 133.06864688225258], [60.03447609322315, 135.3983734349431], [69.9765922128378, 136.3724781509097], [80.36045222554588, 135.74238084068182], [93.32018340004988, 133.1684872501259], [107.4650187874269, 128.7389594827033]  …  [924.2435079066985, 2.2602417834589543], [958.232093653662, 1.9607744768825535], [992.52059449631, 1.7016605215306697], [1026.9884395580605, 1.477412167614483], [1061.4511671373486, 1.283339016615], [1095.6210362302616, 1.1154801068982887], [1129.0319981210923, 0.9706041226665136], [1160.8794141415683, 0.846378989251103], [1189.612695196167, 0.7421168417735724], [1208.7099556609892, 0.6731402015769693]], [0.0, 9.999999999999999e-5, 0.0010999999999999998, 0.00410331816109622, 0.004328261355452321, 0.0044040533026731095, 0.005161972774880993, 0.006016946471397991, 0.007182042598586932, 0.00858894829417847  …  2.3236023042070024, 2.7649373310743957, 3.291401351383909, 3.9200494360280747, 4.671660856117442, 5.571757157753472, 6.652108401581472, 7.95339410789575, 9.533134288529169, 11.18], [[[0.0, 0.0]], [[13632.902892075097, 30749.72562291578], [13632.893346012297, 30749.682559642846], [13632.888572978387, 30749.661028006354], [13632.874253866816, 30749.59643309774], [13632.874253866643, 30749.596433096955], [13632.866071510314, 30749.559521720123], [13632.852775170772, 30749.499540732595], [13632.845615598017, 30749.46724327809]], [[13632.845615598017, 30749.46724327809], [13632.750154268142, 30749.036610548625], [13632.702423352528, 30748.82129418389], [13632.559229602992, 30748.175345089698], [13632.559229602992, 30748.175345089705], [13632.477403927947, 30747.806231321567], [13632.344436158493, 30747.206421448398], [13632.272837591576, 30746.883446901273]], [[13632.272837591576, 30746.883446901273], [13631.986122788474, 30745.590119804096], [13631.842763125525, 30744.943456255507], [13631.41267509052, 30743.00346560975], [13631.41267509052, 30743.00346560975], [13631.166904406406, 30741.89489952643], [13630.767517593402, 30740.093479641084], [13630.552458308495, 30739.1234843182]], [[13630.552458308495, 30739.1234843182], [13630.530981377682, 30739.026616416435], [13630.520242899585, 30738.978182465555], [13630.488027414534, 30738.832880612918], [13630.488027414534, 30738.832880612918], [13630.469618531748, 30738.749850982837], [13630.439704044195, 30738.614927833965], [13630.423596216007, 30738.54227690763]], [[13630.423596216007, 30738.54227690763], [13630.41635975371, 30738.509638414533], [13630.412741521119, 30738.493319167977], [13630.401886817584, 30738.44436142832], [13630.401886817584, 30738.44436142832], [13630.395684125971, 30738.416385577093], [13630.385604746076, 30738.37092481884], [13626.796541540869, 2577.562377691087]], [[13626.796541540869, 2577.562377691087], [13449.10096102353, 2088.4587974705973], [13363.771964415691, 1871.0429836641815], [13111.04545725893, 1238.8032743339027], [13111.453838435804, 1246.394760205003], [12971.112743311844, 909.3049387514293], [12750.340068976566, 418.82278346993553], [12634.624765580622, 174.11295698777758]], [[12634.624765580622, 174.11295698777758], [12463.53516823539, -175.38057184115314], [12381.507525625611, -328.89083860008395], [12138.666319376902, -773.3658535384275], [12139.09029389682, -767.1753459206775], [12004.367734965683, -1002.4266901370138], [11792.717207821259, -1339.5932876453444], [11681.888812907406, -1506.176860807238]], [[11681.888812907406, -1506.176860807238], [11484.374737602058, -1789.7977936651587], [11390.674907388193, -1908.4403963149634], [11114.061465672932, -2247.6376853740912], [11114.824404726338, -2239.095710520014], [10962.298662937572, -2415.028159242447], [10724.864484074396, -2650.761255562702], [10601.303405252445, -2763.18610435554]], [[10601.303405252445, -2763.18610435554], [10406.788734959448, -2928.057592763398], [10314.930770217381, -2993.4323287277257], [10044.068887119283, -3176.643387746575], [10044.953529704017, -3169.7476297253215], [9895.96522053717, -3261.9031038650337], [9664.972574582684, -3374.223011535327], [9545.072234543106, -3424.613440130892]]  …  [[98.58177449912893, -1.0978356799525728], [95.72175000013968, -1.0349047655997445], [94.4070749709558, -1.0079999855249575], [90.56457697557556, -0.9284355520723778], [90.59042489149464, -0.9309517687361604], [88.50807682646436, -0.887485084793487], [85.36168775235944, -0.8271644531076078], [83.7534762034166, -0.796898349792215]], [[83.7534762034166, -0.796898349792215], [81.28753863146203, -0.7511572617792135], [80.15326350252212, -0.73159510917001], [76.83855834441538, -0.6737765319317518], [76.86030160738419, -0.6755792489291638], [75.0639483864948, -0.6440201264271288], [72.34790123543557, -0.6001877949355543], [70.95930601022252, -0.5782014739076775]], [[70.95930601022252, -0.5782014739076775], [68.82810094937277, -0.5449524731812204], [67.84694394738118, -0.5307269637798381], [64.97998880234564, -0.4887085467926967], [64.99821836576255, -0.4899960056338915], [63.44430383604946, -0.46708480984731465], [61.09266495294098, -0.4352307672093293], [59.88986875123841, -0.4192582661944064]], [[59.88986875123841, -0.4192582661944064], [58.04149839839142, -0.39508448926556583], [57.18954665954856, -0.3847363236659256], [54.700058879399684, -0.35419340487421735], [54.71527702555162, -0.355109037121823], [53.365455360608294, -0.3384754453463079], [51.31996131010609, -0.3153186827427273], [50.27298532228472, -0.3037115316533485]], [[50.27298532228472, -0.3037115316533485], [48.661221235491375, -0.28612609156052243], [47.91707862536021, -0.2785928337911662], [45.74194960911119, -0.25637707593033426], [45.754583004356675, -0.25702460549989053], [44.57424277059991, -0.2449433090469638], [42.781928971478514, -0.22809383985532491], [41.863348694340004, -0.21965099928898377]], [[41.863348694340004, -0.21965099928898377], [40.44550239282291, -0.20684038932004192], [39.78924087773992, -0.20134678140794598], [37.86925873036486, -0.18516028620616506], [37.8796691049457, -0.18561468011829685], [36.83598729542024, -0.17682614293052715], [35.24591397172238, -0.16453622225008646], [34.42901327875247, -0.15837859273792734]], [[34.42901327875247, -0.15837859273792734], [33.1627020902205, -0.1490124576330713], [32.57420145721133, -0.14498875362393598], [30.848650061251245, -0.13314035788252856], [30.857143013003164, -0.133455781040598], [29.915709509416374, -0.12703139714532047], [28.4729603998912, -0.11800600321887628], [27.728180978172542, -0.11347976876022707]], [[27.728180978172542, -0.11347976876022707], [26.56461016317612, -0.1065610815061886], [26.01996044981156, -0.10357754994658795], [24.41436275158216, -0.09478330705986919], [24.421198461745828, -0.09499899707690836], [23.537902092476223, -0.09022742571089469], [22.168277008514835, -0.08345558410785188], [21.453653827657373, -0.08004170867744635]], [[21.453653827657373, -0.08004170867744635], [20.316886104014284, -0.074748793039739], [19.776846992392425, -0.07244144583449302], [18.16137522144309, -0.06557767375011281], [18.166821977318683, -0.06572302378334602], [17.258249713734923, -0.06195124739030211], [15.80778286388561, -0.05642136679025752], [15.027926905923882, -0.0535546788936535]], [[15.027926905923882, -0.0535546788936535], [13.93058449914456, -0.04961066980979474], [13.38662391490271, -0.047780915430259564], [11.685359814483673, -0.042057959516986834], [11.688264959347523, -0.04212080333287549], [10.66223603743121, -0.03871060992306472], [8.85819674807623, -0.03287524223596462], [7.767317880062894, -0.02931361537153733]]], true, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}([1208.7099556609892, 0.6731402015769693], [1189.612695196167, 0.7421168417735724], [15.027926905923882, -0.0535546788936535], [13.93058449914456, -0.04961066980979474], [13.38662391490271, -0.047780915430259564], [11.685359814483673, -0.042057959516986834], [11.688264959347523, -0.04212080333287549], [10.66223603743121, -0.03871060992306472], [8.85819674807623, -0.03287524223596462], [7.767317880062894, -0.02931361537153733], [0.012110559811022839, -4.932189091978669e-5], [1206.994081112947, 0.6795766572708888], [0.010019401043982532, -0.06637164998450548], OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}(0.16666666666666666, 0.0625, 0.1875, 0.25, -0.75, -0.75, 3.75, -3.0, 0.5, 0.26895043731778423, -0.7084548104956269, 0.8658892128279884, 0.15462307371928363, 0.06184922948771345, -0.02947695035460993, 0.18500664893617022, 0.4802345261121857, -0.5337849069148937, -0.013090093085106383, 0.7861107753062541, 0.08783068783068783, 0.3006060606060606, 0.22777777777777777, 0.027777777777777776, 0.06218596218596219, 0.2938217338217338, 0.16666666666666666, 0.25, 0.5, 0.5, 0.6428571428571429, 0.875, -0.19894179894179895, 0.9115151515151515, -1.9777777777777779, -0.1111111111111111, 1.67013727013727, -0.2938217338217338, 1.892063492063492, -6.067155067155067, 7.282458282458283, -4.0195360195360195, -7.214545454545455, 20.676923076923078, -20.31142191142191, 7.14965034965035, 7.866666666666666, -18.78205128205128, 13.508547008547009, -2.3653846153846154, 2.0, -5.294871794871795, 4.534188034188034, -1.2115384615384615, -1.4924630924630924, 1.5785667324128863, 1.1958838881915805, -1.219801565955412, -7.051721611721612, 16.273203719357564, -11.978886071193763, 3.0512256973795435, 4.0, -8.384615384615385, 5.769230769230769, -1.3846153846153846))), true, 0, DiffEqBase.DEStats
Number of function 1 evaluations:                  430
Number of function 2 evaluations:                  0
Number of W matrix evaluations:                    0
Number of linear solves:                           0
Number of Jacobians created:                       0
Number of nonlinear solver iterations:             0
Number of nonlinear solver convergence failures:   0
Number of rootfind condition calls:                0
Number of accepted steps:                          48
Number of rejected steps:                          13, :Success), SciMLBase.ODESolution{Float64, 2, Vector{Vector{Float64}}, Nothing, Nothing, Vector{Float64}, Vector{Vector{Vector{Float64}}}, SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}, OwrenZen5, OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}, DiffEqBase.DEStats}([[0.0, 0.0], [3.4454018293551445, 20.15187020891205], [37.898623967543834, 221.66125914130734], [56.781421633138926, 332.09903631025884], [59.58219619947376, 348.4794071082316], [60.0076904816268, 350.967911711573], [64.1908817179444, 351.27557922334563], [72.22861795779541, 349.7654120296449], [81.95398347967667, 344.8964219817852], [93.57390532543772, 335.76368738892205]  …  [1067.2724610921673, 2.2184072721758628], [1101.9587192036608, 1.9250298842666953], [1136.9273543701881, 1.671139252520013], [1172.041128516911, 1.4513726653914871], [1207.0899943986274, 1.2611563253845477], [1241.744424094035, 1.096648642302752], [1275.464275173265, 0.9547680278020901], [1307.2969098690098, 0.8334476273236873], [1335.3325055801088, 0.7327291168899536], [1348.3277146734981, 0.6854909058106784]], nothing, nothing, [0.0, 9.999999999999999e-5, 0.0010999999999999998, 0.0016480884116323094, 0.0017293842243021817, 0.001741734726169323, 0.001865239744840736, 0.002114552008714646, 0.00243849328109591, 0.002859908268289787  …  2.43013963359493, 2.890910631867321, 3.4407187720498307, 4.097469542910511, 4.883016968340457, 5.824276454439865, 6.954921276010912, 8.31862994232289, 9.98150441211527, 11.18], [[[0.0, 0.0]], [[34454.09067019658, 201519.54873973038], [34454.066544673515, 201519.2665228601], [34454.05448190562, 201519.12541442472], [34454.01829357718, 201518.70208912512], [34454.0182935768, 201518.70208912063], [34453.9976145145, 201518.46018894453], [34453.964011011965, 201518.06710116068], [34453.945916804725, 201517.8554385079]], [[34453.945916804725, 201517.8554385079], [34453.704659800176, 201515.03326980377], [34453.58403066437, 201513.6221854516], [34453.22214072288, 201509.38893239535], [34453.22214072287, 201509.3889323953], [34453.01534476391, 201506.96993064886], [34452.67929868323, 201503.0390528109], [34452.49834943598, 201500.92242628278]], [[34452.49834943598, 201500.92242628278], [34452.366113920936, 201499.3756283204], [34452.29999597308, 201498.60222933913], [34452.10164136819, 201496.2820323955], [34452.10164136819, 201496.2820323955], [34451.98829536693, 201494.9562055705], [34451.80410731955, 201492.80173697995], [34451.70492873233, 201491.64163850818]], [[34451.70492873233, 201491.64163850818], [34451.68531433539, 201491.41220800983], [34451.675507132735, 201491.2974927607], [34451.646085508, 201490.9533470132], [34451.646085508, 201490.9533470132], [34451.62927313974, 201490.7566923005], [34451.601953023805, 201490.4371283921], [34451.58724218317, 201490.2650555183]], [[34451.58724218317, 201490.2650555183], [34451.5842623444, 201490.23020031853], [34451.58277242492, 201490.2127727187], [34451.578302666065, 201490.16048991878], [34451.578302666065, 201490.16048991878], [34451.57574851789, 201490.1306140332], [34451.57159802672, 201490.08206571918], [34449.427296253605, 5957.217389567348]], [[34449.427296253605, 5957.217389567348], [34252.504971021546, 4731.248052332579], [34155.76069143917, 4149.435118222114], [33867.245374456244, 2432.4826241434494], [33867.33232900661, 2436.2271010750264], [33704.660055128545, 1491.1923353242746], [33443.918142370676, 20.734148876945255], [33305.24028669111, -742.699116039963]], [[33305.24028669111, -742.699116039963], [32935.85085767524, -2733.97493736248], [32757.379494237088, -3629.3788362409687], [32227.834626493903, -6234.351260404685], [32228.449032619512, -6210.552745109366], [31933.246288377337, -7601.938489270164], [31466.44879063712, -9651.400474923663], [31220.850401761407, -10678.181050433283]], [[31220.850401761407, -10678.181050433283], [30801.951642003463, -12366.956903777464], [30601.025503745048, -13101.893042729935], [30006.07919477221, -15219.903620970843], [30007.098937453102, -15188.165148708533], [29676.93223078602, -16300.407158640359], [29158.02799479084, -17874.052891224797], [28886.22775881913, -18643.679363730946]], [[28886.22775881913, -18643.679363730946], [28423.511944462563, -19885.037325453508], [28203.372904083288, -20398.33341715549], [27552.964959659028, -21853.700867335807], [27554.570379747845, -21816.069460663944], [27195.33900336485, -22560.216704295744], [26634.709221242345, -23536.469360775533], [26342.464271990877, -23992.588840432436]]  …  [[96.44826789662763, -1.030276559037398], [93.64265165156847, -0.9712009686005674], [92.35270148883623, -0.9459422887547944], [88.58250577194134, -0.8712588722028961], [88.60768654276386, -0.8736114380655878], [86.5644370339719, -0.8328219359358594], [83.47645323807413, -0.7762045051159709], [81.89794794372926, -0.7477992504602272]], [[81.89794794372926, -0.7477992504602272], [79.47683251104422, -0.704862634747859], [78.36290771069726, -0.68649819747908], [75.10769192866714, -0.6322293729281908], [75.12887786432862, -0.633914174147881], [73.36466973669259, -0.6043007375247037], [70.69656878655826, -0.5631610595925243], [69.33232988127035, -0.5425274063640977]], [[69.33232988127035, -0.5425274063640977], [67.23775305196054, -0.5113169784925528], [66.27318555860829, -0.49796226325100473], [63.45467072377715, -0.45852342465392454], [63.4724295327919, -0.45972591207968944], [61.944635425878424, -0.43822769356396335], [59.63181075352842, -0.40832978299326644], [58.44867277529549, -0.3933396361773404]], [[58.44867277529549, -0.3933396361773404], [56.62967875677411, -0.37064615970634796], [55.79095975188993, -0.3609303841541758], [53.33999675565769, -0.33225980117127646], [53.354812688815066, -0.33311419171748297], [52.02566095516888, -0.3175054576151056], [50.01062016689464, -0.295767658385857], [48.978959499192605, -0.284872772948979]], [[48.978959499192605, -0.284872772948979], [47.389777552888745, -0.26836018161206443], [46.65568095427983, -0.26128518909333737], [44.50957103493481, -0.24042523966423163], [44.52185654747619, -0.24102861519231908], [43.35688647083385, -0.22968877376398777], [41.58673792068361, -0.21386532600579225], [40.67909728975008, -0.2059370556551961]], [[40.67909728975008, -0.2059370556551961], [39.276828482917615, -0.19390051634758598], [38.62725862524166, -0.18873727963197803], [36.72611528647441, -0.17352686286473795], [36.736220666180024, -0.1739494036218247], [35.70209358728581, -0.16569376565143865], [34.12480868157794, -0.15413943762304236], [33.31376325602257, -0.1483498577367559]], [[33.31376325602257, -0.1483498577367559], [32.05457391255425, -0.13953508203384063], [31.468588455857788, -0.13574593876536037], [29.748830938296567, -0.12458785889460779], [29.757052583328907, -0.12488029383379201], [28.81742621558581, -0.11883093482278574], [27.374393570650785, -0.11031817642896073], [26.6280872133834, -0.10604622580830014]], [[26.6280872133834, -0.10604622580830014], [25.4585468075365, -0.09950193638947195], [24.909669670731635, -0.09667540778912752], [23.28784821254744, -0.08833538555438727], [23.29444220304359, -0.08853457087947011], [22.39908987434295, -0.08400381870783402], [21.00424076264503, -0.07754450348837857], [20.273129062730874, -0.07427760394074773]], [[20.273129062730874, -0.07427760394074773], [19.099625939818875, -0.06917045447224451], [18.53866904768106, -0.06693137116733593], [16.84845645636816, -0.06022673873561894], [16.853739884613105, -0.06036126055108096], [15.892596250518114, -0.056640106122944615], [14.33563015438394, -0.05107810396608638], [13.484594910556508, -0.048136060562706834]], [[13.484594910556508, -0.048136060562706834], [12.648249118103454, -0.04529076322681775], [12.227662990338548, -0.0439167833925043], [10.910873287058834, -0.039599086914452804], [10.911869251793506, -0.039619771554836744], [10.117512251926845, -0.037028800752404695], [8.73092122974314, -0.032543888220922676], [7.911383794563607, -0.029866690979934878]]], SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [0.0, 0.0], (0.0, 11.18), Any[GasChromatographySimulator.Column(11.18, 0.000104, [0.000104], 1.04e-7, [1.04e-7], "FS5ms", "H2"), GasChromatographySimulator.Program{GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}}([0.0, 60.0, 1680.0, 60.0, 360.0, 60.0], [40.0, 40.0, 180.0, 180.0, 300.0, 300.0], [411564.0, 411564.0, 411564.0, 411564.0, 411564.0, 411564.0], [101300.0, 101300.0, 101300.0, 101300.0, 101300.0, 101300.0], GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}([0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0]), [0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0], 11181×6 extrapolate(interpolate((0.0:0.001:11.18,::Vector{Float64}), ::Matrix{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
   ⋮                                       ⋮
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0), GasChromatographySimulator.Substance("C17", "629-78-7", 501.05999999999995, 38.95, 145.36, 0.001, "Leppert2020b, alkane, alkanes", 9.036687565381776e-5, 0.0, 0.0), GasChromatographySimulator.Options(OwrenZen5(), 1.0e-6, 0.001, "inlet", true, true, "Blumberg", "Pressure")], Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}(), SciMLBase.StandardODEProblem()), OwrenZen5(), OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [[0.0, 0.0], [3.4454018293551445, 20.15187020891205], [37.898623967543834, 221.66125914130734], [56.781421633138926, 332.09903631025884], [59.58219619947376, 348.4794071082316], [60.0076904816268, 350.967911711573], [64.1908817179444, 351.27557922334563], [72.22861795779541, 349.7654120296449], [81.95398347967667, 344.8964219817852], [93.57390532543772, 335.76368738892205]  …  [1067.2724610921673, 2.2184072721758628], [1101.9587192036608, 1.9250298842666953], [1136.9273543701881, 1.671139252520013], [1172.041128516911, 1.4513726653914871], [1207.0899943986274, 1.2611563253845477], [1241.744424094035, 1.096648642302752], [1275.464275173265, 0.9547680278020901], [1307.2969098690098, 0.8334476273236873], [1335.3325055801088, 0.7327291168899536], [1348.3277146734981, 0.6854909058106784]], [0.0, 9.999999999999999e-5, 0.0010999999999999998, 0.0016480884116323094, 0.0017293842243021817, 0.001741734726169323, 0.001865239744840736, 0.002114552008714646, 0.00243849328109591, 0.002859908268289787  …  2.43013963359493, 2.890910631867321, 3.4407187720498307, 4.097469542910511, 4.883016968340457, 5.824276454439865, 6.954921276010912, 8.31862994232289, 9.98150441211527, 11.18], [[[0.0, 0.0]], [[34454.09067019658, 201519.54873973038], [34454.066544673515, 201519.2665228601], [34454.05448190562, 201519.12541442472], [34454.01829357718, 201518.70208912512], [34454.0182935768, 201518.70208912063], [34453.9976145145, 201518.46018894453], [34453.964011011965, 201518.06710116068], [34453.945916804725, 201517.8554385079]], [[34453.945916804725, 201517.8554385079], [34453.704659800176, 201515.03326980377], [34453.58403066437, 201513.6221854516], [34453.22214072288, 201509.38893239535], [34453.22214072287, 201509.3889323953], [34453.01534476391, 201506.96993064886], [34452.67929868323, 201503.0390528109], [34452.49834943598, 201500.92242628278]], [[34452.49834943598, 201500.92242628278], [34452.366113920936, 201499.3756283204], [34452.29999597308, 201498.60222933913], [34452.10164136819, 201496.2820323955], [34452.10164136819, 201496.2820323955], [34451.98829536693, 201494.9562055705], [34451.80410731955, 201492.80173697995], [34451.70492873233, 201491.64163850818]], [[34451.70492873233, 201491.64163850818], [34451.68531433539, 201491.41220800983], [34451.675507132735, 201491.2974927607], [34451.646085508, 201490.9533470132], [34451.646085508, 201490.9533470132], [34451.62927313974, 201490.7566923005], [34451.601953023805, 201490.4371283921], [34451.58724218317, 201490.2650555183]], [[34451.58724218317, 201490.2650555183], [34451.5842623444, 201490.23020031853], [34451.58277242492, 201490.2127727187], [34451.578302666065, 201490.16048991878], [34451.578302666065, 201490.16048991878], [34451.57574851789, 201490.1306140332], [34451.57159802672, 201490.08206571918], [34449.427296253605, 5957.217389567348]], [[34449.427296253605, 5957.217389567348], [34252.504971021546, 4731.248052332579], [34155.76069143917, 4149.435118222114], [33867.245374456244, 2432.4826241434494], [33867.33232900661, 2436.2271010750264], [33704.660055128545, 1491.1923353242746], [33443.918142370676, 20.734148876945255], [33305.24028669111, -742.699116039963]], [[33305.24028669111, -742.699116039963], [32935.85085767524, -2733.97493736248], [32757.379494237088, -3629.3788362409687], [32227.834626493903, -6234.351260404685], [32228.449032619512, -6210.552745109366], [31933.246288377337, -7601.938489270164], [31466.44879063712, -9651.400474923663], [31220.850401761407, -10678.181050433283]], [[31220.850401761407, -10678.181050433283], [30801.951642003463, -12366.956903777464], [30601.025503745048, -13101.893042729935], [30006.07919477221, -15219.903620970843], [30007.098937453102, -15188.165148708533], [29676.93223078602, -16300.407158640359], [29158.02799479084, -17874.052891224797], [28886.22775881913, -18643.679363730946]], [[28886.22775881913, -18643.679363730946], [28423.511944462563, -19885.037325453508], [28203.372904083288, -20398.33341715549], [27552.964959659028, -21853.700867335807], [27554.570379747845, -21816.069460663944], [27195.33900336485, -22560.216704295744], [26634.709221242345, -23536.469360775533], [26342.464271990877, -23992.588840432436]]  …  [[96.44826789662763, -1.030276559037398], [93.64265165156847, -0.9712009686005674], [92.35270148883623, -0.9459422887547944], [88.58250577194134, -0.8712588722028961], [88.60768654276386, -0.8736114380655878], [86.5644370339719, -0.8328219359358594], [83.47645323807413, -0.7762045051159709], [81.89794794372926, -0.7477992504602272]], [[81.89794794372926, -0.7477992504602272], [79.47683251104422, -0.704862634747859], [78.36290771069726, -0.68649819747908], [75.10769192866714, -0.6322293729281908], [75.12887786432862, -0.633914174147881], [73.36466973669259, -0.6043007375247037], [70.69656878655826, -0.5631610595925243], [69.33232988127035, -0.5425274063640977]], [[69.33232988127035, -0.5425274063640977], [67.23775305196054, -0.5113169784925528], [66.27318555860829, -0.49796226325100473], [63.45467072377715, -0.45852342465392454], [63.4724295327919, -0.45972591207968944], [61.944635425878424, -0.43822769356396335], [59.63181075352842, -0.40832978299326644], [58.44867277529549, -0.3933396361773404]], [[58.44867277529549, -0.3933396361773404], [56.62967875677411, -0.37064615970634796], [55.79095975188993, -0.3609303841541758], [53.33999675565769, -0.33225980117127646], [53.354812688815066, -0.33311419171748297], [52.02566095516888, -0.3175054576151056], [50.01062016689464, -0.295767658385857], [48.978959499192605, -0.284872772948979]], [[48.978959499192605, -0.284872772948979], [47.389777552888745, -0.26836018161206443], [46.65568095427983, -0.26128518909333737], [44.50957103493481, -0.24042523966423163], [44.52185654747619, -0.24102861519231908], [43.35688647083385, -0.22968877376398777], [41.58673792068361, -0.21386532600579225], [40.67909728975008, -0.2059370556551961]], [[40.67909728975008, -0.2059370556551961], [39.276828482917615, -0.19390051634758598], [38.62725862524166, -0.18873727963197803], [36.72611528647441, -0.17352686286473795], [36.736220666180024, -0.1739494036218247], [35.70209358728581, -0.16569376565143865], [34.12480868157794, -0.15413943762304236], [33.31376325602257, -0.1483498577367559]], [[33.31376325602257, -0.1483498577367559], [32.05457391255425, -0.13953508203384063], [31.468588455857788, -0.13574593876536037], [29.748830938296567, -0.12458785889460779], [29.757052583328907, -0.12488029383379201], [28.81742621558581, -0.11883093482278574], [27.374393570650785, -0.11031817642896073], [26.6280872133834, -0.10604622580830014]], [[26.6280872133834, -0.10604622580830014], [25.4585468075365, -0.09950193638947195], [24.909669670731635, -0.09667540778912752], [23.28784821254744, -0.08833538555438727], [23.29444220304359, -0.08853457087947011], [22.39908987434295, -0.08400381870783402], [21.00424076264503, -0.07754450348837857], [20.273129062730874, -0.07427760394074773]], [[20.273129062730874, -0.07427760394074773], [19.099625939818875, -0.06917045447224451], [18.53866904768106, -0.06693137116733593], [16.84845645636816, -0.06022673873561894], [16.853739884613105, -0.06036126055108096], [15.892596250518114, -0.056640106122944615], [14.33563015438394, -0.05107810396608638], [13.484594910556508, -0.048136060562706834]], [[13.484594910556508, -0.048136060562706834], [12.648249118103454, -0.04529076322681775], [12.227662990338548, -0.0439167833925043], [10.910873287058834, -0.039599086914452804], [10.911869251793506, -0.039619771554836744], [10.117512251926845, -0.037028800752404695], [8.73092122974314, -0.032543888220922676], [7.911383794563607, -0.029866690979934878]]], true, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}([1348.3277146734981, 0.6854909058106784], [1335.3325055801088, 0.7327291168899536], [13.484594910556508, -0.048136060562706834], [12.648249118103454, -0.04529076322681775], [12.227662990338548, -0.0439167833925043], [10.910873287058834, -0.039599086914452804], [10.911869251793506, -0.039619771554836744], [10.117512251926845, -0.037028800752404695], [8.73092122974314, -0.032543888220922676], [7.911383794563607, -0.029866690979934878], [0.004359831011878889, -1.8248976177866655e-5], [1347.079272356587, 0.6901786145383846], [0.003233507500383269, -0.02487154422223056], OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}(0.16666666666666666, 0.0625, 0.1875, 0.25, -0.75, -0.75, 3.75, -3.0, 0.5, 0.26895043731778423, -0.7084548104956269, 0.8658892128279884, 0.15462307371928363, 0.06184922948771345, -0.02947695035460993, 0.18500664893617022, 0.4802345261121857, -0.5337849069148937, -0.013090093085106383, 0.7861107753062541, 0.08783068783068783, 0.3006060606060606, 0.22777777777777777, 0.027777777777777776, 0.06218596218596219, 0.2938217338217338, 0.16666666666666666, 0.25, 0.5, 0.5, 0.6428571428571429, 0.875, -0.19894179894179895, 0.9115151515151515, -1.9777777777777779, -0.1111111111111111, 1.67013727013727, -0.2938217338217338, 1.892063492063492, -6.067155067155067, 7.282458282458283, -4.0195360195360195, -7.214545454545455, 20.676923076923078, -20.31142191142191, 7.14965034965035, 7.866666666666666, -18.78205128205128, 13.508547008547009, -2.3653846153846154, 2.0, -5.294871794871795, 4.534188034188034, -1.2115384615384615, -1.4924630924630924, 1.5785667324128863, 1.1958838881915805, -1.219801565955412, -7.051721611721612, 16.273203719357564, -11.978886071193763, 3.0512256973795435, 4.0, -8.384615384615385, 5.769230769230769, -1.3846153846153846))), true, 0, DiffEqBase.DEStats
Number of function 1 evaluations:                  514
Number of function 2 evaluations:                  0
Number of W matrix evaluations:                    0
Number of linear solves:                           0
Number of Jacobians created:                       0
Number of nonlinear solver iterations:             0
Number of nonlinear solver convergence failures:   0
Number of rootfind condition calls:                0
Number of accepted steps:                          55
Number of rejected steps:                          18, :Success), SciMLBase.ODESolution{Float64, 2, Vector{Vector{Float64}}, Nothing, Nothing, Vector{Float64}, Vector{Vector{Vector{Float64}}}, SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}, OwrenZen5, OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}, DiffEqBase.DEStats}([[0.0, 0.0], [9.045437680539045, 142.36121666537568], [38.3778488232054, 604.0039439052795], [51.32714578675067, 807.802057722045], [60.35392737318195, 949.8662699262217], [97.97210236452028, 864.7912211500826], [111.24185198630585, 818.1453503610187], [135.36744892314962, 726.7385415531794], [153.9964149623712, 655.9060513256161], [177.80293022607793, 569.9370005885305]  …  [1211.713591181078, 2.1073352093988444], [1247.0256889150194, 1.829623393062066], [1282.5752147793426, 1.5891893973819067], [1318.195751046774, 1.3809949010482636], [1353.6304502093392, 1.2007619386270945], [1388.4699163858359, 1.0449438215878095], [1422.0250051125997, 0.9108206576507973], [1453.0241952575607, 0.7969770838074718], [1478.671203206373, 0.7054936684960241], [1481.9646653957764, 0.693293702918449]], nothing, nothing, [0.0, 9.999999999999999e-5, 0.00042428140699718756, 0.0005674424125426281, 0.0006672385426463825, 0.0011590908659365714, 0.0013733125276813834, 0.0018285992938707973, 0.0022470865097864337, 0.002882013330616328  …  2.6145675358561253, 3.110810510367421, 3.703274713903305, 4.411448962263332, 5.2592022290868305, 6.276096091614412, 7.499529081412798, 8.979760939572165, 10.814665833372016, 11.18], [[[0.0, 0.0]], [[90454.56682050809, 1.4236181477468181e6], [90454.50348220207, 1.423616154049131e6], [90454.4718130324, 1.4236151572002864e6], [90454.37680545711, 1.4236121666537612e6], [90454.37680545764, 1.4236121666537772e6], [90454.322515369, 1.4236104577700233e6], [90454.2342939066, 1.4236076808339579e6], [90454.1867900066, 1.4236061855606923e6]], [[90454.1867900066, 1.4236061855606923e6], [90453.98139463243, 1.4235997203697804e6], [90453.8786967704, 1.4235964877743237e6], [90453.57060248482, 1.4235867899879552e6], [90453.57060248482, 1.4235867899879552e6], [90453.39454813617, 1.4235812483957445e6], [90453.10845908879, 1.4235722433084017e6], [90452.9544107654, 1.4235673944152172e6]], [[90452.9544107654, 1.4235673944152172e6], [90452.86373337949, 1.4235645402175598e6], [90452.81839465244, 1.4235631131187312e6], [90452.68237833498, 1.423558831822246e6], [90452.68237833498, 1.423558831822246e6], [90452.60465463315, 1.4235563853671108e6], [90452.47835347528, 1.4235524098775173e6], [90452.41034508643, 1.4235502692292747e6]], [[90452.41034508643, 1.4235502692292747e6], [90452.3471344012, 1.4235482795961364e6], [90452.31552904205, 1.423547284779568e6], [90452.22071289824, 1.4235443003298598e6], [90452.22071289824, 1.4235443003298598e6], [90452.16653220002, 1.4235425949300271e6], [90452.0784884962, 1.4235398236552994e6], [90176.94771710748, -59477.58507562522]], [[90176.94771710748, -59477.58507562522], [84632.90577177297, -128234.77572756773], [82358.82160473928, -143953.29930220684], [75766.17683962283, -193760.9149958745], [76045.32180679955, -166410.85178073042], [72493.58591877193, -208133.94578119752], [67818.3081753992, -213638.1375173207], [65510.605837940966, -218169.5150193835]], [[65510.605837940966, -218169.5150193835], [64239.22052090728, -218852.39157195832], [63640.73999096939, -218827.79195286904], [61877.088528344255, -218378.008375242], [61883.56392306624, -218215.58327036037], [60914.92526154922, -217683.90729734197], [59417.36592646606, -215990.80708429043], [58641.33382320477, -214877.21930490353]], [[58641.33382320477, -214877.21930490353], [56515.71880641415, -211078.575437263], [55567.659230259436, -208763.61532563652], [52802.58398473863, -201331.50241493277], [52840.21367168375, -200926.16255031113], [51351.170106050085, -196691.2340865049], [49169.4331775058, -188779.6713292643], [48067.16895975329, -184551.64016955724]], [[48067.16895975329, -184551.64016955724], [46769.23215320708, -179263.32622896443], [46172.83603360896, -176756.6201368943], [44424.61726256349, -169093.78428863664], [44437.39917963022, -169158.53153282986], [43487.501249497065, -164825.5441910209], [42051.9826392558, -158090.87249195593], [41317.256616932274, -154563.6571073198]], [[41317.256616932274, -154563.6571073198], [39886.661702919584, -147498.653601207], [39245.25280801977, -144367.8965980087], [37373.18346288431, -134859.65314925625], [37396.300683831134, -135138.28926737592], [36386.96786228277, -129796.62456495874], [34899.68823633659, -122125.87821612632], [34146.72043380092, -118199.3563803714]]  …  [[91.35134965820787, -0.905623667333193], [88.67669307652542, -0.8536861727969969], [87.4466605304086, -0.8314771430570745], [83.85185438157731, -0.7658250152953022], [83.8756354473996, -0.7678821707518975], [81.92745501603264, -0.7320374718340253], [78.98244941337497, -0.6822688107326016], [77.47690518681867, -0.6573026666373849]], [[77.47690518681867, -0.6573026666373849], [75.16652468980487, -0.6195496521156719], [74.10321076552731, -0.6034001579064283], [70.9960630909641, -0.5556886220927162], [71.01604685658873, -0.5571602768820891], [69.33202626382618, -0.5311354432376278], [66.78434016173668, -0.49496767057699176], [65.481475354588, -0.4768301566323094]], [[65.481475354588, -0.4768301566323094], [63.47985039801903, -0.4493825709504078], [62.55768269761283, -0.4376359145420761], [59.86307444968053, -0.4029559313156942], [59.87979748503997, -0.4040047267308123], [58.41898451477106, -0.3851095263875515], [56.20645065747694, -0.35881891556342543], [55.07430914067698, -0.34563931473029175]], [[55.07430914067698, -0.34563931473029175], [53.33224137601247, -0.32567528131289125], [52.52847922022908, -0.3171260027686545], [50.17942327065746, -0.2919058684619767], [50.19334358338046, -0.29264951277742346], [48.91906913793368, -0.27892689296113843], [46.9857090583981, -0.2598030111338266], [45.99537280005457, -0.2502194879699041]], [[45.99537280005457, -0.2502194879699041], [44.46800708279924, -0.23568327291154484], [43.76177579548332, -0.22945278597375213], [41.69642732147024, -0.21108896296862514], [41.70793501286894, -0.2116125946347737], [40.586060162612625, -0.20163587459045587], [38.87917525647207, -0.18770040228281215], [38.00314480241658, -0.1807183722598631]], [[38.00314480241658, -0.1807183722598631], [36.647181537409374, -0.17010618122574653], [36.018058931089385, -0.16555099138981894], [34.175176226144245, -0.15213490304882055], [34.18460229950003, -0.1525000715651827], [33.18072724599302, -0.14522229786789692], [31.64602019799436, -0.13501852607389483], [30.855372217612203, -0.12990390375636113]], [[30.855372217612203, -0.12990390375636113], [29.623832105181528, -0.1221002845715135], [29.04908029834768, -0.11874110151006409], [27.358736486965128, -0.10884546663428935], [27.366361617358823, -0.10909671028877972], [26.43979278276568, -0.10373075484985742], [25.01020750386054, -0.0961503058549378], [24.267751430250605, -0.09233884359932382]], [[24.267751430250605, -0.09233884359932382], [23.095968871177373, -0.08646788530244848], [22.542830115317678, -0.0839219699906924], [20.89920366739292, -0.07638489614258556], [20.90528529053791, -0.07655492538355425], [19.990181600303323, -0.07244211948939383], [18.548553210219765, -0.06650786956096244], [17.78432514530473, -0.06347667702290982]], [[17.78432514530473, -0.06347667702290982], [16.522453792900006, -0.05860186371307366], [15.90973057660977, -0.05642845537717812], [14.02481966116709, -0.04977045184421276], [14.029950570211858, -0.04988927975194132], [12.922404306702436, -0.04605557381084421], [11.043666788193631, -0.039932185556087685], [9.955175473449557, -0.03642474582215149]], [[9.955175473449557, -0.03642474582215149], [9.652809478247148, -0.03545071362313018], [9.499575659918312, -0.03495987733022027], [9.027830375953453, -0.0334399094809219], [9.027851270637008, -0.03344033992819901], [8.749850972764044, -0.0325416379236638], [8.28291372195464, -0.031026394555652422], [8.022584032155352, -0.03017713227719846]]], SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [0.0, 0.0], (0.0, 11.18), Any[GasChromatographySimulator.Column(11.18, 0.000104, [0.000104], 1.04e-7, [1.04e-7], "FS5ms", "H2"), GasChromatographySimulator.Program{GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}}([0.0, 60.0, 1680.0, 60.0, 360.0, 60.0], [40.0, 40.0, 180.0, 180.0, 300.0, 300.0], [411564.0, 411564.0, 411564.0, 411564.0, 411564.0, 411564.0], [101300.0, 101300.0, 101300.0, 101300.0, 101300.0, 101300.0], GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}([0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0]), [0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0], 11181×6 extrapolate(interpolate((0.0:0.001:11.18,::Vector{Float64}), ::Matrix{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
   ⋮                                       ⋮
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0), GasChromatographySimulator.Substance("C18", "593-45-3", 513.25, 39.58, 153.29, 0.001, "Leppert2020b, alkane, alkanes", 8.768068754143736e-5, 0.0, 0.0), GasChromatographySimulator.Options(OwrenZen5(), 1.0e-6, 0.001, "inlet", true, true, "Blumberg", "Pressure")], Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}(), SciMLBase.StandardODEProblem()), OwrenZen5(), OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [[0.0, 0.0], [9.045437680539045, 142.36121666537568], [38.3778488232054, 604.0039439052795], [51.32714578675067, 807.802057722045], [60.35392737318195, 949.8662699262217], [97.97210236452028, 864.7912211500826], [111.24185198630585, 818.1453503610187], [135.36744892314962, 726.7385415531794], [153.9964149623712, 655.9060513256161], [177.80293022607793, 569.9370005885305]  …  [1211.713591181078, 2.1073352093988444], [1247.0256889150194, 1.829623393062066], [1282.5752147793426, 1.5891893973819067], [1318.195751046774, 1.3809949010482636], [1353.6304502093392, 1.2007619386270945], [1388.4699163858359, 1.0449438215878095], [1422.0250051125997, 0.9108206576507973], [1453.0241952575607, 0.7969770838074718], [1478.671203206373, 0.7054936684960241], [1481.9646653957764, 0.693293702918449]], [0.0, 9.999999999999999e-5, 0.00042428140699718756, 0.0005674424125426281, 0.0006672385426463825, 0.0011590908659365714, 0.0013733125276813834, 0.0018285992938707973, 0.0022470865097864337, 0.002882013330616328  …  2.6145675358561253, 3.110810510367421, 3.703274713903305, 4.411448962263332, 5.2592022290868305, 6.276096091614412, 7.499529081412798, 8.979760939572165, 10.814665833372016, 11.18], [[[0.0, 0.0]], [[90454.56682050809, 1.4236181477468181e6], [90454.50348220207, 1.423616154049131e6], [90454.4718130324, 1.4236151572002864e6], [90454.37680545711, 1.4236121666537612e6], [90454.37680545764, 1.4236121666537772e6], [90454.322515369, 1.4236104577700233e6], [90454.2342939066, 1.4236076808339579e6], [90454.1867900066, 1.4236061855606923e6]], [[90454.1867900066, 1.4236061855606923e6], [90453.98139463243, 1.4235997203697804e6], [90453.8786967704, 1.4235964877743237e6], [90453.57060248482, 1.4235867899879552e6], [90453.57060248482, 1.4235867899879552e6], [90453.39454813617, 1.4235812483957445e6], [90453.10845908879, 1.4235722433084017e6], [90452.9544107654, 1.4235673944152172e6]], [[90452.9544107654, 1.4235673944152172e6], [90452.86373337949, 1.4235645402175598e6], [90452.81839465244, 1.4235631131187312e6], [90452.68237833498, 1.423558831822246e6], [90452.68237833498, 1.423558831822246e6], [90452.60465463315, 1.4235563853671108e6], [90452.47835347528, 1.4235524098775173e6], [90452.41034508643, 1.4235502692292747e6]], [[90452.41034508643, 1.4235502692292747e6], [90452.3471344012, 1.4235482795961364e6], [90452.31552904205, 1.423547284779568e6], [90452.22071289824, 1.4235443003298598e6], [90452.22071289824, 1.4235443003298598e6], [90452.16653220002, 1.4235425949300271e6], [90452.0784884962, 1.4235398236552994e6], [90176.94771710748, -59477.58507562522]], [[90176.94771710748, -59477.58507562522], [84632.90577177297, -128234.77572756773], [82358.82160473928, -143953.29930220684], [75766.17683962283, -193760.9149958745], [76045.32180679955, -166410.85178073042], [72493.58591877193, -208133.94578119752], [67818.3081753992, -213638.1375173207], [65510.605837940966, -218169.5150193835]], [[65510.605837940966, -218169.5150193835], [64239.22052090728, -218852.39157195832], [63640.73999096939, -218827.79195286904], [61877.088528344255, -218378.008375242], [61883.56392306624, -218215.58327036037], [60914.92526154922, -217683.90729734197], [59417.36592646606, -215990.80708429043], [58641.33382320477, -214877.21930490353]], [[58641.33382320477, -214877.21930490353], [56515.71880641415, -211078.575437263], [55567.659230259436, -208763.61532563652], [52802.58398473863, -201331.50241493277], [52840.21367168375, -200926.16255031113], [51351.170106050085, -196691.2340865049], [49169.4331775058, -188779.6713292643], [48067.16895975329, -184551.64016955724]], [[48067.16895975329, -184551.64016955724], [46769.23215320708, -179263.32622896443], [46172.83603360896, -176756.6201368943], [44424.61726256349, -169093.78428863664], [44437.39917963022, -169158.53153282986], [43487.501249497065, -164825.5441910209], [42051.9826392558, -158090.87249195593], [41317.256616932274, -154563.6571073198]], [[41317.256616932274, -154563.6571073198], [39886.661702919584, -147498.653601207], [39245.25280801977, -144367.8965980087], [37373.18346288431, -134859.65314925625], [37396.300683831134, -135138.28926737592], [36386.96786228277, -129796.62456495874], [34899.68823633659, -122125.87821612632], [34146.72043380092, -118199.3563803714]]  …  [[91.35134965820787, -0.905623667333193], [88.67669307652542, -0.8536861727969969], [87.4466605304086, -0.8314771430570745], [83.85185438157731, -0.7658250152953022], [83.8756354473996, -0.7678821707518975], [81.92745501603264, -0.7320374718340253], [78.98244941337497, -0.6822688107326016], [77.47690518681867, -0.6573026666373849]], [[77.47690518681867, -0.6573026666373849], [75.16652468980487, -0.6195496521156719], [74.10321076552731, -0.6034001579064283], [70.9960630909641, -0.5556886220927162], [71.01604685658873, -0.5571602768820891], [69.33202626382618, -0.5311354432376278], [66.78434016173668, -0.49496767057699176], [65.481475354588, -0.4768301566323094]], [[65.481475354588, -0.4768301566323094], [63.47985039801903, -0.4493825709504078], [62.55768269761283, -0.4376359145420761], [59.86307444968053, -0.4029559313156942], [59.87979748503997, -0.4040047267308123], [58.41898451477106, -0.3851095263875515], [56.20645065747694, -0.35881891556342543], [55.07430914067698, -0.34563931473029175]], [[55.07430914067698, -0.34563931473029175], [53.33224137601247, -0.32567528131289125], [52.52847922022908, -0.3171260027686545], [50.17942327065746, -0.2919058684619767], [50.19334358338046, -0.29264951277742346], [48.91906913793368, -0.27892689296113843], [46.9857090583981, -0.2598030111338266], [45.99537280005457, -0.2502194879699041]], [[45.99537280005457, -0.2502194879699041], [44.46800708279924, -0.23568327291154484], [43.76177579548332, -0.22945278597375213], [41.69642732147024, -0.21108896296862514], [41.70793501286894, -0.2116125946347737], [40.586060162612625, -0.20163587459045587], [38.87917525647207, -0.18770040228281215], [38.00314480241658, -0.1807183722598631]], [[38.00314480241658, -0.1807183722598631], [36.647181537409374, -0.17010618122574653], [36.018058931089385, -0.16555099138981894], [34.175176226144245, -0.15213490304882055], [34.18460229950003, -0.1525000715651827], [33.18072724599302, -0.14522229786789692], [31.64602019799436, -0.13501852607389483], [30.855372217612203, -0.12990390375636113]], [[30.855372217612203, -0.12990390375636113], [29.623832105181528, -0.1221002845715135], [29.04908029834768, -0.11874110151006409], [27.358736486965128, -0.10884546663428935], [27.366361617358823, -0.10909671028877972], [26.43979278276568, -0.10373075484985742], [25.01020750386054, -0.0961503058549378], [24.267751430250605, -0.09233884359932382]], [[24.267751430250605, -0.09233884359932382], [23.095968871177373, -0.08646788530244848], [22.542830115317678, -0.0839219699906924], [20.89920366739292, -0.07638489614258556], [20.90528529053791, -0.07655492538355425], [19.990181600303323, -0.07244211948939383], [18.548553210219765, -0.06650786956096244], [17.78432514530473, -0.06347667702290982]], [[17.78432514530473, -0.06347667702290982], [16.522453792900006, -0.05860186371307366], [15.90973057660977, -0.05642845537717812], [14.02481966116709, -0.04977045184421276], [14.029950570211858, -0.04988927975194132], [12.922404306702436, -0.04605557381084421], [11.043666788193631, -0.039932185556087685], [9.955175473449557, -0.03642474582215149]], [[9.955175473449557, -0.03642474582215149], [9.652809478247148, -0.03545071362313018], [9.499575659918312, -0.03495987733022027], [9.027830375953453, -0.0334399094809219], [9.027851270637008, -0.03344033992819901], [8.749850972764044, -0.0325416379236638], [8.28291372195464, -0.031026394555652422], [8.022584032155352, -0.03017713227719846]]], true, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}([1481.9646653957764, 0.693293702918449], [1478.671203206373, 0.7054936684960241], [9.955175473449557, -0.03642474582215149], [9.652809478247148, -0.03545071362313018], [9.499575659918312, -0.03495987733022027], [9.027830375953453, -0.0334399094809219], [9.027851270637008, -0.03344033992819901], [8.749850972764044, -0.0325416379236638], [8.28291372195464, -0.031026394555652422], [8.022584032155352, -0.03017713227719846], [4.453118656898261e-5, -1.912594401817395e-7], [1481.5922935676956, 0.6946915615602365], [3.0048730283565666e-5, -0.0002707164249453084], OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}(0.16666666666666666, 0.0625, 0.1875, 0.25, -0.75, -0.75, 3.75, -3.0, 0.5, 0.26895043731778423, -0.7084548104956269, 0.8658892128279884, 0.15462307371928363, 0.06184922948771345, -0.02947695035460993, 0.18500664893617022, 0.4802345261121857, -0.5337849069148937, -0.013090093085106383, 0.7861107753062541, 0.08783068783068783, 0.3006060606060606, 0.22777777777777777, 0.027777777777777776, 0.06218596218596219, 0.2938217338217338, 0.16666666666666666, 0.25, 0.5, 0.5, 0.6428571428571429, 0.875, -0.19894179894179895, 0.9115151515151515, -1.9777777777777779, -0.1111111111111111, 1.67013727013727, -0.2938217338217338, 1.892063492063492, -6.067155067155067, 7.282458282458283, -4.0195360195360195, -7.214545454545455, 20.676923076923078, -20.31142191142191, 7.14965034965035, 7.866666666666666, -18.78205128205128, 13.508547008547009, -2.3653846153846154, 2.0, -5.294871794871795, 4.534188034188034, -1.2115384615384615, -1.4924630924630924, 1.5785667324128863, 1.1958838881915805, -1.219801565955412, -7.051721611721612, 16.273203719357564, -11.978886071193763, 3.0512256973795435, 4.0, -8.384615384615385, 5.769230769230769, -1.3846153846153846))), true, 0, DiffEqBase.DEStats
Number of function 1 evaluations:                  458
Number of function 2 evaluations:                  0
Number of W matrix evaluations:                    0
Number of linear solves:                           0
Number of Jacobians created:                       0
Number of nonlinear solver iterations:             0
Number of nonlinear solver convergence failures:   0
Number of rootfind condition calls:                0
Number of accepted steps:                          56
Number of rejected steps:                          9, :Success)  …  SciMLBase.ODESolution{Float64, 2, Vector{Vector{Float64}}, Nothing, Nothing, Vector{Float64}, Vector{Vector{Vector{Float64}}}, SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}, OwrenZen5, OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}, DiffEqBase.DEStats}([[0.0, 0.0], [36.46999475176144, 11627.833468878944], [50.98894756823326, 16256.950116220725], [59.677478263546554, 19027.136859996343], [60.01279666732794, 19134.047283264434], [63.30939966152717, 18886.414956402434], [70.35702777289912, 18306.60784896539], [79.12385798185468, 17514.62401047433], [89.48880384295089, 16516.967049644536], [101.4913217675015, 15327.09845355328]  …  [1745.5033038829256, 1.1399094845752085], [1784.6535115640013, 1.2662873843977431], [1793.8142764606914, 1.2935623344940956], [1800.692523933218, 1.3133903959190998], [1818.7793073262144, 0.8411898101913069], [1825.1344898208872, 0.724238772061658], [1835.086309997159, 0.5765234868736365], [1842.1433532297326, 0.4923271769262027], [1849.09134118721, 0.4221937621150325], [1849.7958097184876, 0.4156588221760513]], nothing, nothing, [0.0, 2.1309474052151082e-5, 2.9792925833424115e-5, 3.4869652311690857e-5, 3.506557957112913e-5, 3.702485216551186e-5, 4.144094191531657e-5, 4.7393935243721895e-5, 5.514606940472515e-5, 6.51884871346913e-5  …  6.095652862425779, 7.324520878476427, 7.635939166009505, 7.877432839400523, 8.653477635990866, 9.001177360874669, 9.662623319778731, 10.262873706230286, 11.072151773996328, 11.18], [[[0.0, 0.0]], [[1.7114458568044365e6, 5.456654561543545e8], [1.7114456014333519e6, 5.456652933128967e8], [1.7114454737477945e6, 5.456652118921678e8], [1.7114450906910675e6, 5.456649676299812e8], [1.7114450906910675e6, 5.456649676299812e8], [1.7114448718014704e6, 5.456648280515885e8], [1.7114445161058155e6, 5.45664601236701e8], [1.7114443245773553e6, 5.456644791056077e8]], [[1.7114443245773553e6, 5.456644791056077e8], [1.7114442229122408e6, 5.456644142772758e8], [1.7114441720796807e6, 5.456643818631098e8], [1.7114440195819747e6, 5.456642846206007e8], [1.7114440195819747e6, 5.456642846206007e8], [1.7114439324404506e6, 5.456642290534706e8], [1.711443790835435e6, 5.456641387568655e8], [1.7114437145865755e6, 5.456640901356165e8]], [[1.7114437145865755e6, 5.456640901356165e8], [1.7114436537474066e6, 5.456640513405936e8], [1.7114436233278029e6, 5.456640319430702e8], [1.7114435320690433e6, 5.456639737505352e8], [1.7114435320690433e6, 5.456639737505352e8], [1.7114434799211968e6, 5.456639404976699e8], [1.7114433951809132e6, 5.456638864617448e8], [1.711443349551528e6, 5.456638573654774e8]], [[1.711443349551528e6, 5.456638573654774e8], [1.7114433472035474e6, 5.456638558682522e8], [1.7114433460295575e6, 5.456638551196396e8], [1.7114433425075684e6, 5.4566385287379e8], [1.7114433425075684e6, 5.4566385287379e8], [1.7114433404950358e6, 5.456638515904682e8], [1.7114433372246316e6, 5.456638495050455e8], [1.7112194333085215e6, -1.240094688514986e8]], [[1.7112194333085215e6, -1.240094688514986e8], [1.7014727162095776e6, -1.2489426434904444e8], [1.6966836656232106e6, -1.2529842574193788e8], [1.68239978722693e6, -1.2646696835060757e8], [1.6824040617452264e6, -1.2646232142375731e8], [1.6743491301542548e6, -1.2708234727045971e8], [1.661436081627466e6, -1.2800510532938278e8], [1.6545671626706596e6, -1.2846510843178523e8]], [[1.6545671626706596e6, -1.2846510843178523e8], [1.6341486508255145e6, -1.2974013681569803e8], [1.6243201671753048e6, -1.3023315221704555e8], [1.5951841130948886e6, -1.3156210159968436e8], [1.5952261811929613e6, -1.3152284562542081e8], [1.5790197033705208e6, -1.321378179967187e8], [1.5534704982410446e6, -1.328176914233566e8], [1.5400577519705452e6, -1.3307428673018616e8]], [[1.5400577519705452e6, -1.3307428673018616e8], [1.5163651240798533e6, -1.333867583872801e8], [1.5050683830144184e6, -1.3340351781710911e8], [1.4716652277257992e6, -1.3329616753307796e8], [1.4717410930330623e6, -1.332476639924826e8], [1.453265418976645e6, -1.3305806523287451e8], [1.4243735891755142e6, -1.324344275650543e8], [1.4092916193273058e6, -1.3200468357900321e8]], [[1.4092916193273058e6, -1.3200468357900321e8], [1.383649311582397e6, -1.3112730203815591e8], [1.3715302047857726e6, -1.3059717615241897e8], [1.3357750529118804e6, -1.2886944579245949e8], [1.3358898972794234e6, -1.2882969201332271e8], [1.316208377089276e6, -1.277608062152164e8], [1.2856680835851151e6, -1.2580757254824108e8], [1.2698053878977094e6, -1.247031373637411e8]], [[1.2698053878977094e6, -1.247031373637411e8], [1.2430696084351363e6, -1.22706964252195e8], [1.2305470152368096e6, -1.2169121093479735e8], [1.1936800508373226e6, -1.185395203828809e8], [1.193840355679632e6, -1.1852610089907902e8], [1.1736382730102343e6, -1.1669911444584191e8], [1.1425447632113395e6, -1.1367536012806511e8], [1.1264736655901023e6, -1.1204529507804316e8]]  …  [[34.06735036994164, 0.1174563241762398], [34.00826593235557, 0.11704925859874413], [33.97868518607742, 0.11684572580999776], [33.88978803003574, 0.11623512744375591], [33.8897880300356, 0.11623512744375492], [33.8388848010054, 0.1158862140916168], [33.75600333777741, 0.11531922989439221], [33.71129045606438, 0.11501393071127126]], [[33.71129045606438, 0.11501393071127126], [33.111286175422926, 0.1109562557254525], [32.80716928019745, 0.10892741823253999], [31.87741533038597, 0.10284090575380882], [31.87741533038597, 0.10284090575380882], [31.333743255673074, 0.09936289862310531], [30.429565985986695, 0.09371113703571204], [29.931390079291603, 0.09066788079634644]], [[29.931390079291603, 0.09066788079634644], [29.761175721334887, 0.0896395895730862], [29.675702425299068, 0.08912544396145604], [29.417792520702275, 0.08758300712656568], [29.417792520702275, 0.08758300712656568], [29.2693951007883, 0.08670161464948549], [29.02663122591675, 0.08526935187423011], [28.895067425141228, 0.08449813345678492]], [[28.895067425141228, 0.08449813345678492], [28.758403899038697, 0.08370073062348317], [28.6898280141, 0.08330202920683229], [28.483109757430217, 0.08210592495687961], [28.483109757430217, 0.08210592495687961], [28.364308634210985, 0.08142243681404951], [28.170188256676457, 0.08031176858195134], [27.797832448138347, -0.9297602160723988]], [[27.797832448138347, -0.9297602160723988], [26.030199170314006, -0.780000328144288], [25.277019962984756, -0.7293126898909018], [23.107527031577213, -0.5788872627383584], [23.159563473466427, -0.6033074046814156], [22.005200174575197, -0.5133463440533983], [20.391003791840863, -0.432351816360711], [19.586688840851643, -0.3924800173404359]], [[19.586688840851643, -0.3924800173404359], [19.125929839938685, -0.3713531132670189], [18.90621926343602, -0.3619305804573749], [18.257867552467644, -0.3344621948357066], [18.259176692597702, -0.334799059804443], [17.900973177520207, -0.32006523463056624], [17.340542590272587, -0.29847866899931036], [17.04786413039238, -0.28761788356700313]], [[17.04786413039238, -0.28761788356700313], [16.3242453774307, -0.26164276889243376], [15.988481572673644, -0.25091917833381205], [15.002633519420883, -0.2199515449895129], [15.007803163443368, -0.22102195786748935], [14.46885751000141, -0.20458405386035677], [13.64120686484432, -0.18266328425236575], [13.212346856183274, -0.171940325018909]], [[13.212346856183274, -0.171940325018909], [12.704221744268681, -0.15979667575143744], [12.46160824214808, -0.15448568130838045], [11.74035514533846, -0.1390642296829387], [11.742047501193603, -0.13930669319878544], [11.339666854604957, -0.1310822939187008], [10.703156185990803, -0.11922476918130925], [10.366210241124326, -0.11328472818274955]], [[10.366210241124326, -0.11328472818274955], [9.763883958491414, -0.1031413319403854], [9.47275984968753, -0.09872406375391757], [8.58926081751441, -0.08579201555167748], [8.591350953074075, -0.08600848384125344], [8.083268052105018, -0.07901543795540153], [7.247991035238013, -0.06871678309858116], [6.7850683665652705, -0.06338413974229086]], [[6.7850683665652705, -0.06338413974229086], [6.701417003379618, -0.062448337469439605], [6.6595043934235045, -0.0619845343647822], [6.532838824034314, -0.06059075044606307], [6.532841238661442, -0.060590934376008515], [6.459925408189431, -0.059796482618993604], [6.34055116311933, -0.05850842708072013], [6.275788201411815, -0.05781584072390198]]], SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [0.0, 0.0], (0.0, 11.18), Any[GasChromatographySimulator.Column(11.18, 0.000104, [0.000104], 1.04e-7, [1.04e-7], "FS5ms", "H2"), GasChromatographySimulator.Program{GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}}([0.0, 60.0, 1680.0, 60.0, 360.0, 60.0], [40.0, 40.0, 180.0, 180.0, 300.0, 300.0], [411564.0, 411564.0, 411564.0, 411564.0, 411564.0, 411564.0], [101300.0, 101300.0, 101300.0, 101300.0, 101300.0, 101300.0], GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}([0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0]), [0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0], 11181×6 extrapolate(interpolate((0.0:0.001:11.18,::Vector{Float64}), ::Matrix{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
   ⋮                                       ⋮
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0), GasChromatographySimulator.Substance("C21", "629-94-7", 546.54, 41.43, 179.47, 0.001, "Leppert2020b, alkane, alkanes", 8.077845767414391e-5, 0.0, 0.0), GasChromatographySimulator.Options(OwrenZen5(), 1.0e-6, 0.001, "inlet", true, true, "Blumberg", "Pressure")], Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}(), SciMLBase.StandardODEProblem()), OwrenZen5(), OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [[0.0, 0.0], [36.46999475176144, 11627.833468878944], [50.98894756823326, 16256.950116220725], [59.677478263546554, 19027.136859996343], [60.01279666732794, 19134.047283264434], [63.30939966152717, 18886.414956402434], [70.35702777289912, 18306.60784896539], [79.12385798185468, 17514.62401047433], [89.48880384295089, 16516.967049644536], [101.4913217675015, 15327.09845355328]  …  [1745.5033038829256, 1.1399094845752085], [1784.6535115640013, 1.2662873843977431], [1793.8142764606914, 1.2935623344940956], [1800.692523933218, 1.3133903959190998], [1818.7793073262144, 0.8411898101913069], [1825.1344898208872, 0.724238772061658], [1835.086309997159, 0.5765234868736365], [1842.1433532297326, 0.4923271769262027], [1849.09134118721, 0.4221937621150325], [1849.7958097184876, 0.4156588221760513]], [0.0, 2.1309474052151082e-5, 2.9792925833424115e-5, 3.4869652311690857e-5, 3.506557957112913e-5, 3.702485216551186e-5, 4.144094191531657e-5, 4.7393935243721895e-5, 5.514606940472515e-5, 6.51884871346913e-5  …  6.095652862425779, 7.324520878476427, 7.635939166009505, 7.877432839400523, 8.653477635990866, 9.001177360874669, 9.662623319778731, 10.262873706230286, 11.072151773996328, 11.18], [[[0.0, 0.0]], [[1.7114458568044365e6, 5.456654561543545e8], [1.7114456014333519e6, 5.456652933128967e8], [1.7114454737477945e6, 5.456652118921678e8], [1.7114450906910675e6, 5.456649676299812e8], [1.7114450906910675e6, 5.456649676299812e8], [1.7114448718014704e6, 5.456648280515885e8], [1.7114445161058155e6, 5.45664601236701e8], [1.7114443245773553e6, 5.456644791056077e8]], [[1.7114443245773553e6, 5.456644791056077e8], [1.7114442229122408e6, 5.456644142772758e8], [1.7114441720796807e6, 5.456643818631098e8], [1.7114440195819747e6, 5.456642846206007e8], [1.7114440195819747e6, 5.456642846206007e8], [1.7114439324404506e6, 5.456642290534706e8], [1.711443790835435e6, 5.456641387568655e8], [1.7114437145865755e6, 5.456640901356165e8]], [[1.7114437145865755e6, 5.456640901356165e8], [1.7114436537474066e6, 5.456640513405936e8], [1.7114436233278029e6, 5.456640319430702e8], [1.7114435320690433e6, 5.456639737505352e8], [1.7114435320690433e6, 5.456639737505352e8], [1.7114434799211968e6, 5.456639404976699e8], [1.7114433951809132e6, 5.456638864617448e8], [1.711443349551528e6, 5.456638573654774e8]], [[1.711443349551528e6, 5.456638573654774e8], [1.7114433472035474e6, 5.456638558682522e8], [1.7114433460295575e6, 5.456638551196396e8], [1.7114433425075684e6, 5.4566385287379e8], [1.7114433425075684e6, 5.4566385287379e8], [1.7114433404950358e6, 5.456638515904682e8], [1.7114433372246316e6, 5.456638495050455e8], [1.7112194333085215e6, -1.240094688514986e8]], [[1.7112194333085215e6, -1.240094688514986e8], [1.7014727162095776e6, -1.2489426434904444e8], [1.6966836656232106e6, -1.2529842574193788e8], [1.68239978722693e6, -1.2646696835060757e8], [1.6824040617452264e6, -1.2646232142375731e8], [1.6743491301542548e6, -1.2708234727045971e8], [1.661436081627466e6, -1.2800510532938278e8], [1.6545671626706596e6, -1.2846510843178523e8]], [[1.6545671626706596e6, -1.2846510843178523e8], [1.6341486508255145e6, -1.2974013681569803e8], [1.6243201671753048e6, -1.3023315221704555e8], [1.5951841130948886e6, -1.3156210159968436e8], [1.5952261811929613e6, -1.3152284562542081e8], [1.5790197033705208e6, -1.321378179967187e8], [1.5534704982410446e6, -1.328176914233566e8], [1.5400577519705452e6, -1.3307428673018616e8]], [[1.5400577519705452e6, -1.3307428673018616e8], [1.5163651240798533e6, -1.333867583872801e8], [1.5050683830144184e6, -1.3340351781710911e8], [1.4716652277257992e6, -1.3329616753307796e8], [1.4717410930330623e6, -1.332476639924826e8], [1.453265418976645e6, -1.3305806523287451e8], [1.4243735891755142e6, -1.324344275650543e8], [1.4092916193273058e6, -1.3200468357900321e8]], [[1.4092916193273058e6, -1.3200468357900321e8], [1.383649311582397e6, -1.3112730203815591e8], [1.3715302047857726e6, -1.3059717615241897e8], [1.3357750529118804e6, -1.2886944579245949e8], [1.3358898972794234e6, -1.2882969201332271e8], [1.316208377089276e6, -1.277608062152164e8], [1.2856680835851151e6, -1.2580757254824108e8], [1.2698053878977094e6, -1.247031373637411e8]], [[1.2698053878977094e6, -1.247031373637411e8], [1.2430696084351363e6, -1.22706964252195e8], [1.2305470152368096e6, -1.2169121093479735e8], [1.1936800508373226e6, -1.185395203828809e8], [1.193840355679632e6, -1.1852610089907902e8], [1.1736382730102343e6, -1.1669911444584191e8], [1.1425447632113395e6, -1.1367536012806511e8], [1.1264736655901023e6, -1.1204529507804316e8]]  …  [[34.06735036994164, 0.1174563241762398], [34.00826593235557, 0.11704925859874413], [33.97868518607742, 0.11684572580999776], [33.88978803003574, 0.11623512744375591], [33.8897880300356, 0.11623512744375492], [33.8388848010054, 0.1158862140916168], [33.75600333777741, 0.11531922989439221], [33.71129045606438, 0.11501393071127126]], [[33.71129045606438, 0.11501393071127126], [33.111286175422926, 0.1109562557254525], [32.80716928019745, 0.10892741823253999], [31.87741533038597, 0.10284090575380882], [31.87741533038597, 0.10284090575380882], [31.333743255673074, 0.09936289862310531], [30.429565985986695, 0.09371113703571204], [29.931390079291603, 0.09066788079634644]], [[29.931390079291603, 0.09066788079634644], [29.761175721334887, 0.0896395895730862], [29.675702425299068, 0.08912544396145604], [29.417792520702275, 0.08758300712656568], [29.417792520702275, 0.08758300712656568], [29.2693951007883, 0.08670161464948549], [29.02663122591675, 0.08526935187423011], [28.895067425141228, 0.08449813345678492]], [[28.895067425141228, 0.08449813345678492], [28.758403899038697, 0.08370073062348317], [28.6898280141, 0.08330202920683229], [28.483109757430217, 0.08210592495687961], [28.483109757430217, 0.08210592495687961], [28.364308634210985, 0.08142243681404951], [28.170188256676457, 0.08031176858195134], [27.797832448138347, -0.9297602160723988]], [[27.797832448138347, -0.9297602160723988], [26.030199170314006, -0.780000328144288], [25.277019962984756, -0.7293126898909018], [23.107527031577213, -0.5788872627383584], [23.159563473466427, -0.6033074046814156], [22.005200174575197, -0.5133463440533983], [20.391003791840863, -0.432351816360711], [19.586688840851643, -0.3924800173404359]], [[19.586688840851643, -0.3924800173404359], [19.125929839938685, -0.3713531132670189], [18.90621926343602, -0.3619305804573749], [18.257867552467644, -0.3344621948357066], [18.259176692597702, -0.334799059804443], [17.900973177520207, -0.32006523463056624], [17.340542590272587, -0.29847866899931036], [17.04786413039238, -0.28761788356700313]], [[17.04786413039238, -0.28761788356700313], [16.3242453774307, -0.26164276889243376], [15.988481572673644, -0.25091917833381205], [15.002633519420883, -0.2199515449895129], [15.007803163443368, -0.22102195786748935], [14.46885751000141, -0.20458405386035677], [13.64120686484432, -0.18266328425236575], [13.212346856183274, -0.171940325018909]], [[13.212346856183274, -0.171940325018909], [12.704221744268681, -0.15979667575143744], [12.46160824214808, -0.15448568130838045], [11.74035514533846, -0.1390642296829387], [11.742047501193603, -0.13930669319878544], [11.339666854604957, -0.1310822939187008], [10.703156185990803, -0.11922476918130925], [10.366210241124326, -0.11328472818274955]], [[10.366210241124326, -0.11328472818274955], [9.763883958491414, -0.1031413319403854], [9.47275984968753, -0.09872406375391757], [8.58926081751441, -0.08579201555167748], [8.591350953074075, -0.08600848384125344], [8.083268052105018, -0.07901543795540153], [7.247991035238013, -0.06871678309858116], [6.7850683665652705, -0.06338413974229086]], [[6.7850683665652705, -0.06338413974229086], [6.701417003379618, -0.062448337469439605], [6.6595043934235045, -0.0619845343647822], [6.532838824034314, -0.06059075044606307], [6.532841238661442, -0.060590934376008515], [6.459925408189431, -0.059796482618993604], [6.34055116311933, -0.05850842708072013], [6.275788201411815, -0.05781584072390198]]], true, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}([1849.7958097184876, 0.4156588221760513], [1849.09134118721, 0.4221937621150325], [6.7850683665652705, -0.06338413974229086], [6.701417003379618, -0.062448337469439605], [6.6595043934235045, -0.0619845343647822], [6.532838824034314, -0.06059075044606307], [6.532841238661442, -0.060590934376008515], [6.459925408189431, -0.059796482618993604], [6.34055116311933, -0.05850842708072013], [6.275788201411815, -0.05781584072390198], [1.2931770941468877e-7, -9.051245008162246e-10], [1849.7107672816799, 0.4164429506419605], [6.990914285032693e-8, -2.138794523559621e-6], OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}(0.16666666666666666, 0.0625, 0.1875, 0.25, -0.75, -0.75, 3.75, -3.0, 0.5, 0.26895043731778423, -0.7084548104956269, 0.8658892128279884, 0.15462307371928363, 0.06184922948771345, -0.02947695035460993, 0.18500664893617022, 0.4802345261121857, -0.5337849069148937, -0.013090093085106383, 0.7861107753062541, 0.08783068783068783, 0.3006060606060606, 0.22777777777777777, 0.027777777777777776, 0.06218596218596219, 0.2938217338217338, 0.16666666666666666, 0.25, 0.5, 0.5, 0.6428571428571429, 0.875, -0.19894179894179895, 0.9115151515151515, -1.9777777777777779, -0.1111111111111111, 1.67013727013727, -0.2938217338217338, 1.892063492063492, -6.067155067155067, 7.282458282458283, -4.0195360195360195, -7.214545454545455, 20.676923076923078, -20.31142191142191, 7.14965034965035, 7.866666666666666, -18.78205128205128, 13.508547008547009, -2.3653846153846154, 2.0, -5.294871794871795, 4.534188034188034, -1.2115384615384615, -1.4924630924630924, 1.5785667324128863, 1.1958838881915805, -1.219801565955412, -7.051721611721612, 16.273203719357564, -11.978886071193763, 3.0512256973795435, 4.0, -8.384615384615385, 5.769230769230769, -1.3846153846153846))), true, 0, DiffEqBase.DEStats
Number of function 1 evaluations:                  927
Number of function 2 evaluations:                  0
Number of W matrix evaluations:                    0
Number of linear solves:                           0
Number of Jacobians created:                       0
Number of nonlinear solver iterations:             0
Number of nonlinear solver convergence failures:   0
Number of rootfind condition calls:                0
Number of accepted steps:                          88
Number of rejected steps:                          44, :Success), SciMLBase.ODESolution{Float64, 2, Vector{Vector{Float64}}, Nothing, Nothing, Vector{Float64}, Vector{Vector{Vector{Float64}}}, SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}, OwrenZen5, OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}, DiffEqBase.DEStats}([[0.0, 0.0], [36.10254341543524, 28950.526545726527], [49.78454880584168, 39922.08490389185], [57.563823622059566, 46160.26096541256], [59.68080700665526, 47857.863214077064], [60.00191455833749, 48115.3583362121], [63.15919393411739, 47389.54821161078], [70.09121040649096, 45698.35575703346], [78.77951633095715, 43447.703935887585], [89.0368710051686, 40695.427611298284]  …  [1837.3438503109944, 0.8433947122057158], [1845.7948211091527, 0.6979687632219495], [1855.471849159804, 0.5668576370971019], [1864.5090222247275, 0.4704922743237069], [1873.8743407814427, 0.3908482280886043], [1883.0192858448245, 0.3283514569495861], [1892.1092263883431, 0.2777586828850508], [1900.8362612900953, 0.23755532337615118], [1908.9196172776406, 0.20593526073672488], [1915.21464875939, 0.1840215325583278]], nothing, nothing, [0.0, 8.56648549282766e-6, 1.1812980578395823e-5, 1.3658863505726938e-5, 1.4161185865091524e-5, 1.4237378954798664e-5, 1.4999309851870076e-5, 1.6764696614062882e-5, 1.9168447644388215e-5, 2.230431929948107e-5  …  5.462931243989206, 5.750770805226568, 6.131593659670362, 6.5455572575485705, 7.046494437169255, 7.6234920561778985, 8.309417102310476, 9.117324296406762, 10.082487192835861, 11.18], [[[0.0, 0.0]], [[4.214394566177089e6, 3.379511584937933e9], [4.21439431337906e6, 3.3795111795018353e9], [4.214394186980038e6, 3.379510976783785e9], [4.2143938077829555e6, 3.3795103686296415e9], [4.2143938077829555e6, 3.3795103686296415e9], [4.214393591098954e6, 3.379510021113084e9], [4.214393238987266e6, 3.379509456398421e9], [4.214393049388685e6, 3.3795091523213468e9]], [[4.214393049388685e6, 3.3795091523213468e9], [4.214392953584189e6, 3.379508998670672e9], [4.214392905681906e6, 3.3795089218452806e9], [4.214392761975186e6, 3.3795086913693156e9], [4.214392761975186e6, 3.3795086913693156e9], [4.214392679857039e6, 3.379508559668735e9], [4.214392546415048e6, 3.3795083456552916e9], [4.214392474561667e6, 3.3795082304172845e9]], [[4.214392474561667e6, 3.3795082304172845e9], [4.214392420089411e6, 3.379508143055019e9], [4.214392392853283e6, 3.379508099373888e9], [4.214392311144899e6, 3.3795079683304915e9], [4.214392311144899e6, 3.3795079683304915e9], [4.214392264454391e6, 3.3795078934485493e9], [4.214392188582317e6, 3.379507771765396e9], [4.214392147728183e6, 3.3795077062437963e9]], [[4.214392147728183e6, 3.3795077062437963e9], [4.214392132904521e6, 3.3795076824697e9], [4.21439212549272e6, 3.3795076705827e9], [4.214392103257316e6, 3.379507634921701e9], [4.214392103257316e6, 3.379507634921701e9], [4.214392090551372e6, 3.3795076145439878e9], [4.214392069904211e6, 3.3795075814302025e9], [4.21439205878651e6, 3.3795075635997043e9]], [[4.21439205878651e6, 3.3795075635997043e9], [4.21439205653801e6, 3.379507559993574e9], [4.214392055413807e6, 3.3795075581905847e9], [4.214392052041072e6, 3.3795075527814145e9], [4.214392052041072e6, 3.3795075527814145e9], [4.214392050113846e6, 3.3795075496905403e9], [4.214392046982049e6, 3.3795075446677856e9], [4.214305975337522e6, -9.466886048144455e8]], [[4.214305975337522e6, -9.466886048144455e8], [4.1903203611298082e6, -9.490980264816656e8], [4.178534715513605e6, -9.50123544451323e8], [4.1433819597961623e6, -9.529685967609482e8], [4.1433924631738714e6, -9.529466706063285e8], [4.123568618123556e6, -9.543390062172318e8], [4.0917876230429327e6, -9.561906877156491e8], [4.074881712690431e6, -9.570090650250373e8]], [[4.074881712690431e6, -9.570090650250373e8], [4.02322941378132e6, -9.589671677712107e8], [3.998391672420922e6, -9.592563875375967e8], [3.9247799242763356e6, -9.592967864234586e8], [3.924892205573184e6, -9.591013252975683e8], [3.88397127617313e6, -9.584104369450316e8], [3.8195142270768723e6, -9.557218715169106e8], [3.7856960033985605e6, -9.537485490097175e8]], [[3.7856960033985605e6, -9.537485490097175e8], [3.725386761633279e6, -9.494012567842493e8], [3.6966791149696903e6, -9.466332350119133e8], [3.611827518694038e6, -9.374682285534229e8], [3.6120346050775438e6, -9.372469453985538e8], [3.565145011711225e6, -9.314291480773802e8], [3.4919253173533725e6, -9.20576028898313e8], [3.4537397345432425e6, -9.143379280848722e8]], [[3.4537397345432425e6, -9.143379280848722e8], [3.3887432447257102e6, -9.028713492404566e8], [3.3580833224482196e6, -8.968974572738178e8], [3.267665019377353e6, -8.782521173483591e8], [3.2679764310349897e6, -8.781268990470865e8], [3.2182530144449887e6, -8.671926733962803e8], [3.141226825354091e6, -8.48777828873539e8], [3.101260695659117e6, -8.387426426854272e8]]  …  [[37.34013001476098, -0.9765550182525771], [36.18631718588171, -0.8928225811032697], [35.65831899649486, -0.858545684863381], [34.11829881451928, -0.7586624496341955], [34.12953353926299, -0.7629960217899996], [33.29728848817474, -0.7091950788466396], [32.04541620104148, -0.6389531900002168], [31.40723673150323, -0.6045193060724718]], [[31.40723673150323, -0.6045193060724718], [30.672314008566605, -0.5661747163866081], [30.327876594144307, -0.5495872528066309], [29.317362643333336, -0.5012013703189002], [29.32119011641529, -0.5022627059591395], [28.769044685620717, -0.4763234876118407], [27.919615357011644, -0.4396990942079727], [27.481245099622807, -0.4214586883552054]], [[27.481245099622807, -0.4214586883552054], [26.731145578267753, -0.39109065088622036], [26.38258243426983, -0.3782213412949672], [25.362613053639112, -0.3407597484285141], [25.36754477259147, -0.34182944757788014], [24.812755829438082, -0.3217794315370284], [23.96582041625987, -0.294219919305212], [23.530713364539146, -0.2805972628757362]], [[23.530713364539146, -0.2805972628757362], [22.919314842240816, -0.2620181656537412], [22.633231845298766, -0.25402717879944914], [21.79462710854168, -0.23076547488144994], [21.797906369132924, -0.23130335211694517], [21.340171935229186, -0.21886369052213012], [20.636820319660846, -0.20141905425598522], [20.274070372009355, -0.19275739978441572]], [[20.274070372009355, -0.19275739978441572], [19.70589850473943, -0.17957847295285148], [19.440263581958398, -0.17393340467496624], [18.66176453175088, -0.1575232213089175], [18.664870101648486, -0.15791680408688918], [18.240042665555602, -0.14915552060940854], [17.587432062817715, -0.13692789181302512], [17.250815458406784, -0.13086902358960192]], [[17.250815458406784, -0.13086902358960192], [16.748527479862656, -0.12210074427527338], [16.5128236243633, -0.11832542011581233], [15.821030454680047, -0.10735851453703554], [15.823495076742786, -0.10759753144961648], [15.444983935241035, -0.1017490530484782], [14.86106053346125, -0.09352616550647566], [14.558927631766172, -0.08944618114859407]], [[14.558927631766172, -0.08944618114859407], [14.09264214603625, -0.08334825402190231], [13.873200268916209, -0.08072067282901224], [13.227794584824348, -0.07309597500714779], [13.229935133751734, -0.07325530414823454], [12.875639922171324, -0.06919510000659229], [12.326595032209585, -0.06347298756013928], [12.041339714609668, -0.060633257576525365]], [[12.041339714609668, -0.060633257576525365], [11.603483646351425, -0.05642540257239216], [11.396117214369552, -0.054604114894266115], [10.783179522617749, -0.0493189795565593], [10.784942294281196, -0.04941883912204], [10.445915554493139, -0.046604427135538584], [9.915351320851101, -0.04260374379392734], [9.637169693138874, -0.04061113357186889]], [[9.637169693138874, -0.04061113357186889], [9.200425261824227, -0.03760531594148452], [8.991205784995962, -0.03629437621943969], [8.365528155027315, -0.03247447267565241], [8.367007083839466, -0.03253731828537888], [8.014919531457014, -0.03049043956866228], [7.451991251066804, -0.027524532382121842], [7.1502886743636775, -0.02602525553717353]], [[7.1502886743636775, -0.02602525553717353], [6.689492129168893, -0.023834389502829477], [6.462199241178457, -0.022846176427282937], [5.759195868020039, -0.019885716199692264], [5.760286973585726, -0.01991808677251799], [5.34388581785347, -0.018258413304610678], [4.632041047712801, -0.015638669139393033], [4.219441810255534, -0.014191083010508176]]], SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [0.0, 0.0], (0.0, 11.18), Any[GasChromatographySimulator.Column(11.18, 0.000104, [0.000104], 1.04e-7, [1.04e-7], "FS5ms", "H2"), GasChromatographySimulator.Program{GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}}([0.0, 60.0, 1680.0, 60.0, 360.0, 60.0], [40.0, 40.0, 180.0, 180.0, 300.0, 300.0], [411564.0, 411564.0, 411564.0, 411564.0, 411564.0, 411564.0], [101300.0, 101300.0, 101300.0, 101300.0, 101300.0, 101300.0], GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}([0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0]), [0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0], 11181×6 extrapolate(interpolate((0.0:0.001:11.18,::Vector{Float64}), ::Matrix{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
   ⋮                                       ⋮
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0), GasChromatographySimulator.Substance("C22", "629-97-0", 556.7, 41.89, 183.35, 0.001, "Leppert2020b, alkane, alkanes", 7.879073502414208e-5, 0.0, 0.0), GasChromatographySimulator.Options(OwrenZen5(), 1.0e-6, 0.001, "inlet", true, true, "Blumberg", "Pressure")], Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}(), SciMLBase.StandardODEProblem()), OwrenZen5(), OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [[0.0, 0.0], [36.10254341543524, 28950.526545726527], [49.78454880584168, 39922.08490389185], [57.563823622059566, 46160.26096541256], [59.68080700665526, 47857.863214077064], [60.00191455833749, 48115.3583362121], [63.15919393411739, 47389.54821161078], [70.09121040649096, 45698.35575703346], [78.77951633095715, 43447.703935887585], [89.0368710051686, 40695.427611298284]  …  [1837.3438503109944, 0.8433947122057158], [1845.7948211091527, 0.6979687632219495], [1855.471849159804, 0.5668576370971019], [1864.5090222247275, 0.4704922743237069], [1873.8743407814427, 0.3908482280886043], [1883.0192858448245, 0.3283514569495861], [1892.1092263883431, 0.2777586828850508], [1900.8362612900953, 0.23755532337615118], [1908.9196172776406, 0.20593526073672488], [1915.21464875939, 0.1840215325583278]], [0.0, 8.56648549282766e-6, 1.1812980578395823e-5, 1.3658863505726938e-5, 1.4161185865091524e-5, 1.4237378954798664e-5, 1.4999309851870076e-5, 1.6764696614062882e-5, 1.9168447644388215e-5, 2.230431929948107e-5  …  5.462931243989206, 5.750770805226568, 6.131593659670362, 6.5455572575485705, 7.046494437169255, 7.6234920561778985, 8.309417102310476, 9.117324296406762, 10.082487192835861, 11.18], [[[0.0, 0.0]], [[4.214394566177089e6, 3.379511584937933e9], [4.21439431337906e6, 3.3795111795018353e9], [4.214394186980038e6, 3.379510976783785e9], [4.2143938077829555e6, 3.3795103686296415e9], [4.2143938077829555e6, 3.3795103686296415e9], [4.214393591098954e6, 3.379510021113084e9], [4.214393238987266e6, 3.379509456398421e9], [4.214393049388685e6, 3.3795091523213468e9]], [[4.214393049388685e6, 3.3795091523213468e9], [4.214392953584189e6, 3.379508998670672e9], [4.214392905681906e6, 3.3795089218452806e9], [4.214392761975186e6, 3.3795086913693156e9], [4.214392761975186e6, 3.3795086913693156e9], [4.214392679857039e6, 3.379508559668735e9], [4.214392546415048e6, 3.3795083456552916e9], [4.214392474561667e6, 3.3795082304172845e9]], [[4.214392474561667e6, 3.3795082304172845e9], [4.214392420089411e6, 3.379508143055019e9], [4.214392392853283e6, 3.379508099373888e9], [4.214392311144899e6, 3.3795079683304915e9], [4.214392311144899e6, 3.3795079683304915e9], [4.214392264454391e6, 3.3795078934485493e9], [4.214392188582317e6, 3.379507771765396e9], [4.214392147728183e6, 3.3795077062437963e9]], [[4.214392147728183e6, 3.3795077062437963e9], [4.214392132904521e6, 3.3795076824697e9], [4.21439212549272e6, 3.3795076705827e9], [4.214392103257316e6, 3.379507634921701e9], [4.214392103257316e6, 3.379507634921701e9], [4.214392090551372e6, 3.3795076145439878e9], [4.214392069904211e6, 3.3795075814302025e9], [4.21439205878651e6, 3.3795075635997043e9]], [[4.21439205878651e6, 3.3795075635997043e9], [4.21439205653801e6, 3.379507559993574e9], [4.214392055413807e6, 3.3795075581905847e9], [4.214392052041072e6, 3.3795075527814145e9], [4.214392052041072e6, 3.3795075527814145e9], [4.214392050113846e6, 3.3795075496905403e9], [4.214392046982049e6, 3.3795075446677856e9], [4.214305975337522e6, -9.466886048144455e8]], [[4.214305975337522e6, -9.466886048144455e8], [4.1903203611298082e6, -9.490980264816656e8], [4.178534715513605e6, -9.50123544451323e8], [4.1433819597961623e6, -9.529685967609482e8], [4.1433924631738714e6, -9.529466706063285e8], [4.123568618123556e6, -9.543390062172318e8], [4.0917876230429327e6, -9.561906877156491e8], [4.074881712690431e6, -9.570090650250373e8]], [[4.074881712690431e6, -9.570090650250373e8], [4.02322941378132e6, -9.589671677712107e8], [3.998391672420922e6, -9.592563875375967e8], [3.9247799242763356e6, -9.592967864234586e8], [3.924892205573184e6, -9.591013252975683e8], [3.88397127617313e6, -9.584104369450316e8], [3.8195142270768723e6, -9.557218715169106e8], [3.7856960033985605e6, -9.537485490097175e8]], [[3.7856960033985605e6, -9.537485490097175e8], [3.725386761633279e6, -9.494012567842493e8], [3.6966791149696903e6, -9.466332350119133e8], [3.611827518694038e6, -9.374682285534229e8], [3.6120346050775438e6, -9.372469453985538e8], [3.565145011711225e6, -9.314291480773802e8], [3.4919253173533725e6, -9.20576028898313e8], [3.4537397345432425e6, -9.143379280848722e8]], [[3.4537397345432425e6, -9.143379280848722e8], [3.3887432447257102e6, -9.028713492404566e8], [3.3580833224482196e6, -8.968974572738178e8], [3.267665019377353e6, -8.782521173483591e8], [3.2679764310349897e6, -8.781268990470865e8], [3.2182530144449887e6, -8.671926733962803e8], [3.141226825354091e6, -8.48777828873539e8], [3.101260695659117e6, -8.387426426854272e8]]  …  [[37.34013001476098, -0.9765550182525771], [36.18631718588171, -0.8928225811032697], [35.65831899649486, -0.858545684863381], [34.11829881451928, -0.7586624496341955], [34.12953353926299, -0.7629960217899996], [33.29728848817474, -0.7091950788466396], [32.04541620104148, -0.6389531900002168], [31.40723673150323, -0.6045193060724718]], [[31.40723673150323, -0.6045193060724718], [30.672314008566605, -0.5661747163866081], [30.327876594144307, -0.5495872528066309], [29.317362643333336, -0.5012013703189002], [29.32119011641529, -0.5022627059591395], [28.769044685620717, -0.4763234876118407], [27.919615357011644, -0.4396990942079727], [27.481245099622807, -0.4214586883552054]], [[27.481245099622807, -0.4214586883552054], [26.731145578267753, -0.39109065088622036], [26.38258243426983, -0.3782213412949672], [25.362613053639112, -0.3407597484285141], [25.36754477259147, -0.34182944757788014], [24.812755829438082, -0.3217794315370284], [23.96582041625987, -0.294219919305212], [23.530713364539146, -0.2805972628757362]], [[23.530713364539146, -0.2805972628757362], [22.919314842240816, -0.2620181656537412], [22.633231845298766, -0.25402717879944914], [21.79462710854168, -0.23076547488144994], [21.797906369132924, -0.23130335211694517], [21.340171935229186, -0.21886369052213012], [20.636820319660846, -0.20141905425598522], [20.274070372009355, -0.19275739978441572]], [[20.274070372009355, -0.19275739978441572], [19.70589850473943, -0.17957847295285148], [19.440263581958398, -0.17393340467496624], [18.66176453175088, -0.1575232213089175], [18.664870101648486, -0.15791680408688918], [18.240042665555602, -0.14915552060940854], [17.587432062817715, -0.13692789181302512], [17.250815458406784, -0.13086902358960192]], [[17.250815458406784, -0.13086902358960192], [16.748527479862656, -0.12210074427527338], [16.5128236243633, -0.11832542011581233], [15.821030454680047, -0.10735851453703554], [15.823495076742786, -0.10759753144961648], [15.444983935241035, -0.1017490530484782], [14.86106053346125, -0.09352616550647566], [14.558927631766172, -0.08944618114859407]], [[14.558927631766172, -0.08944618114859407], [14.09264214603625, -0.08334825402190231], [13.873200268916209, -0.08072067282901224], [13.227794584824348, -0.07309597500714779], [13.229935133751734, -0.07325530414823454], [12.875639922171324, -0.06919510000659229], [12.326595032209585, -0.06347298756013928], [12.041339714609668, -0.060633257576525365]], [[12.041339714609668, -0.060633257576525365], [11.603483646351425, -0.05642540257239216], [11.396117214369552, -0.054604114894266115], [10.783179522617749, -0.0493189795565593], [10.784942294281196, -0.04941883912204], [10.445915554493139, -0.046604427135538584], [9.915351320851101, -0.04260374379392734], [9.637169693138874, -0.04061113357186889]], [[9.637169693138874, -0.04061113357186889], [9.200425261824227, -0.03760531594148452], [8.991205784995962, -0.03629437621943969], [8.365528155027315, -0.03247447267565241], [8.367007083839466, -0.03253731828537888], [8.014919531457014, -0.03049043956866228], [7.451991251066804, -0.027524532382121842], [7.1502886743636775, -0.02602525553717353]], [[7.1502886743636775, -0.02602525553717353], [6.689492129168893, -0.023834389502829477], [6.462199241178457, -0.022846176427282937], [5.759195868020039, -0.019885716199692264], [5.760286973585726, -0.01991808677251799], [5.34388581785347, -0.018258413304610678], [4.632041047712801, -0.015638669139393033], [4.219441810255534, -0.014191083010508176]]], true, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}([1915.21464875939, 0.1840215325583278], [1908.9196172776406, 0.20593526073672488], [7.1502886743636775, -0.02602525553717353], [6.689492129168893, -0.023834389502829477], [6.462199241178457, -0.022846176427282937], [5.759195868020039, -0.019885716199692264], [5.760286973585726, -0.01991808677251799], [5.34388581785347, -0.018258413304610678], [4.632041047712801, -0.015638669139393033], [4.219441810255534, -0.014191083010508176], [0.0016334030701333454, -3.898517081752847e-6], [1914.6063960304882, 0.1860794884487537], [0.0008528559544672721, -0.018839307848616326], OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}(0.16666666666666666, 0.0625, 0.1875, 0.25, -0.75, -0.75, 3.75, -3.0, 0.5, 0.26895043731778423, -0.7084548104956269, 0.8658892128279884, 0.15462307371928363, 0.06184922948771345, -0.02947695035460993, 0.18500664893617022, 0.4802345261121857, -0.5337849069148937, -0.013090093085106383, 0.7861107753062541, 0.08783068783068783, 0.3006060606060606, 0.22777777777777777, 0.027777777777777776, 0.06218596218596219, 0.2938217338217338, 0.16666666666666666, 0.25, 0.5, 0.5, 0.6428571428571429, 0.875, -0.19894179894179895, 0.9115151515151515, -1.9777777777777779, -0.1111111111111111, 1.67013727013727, -0.2938217338217338, 1.892063492063492, -6.067155067155067, 7.282458282458283, -4.0195360195360195, -7.214545454545455, 20.676923076923078, -20.31142191142191, 7.14965034965035, 7.866666666666666, -18.78205128205128, 13.508547008547009, -2.3653846153846154, 2.0, -5.294871794871795, 4.534188034188034, -1.2115384615384615, -1.4924630924630924, 1.5785667324128863, 1.1958838881915805, -1.219801565955412, -7.051721611721612, 16.273203719357564, -11.978886071193763, 3.0512256973795435, 4.0, -8.384615384615385, 5.769230769230769, -1.3846153846153846))), true, 0, DiffEqBase.DEStats
Number of function 1 evaluations:                  843
Number of function 2 evaluations:                  0
Number of W matrix evaluations:                    0
Number of linear solves:                           0
Number of Jacobians created:                       0
Number of nonlinear solver iterations:             0
Number of nonlinear solver convergence failures:   0
Number of rootfind condition calls:                0
Number of accepted steps:                          92
Number of rejected steps:                          28, :Success), SciMLBase.ODESolution{Float64, 2, Vector{Vector{Float64}}, Nothing, Nothing, Vector{Float64}, Vector{Vector{Vector{Float64}}}, SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}, OwrenZen5, OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}, DiffEqBase.DEStats}([[0.0, 0.0], [34.34293416780477, 72046.53197204512], [63.398246612273994, 133000.3872449004], [112.53401939604558, 89535.90269292975], [128.09851203361546, 78004.91903185604], [151.55027851647276, 63013.448847105945], [168.38640902976195, 53918.37218237486], [187.0664153959642, 45289.73878889312], [203.9423668879847, 38664.056072035426], [221.22175495148875, 32879.89461960968]  …  [1882.4387299638095, 0.47177562957679137], [1892.029074249882, 0.3936282021058338], [1901.698717883373, 0.3307017819780711], [1911.4980808124437, 0.2793975069945448], [1921.3420304218967, 0.23758321013499256], [1931.1655200375017, 0.20334790049742762], [1940.804738258611, 0.1753625586850955], [1949.9775074829133, 0.15266297989918304], [1958.0794820973697, 0.13489797231284562], [1961.0467079870948, 0.1286864146226903]], nothing, nothing, [0.0, 3.179189625485196e-6, 5.868894553595075e-6, 1.2133723234664337e-5, 1.4922299157110278e-5, 2.0099799532910173e-5, 2.4686540782453472e-5, 3.08055484078781e-5, 3.743577190012287e-5, 4.550611928635955e-5  …  4.558940710422597, 4.944830025205526, 5.39512001436814, 5.9260595917372125, 6.5516554667131235, 7.292852986241323, 8.173700652316567, 9.22674232577817, 10.49918043972625, 11.18], [[[0.0, 0.0]], [[1.0802418385511627e7, 2.2661920200555973e10], [1.0802418145034807e7, 2.266191919158441e10], [1.080241802479639e7, 2.2661918687098614e10], [1.0802417664081145e7, 2.2661917173641277e10], [1.0802417664081145e7, 2.2661917173641277e10], [1.0802417457958141e7, 2.2661916308808502e10], [1.080241712300825e7, 2.2661914903455246e10], [1.0802416942650728e7, 2.2661914146727066e10]], [[1.0802416942650728e7, 2.2661914146727066e10], [1.0802416739198834e7, 2.266191329310155e10], [1.0802416637472944e7, 2.2661912866289043e10], [1.0802416332295267e7, 2.2661911585851517e10], [1.0802416332295267e7, 2.2661911585851517e10], [1.0802416157907961e7, 2.266191085417268e10], [1.0802415874528738e7, 2.2661909665195236e10], [1.040105534088417e7, -9.82073538559444e9]], [[1.040105534088417e7, -9.82073538559444e9], [9.22107070517991e6, -8.62483387064911e9], [8.818734220894534e6, -8.176759272195179e9], [7.621183352837783e6, -6.708394166771442e9], [7.816982928295134e6, -6.99000688692487e9], [7.089634801442126e6, -6.034567425912561e9], [6.414324595541615e6, -5.172715214636343e9], [6.074483474675806e6, -4.747656292070301e9]], [[6.074483474675806e6, -4.747656292070301e9], [5.892826960425775e6, -4.516669951611319e9], [5.810092418470201e6, -4.416124131714736e9], [5.567866743624926e6, -4.114492845249196e9], [5.570061063710761e6, -4.1238903002644234e9], [5.43880589786829e6, -3.9562617389196224e9], [5.242183556702517e6, -3.7192946605105476e9], [5.141938800096481e6, -3.5987870334882135e9]], [[5.141938800096481e6, -3.5987870334882135e9], [4.904909430408639e6, -3.3133186958924513e9], [4.802482300426672e6, -3.200384585114933e9], [4.504653385519294e6, -2.8569108488641057e9], [4.511421152154601e6, -2.8864404281211524e9], [4.351610407309388e6, -2.6872080568454857e9], [4.125944671477054e6, -2.448212971464078e9], [4.013157045085146e6, -2.328008215669781e9]], [[4.013157045085146e6, -2.328008215669781e9], [3.8862419466998708e6, -2.1947745898579593e9], [3.828758383707906e6, -2.1382138334137936e9], [3.660625538187333e6, -1.9690713809571834e9], [3.6623392711048964e6, -1.9758627155187974e9], [3.5713932889717715e6, -1.8819299579730854e9], [3.435929148148729e6, -1.753614247154004e9], [3.367035349725438e6, -1.6888861823061807e9]], [[3.367035349725438e6, -1.6888861823061807e9], [3.2494030261651725e6, -1.579259991800626e9], [3.1966894971490656e6, -1.5337662506860588e9], [3.0427691005466105e6, -1.3975116417341228e9], [3.0447058195060208e6, -1.4045097899397554e9], [2.9616881623930503e6, -1.3283391751528935e9], [2.8394243919170545e6, -1.227956481083881e9], [2.7775231187733896e6, -1.1775356705241969e9]], [[2.7775231187733896e6, -1.1775356705241969e9], [2.6916746467588986e6, -1.1084649212147603e9], [2.6527029345596666e6, -1.0792257316612277e9], [2.538674468905472e6, -9.91986347452733e8], [2.539781907834477e6, -9.954965178496914e8], [2.478060773687478e6, -9.471750223008652e8], [2.385911032863749e6, -8.813625050307623e8], [2.3389997680589925e6, -8.48230689340078e8]], [[2.3389997680589925e6, -8.48230689340078e8], [2.265740584608125e6, -7.970572158810464e8], [2.2325282857764703e6, -7.754908323916273e8], [2.1353747210898534e6, -7.11163256261151e8], [2.1363450372115024e6, -7.138684548990561e8], [2.0837801583232493e6, -6.782251412553991e8], [2.0054090117212126e6, -6.299973077585466e8], [1.9655358231101618e6, -6.057492168910676e8]]  …  [[30.740804142214074, -0.3536318460363545], [29.98426764699045, -0.33038794904878555], [29.631363846122042, -0.3204190593580121], [28.597460276968388, -0.2913320062705558], [28.601972637572317, -0.29206082114657106], [28.038491599381857, -0.2764566779978113], [27.175408223714417, -0.2546677984916394], [26.73118006248059, -0.24384055555512008]], [[26.73118006248059, -0.24384055555512008], [26.053179764681353, -0.22775115723282635], [25.736937129280737, -0.22085505610707584], [24.81071916717544, -0.20074695705269718], [24.814729435528992, -0.20124983902948435], [24.310060982238287, -0.19047128670132318], [23.53708700562212, -0.1754291064804224], [23.139260789060824, -0.1679585958264348]], [[23.139260789060824, -0.1679585958264348], [22.53902994690077, -0.15698814788513044], [22.258731679744074, -0.15227747710673117], [21.437704291499866, -0.13855020895000916], [21.44110218261834, -0.13888075785589116], [20.99353115151624, -0.13152901641045395], [20.30717690856097, -0.12124108647808476], [19.953668250514326, -0.11613058941479774]], [[19.953668250514326, -0.11613058941479774], [19.41451764348263, -0.10854697719471933], [19.162513735602214, -0.10528888103516015], [18.424248693268247, -0.09580225739937226], [18.427196954000443, -0.09602533363476093], [18.02453163241435, -0.09095031835223687], [17.40633077333095, -0.08384022998723456], [17.087657180691984, -0.08030930086279715]], [[17.087657180691984, -0.08030930086279715], [16.601651544281516, -0.0750743012681005], [16.374089630195826, -0.07282222569164742], [15.70697888830421, -0.06627049764417767], [15.70949586564188, -0.06641859739796671], [15.34515594265678, -0.06291796507878107], [14.78453307462356, -0.05800185324858366], [14.495031119866715, -0.05556044451798206]], [[14.495031119866715, -0.05556044451798206], [14.050462129079717, -0.05192083255086128], [13.841760584838303, -0.05035299471465379], [13.22901144687729, -0.04579585679909399], [13.231162896707902, -0.0458942757746261], [12.895662394723965, -0.04346251804985131], [12.377492095109726, -0.04003781409791156], [12.10905846135993, -0.03833663185541511]], [[12.10905846135993, -0.03833663185541511], [11.694436386240127, -0.03579185620029109], [11.498904462522907, -0.03469300091910518], [10.922855356119237, -0.03150029924056693], [10.924672952256007, -0.03156476329336483], [10.60759825495812, -0.029862296933557304], [10.11442595404682, -0.02745194928956318], [9.857293720756582, -0.026252494039576413]], [[9.857293720756582, -0.026252494039576413], [9.455413145108663, -0.024443910297137408], [9.264276764251433, -0.023659070912213923], [8.69672263090384, -0.02137427602715574], [8.698245079019513, -0.021415851479096196], [8.382171604554786, -0.020194311166836745], [7.88326652521902, -0.018443477471116538], [7.61935229174262, -0.017565205865195985]], [[7.61935229174262, -0.017565205865195985], [7.1965019907781045, -0.016214530510195228], [6.991599143974538, -0.015619498658104903], [6.369995009218404, -0.013862488824981192], [6.371282281857758, -0.01388881727289781], [6.013891037049249, -0.01292869071178309], [5.426592507784542, -0.011489829747114235], [5.101859806771271, -0.010735678787475476]], [[5.101859806771271, -0.010735678787475476], [4.864256946413874, -0.010198964636589427], [4.744301553880693, -0.00993771779490392], [4.372118536289125, -0.00913604348880188], [4.372226573918654, -0.009137638861603202], [4.150750417364882, -0.008671069787983706], [3.773064798534283, -0.007893757323399638], [3.55790891935728, -0.0074575277680203125]]], SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [0.0, 0.0], (0.0, 11.18), Any[GasChromatographySimulator.Column(11.18, 0.000104, [0.000104], 1.04e-7, [1.04e-7], "FS5ms", "H2"), GasChromatographySimulator.Program{GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}}([0.0, 60.0, 1680.0, 60.0, 360.0, 60.0], [40.0, 40.0, 180.0, 180.0, 300.0, 300.0], [411564.0, 411564.0, 411564.0, 411564.0, 411564.0, 411564.0], [101300.0, 101300.0, 101300.0, 101300.0, 101300.0, 101300.0], GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}([0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0]), [0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0], 11181×6 extrapolate(interpolate((0.0:0.001:11.18,::Vector{Float64}), ::Matrix{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
   ⋮                                       ⋮
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0), GasChromatographySimulator.Substance("C23", "638-67-5", 566.26, 42.25, 188.99, 0.001, "Leppert2020b, alkane, alkanes", 7.693149436827684e-5, 0.0, 0.0), GasChromatographySimulator.Options(OwrenZen5(), 1.0e-6, 0.001, "inlet", true, true, "Blumberg", "Pressure")], Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}(), SciMLBase.StandardODEProblem()), OwrenZen5(), OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [[0.0, 0.0], [34.34293416780477, 72046.53197204512], [63.398246612273994, 133000.3872449004], [112.53401939604558, 89535.90269292975], [128.09851203361546, 78004.91903185604], [151.55027851647276, 63013.448847105945], [168.38640902976195, 53918.37218237486], [187.0664153959642, 45289.73878889312], [203.9423668879847, 38664.056072035426], [221.22175495148875, 32879.89461960968]  …  [1882.4387299638095, 0.47177562957679137], [1892.029074249882, 0.3936282021058338], [1901.698717883373, 0.3307017819780711], [1911.4980808124437, 0.2793975069945448], [1921.3420304218967, 0.23758321013499256], [1931.1655200375017, 0.20334790049742762], [1940.804738258611, 0.1753625586850955], [1949.9775074829133, 0.15266297989918304], [1958.0794820973697, 0.13489797231284562], [1961.0467079870948, 0.1286864146226903]], [0.0, 3.179189625485196e-6, 5.868894553595075e-6, 1.2133723234664337e-5, 1.4922299157110278e-5, 2.0099799532910173e-5, 2.4686540782453472e-5, 3.08055484078781e-5, 3.743577190012287e-5, 4.550611928635955e-5  …  4.558940710422597, 4.944830025205526, 5.39512001436814, 5.9260595917372125, 6.5516554667131235, 7.292852986241323, 8.173700652316567, 9.22674232577817, 10.49918043972625, 11.18], [[[0.0, 0.0]], [[1.0802418385511627e7, 2.2661920200555973e10], [1.0802418145034807e7, 2.266191919158441e10], [1.080241802479639e7, 2.2661918687098614e10], [1.0802417664081145e7, 2.2661917173641277e10], [1.0802417664081145e7, 2.2661917173641277e10], [1.0802417457958141e7, 2.2661916308808502e10], [1.080241712300825e7, 2.2661914903455246e10], [1.0802416942650728e7, 2.2661914146727066e10]], [[1.0802416942650728e7, 2.2661914146727066e10], [1.0802416739198834e7, 2.266191329310155e10], [1.0802416637472944e7, 2.2661912866289043e10], [1.0802416332295267e7, 2.2661911585851517e10], [1.0802416332295267e7, 2.2661911585851517e10], [1.0802416157907961e7, 2.266191085417268e10], [1.0802415874528738e7, 2.2661909665195236e10], [1.040105534088417e7, -9.82073538559444e9]], [[1.040105534088417e7, -9.82073538559444e9], [9.22107070517991e6, -8.62483387064911e9], [8.818734220894534e6, -8.176759272195179e9], [7.621183352837783e6, -6.708394166771442e9], [7.816982928295134e6, -6.99000688692487e9], [7.089634801442126e6, -6.034567425912561e9], [6.414324595541615e6, -5.172715214636343e9], [6.074483474675806e6, -4.747656292070301e9]], [[6.074483474675806e6, -4.747656292070301e9], [5.892826960425775e6, -4.516669951611319e9], [5.810092418470201e6, -4.416124131714736e9], [5.567866743624926e6, -4.114492845249196e9], [5.570061063710761e6, -4.1238903002644234e9], [5.43880589786829e6, -3.9562617389196224e9], [5.242183556702517e6, -3.7192946605105476e9], [5.141938800096481e6, -3.5987870334882135e9]], [[5.141938800096481e6, -3.5987870334882135e9], [4.904909430408639e6, -3.3133186958924513e9], [4.802482300426672e6, -3.200384585114933e9], [4.504653385519294e6, -2.8569108488641057e9], [4.511421152154601e6, -2.8864404281211524e9], [4.351610407309388e6, -2.6872080568454857e9], [4.125944671477054e6, -2.448212971464078e9], [4.013157045085146e6, -2.328008215669781e9]], [[4.013157045085146e6, -2.328008215669781e9], [3.8862419466998708e6, -2.1947745898579593e9], [3.828758383707906e6, -2.1382138334137936e9], [3.660625538187333e6, -1.9690713809571834e9], [3.6623392711048964e6, -1.9758627155187974e9], [3.5713932889717715e6, -1.8819299579730854e9], [3.435929148148729e6, -1.753614247154004e9], [3.367035349725438e6, -1.6888861823061807e9]], [[3.367035349725438e6, -1.6888861823061807e9], [3.2494030261651725e6, -1.579259991800626e9], [3.1966894971490656e6, -1.5337662506860588e9], [3.0427691005466105e6, -1.3975116417341228e9], [3.0447058195060208e6, -1.4045097899397554e9], [2.9616881623930503e6, -1.3283391751528935e9], [2.8394243919170545e6, -1.227956481083881e9], [2.7775231187733896e6, -1.1775356705241969e9]], [[2.7775231187733896e6, -1.1775356705241969e9], [2.6916746467588986e6, -1.1084649212147603e9], [2.6527029345596666e6, -1.0792257316612277e9], [2.538674468905472e6, -9.91986347452733e8], [2.539781907834477e6, -9.954965178496914e8], [2.478060773687478e6, -9.471750223008652e8], [2.385911032863749e6, -8.813625050307623e8], [2.3389997680589925e6, -8.48230689340078e8]], [[2.3389997680589925e6, -8.48230689340078e8], [2.265740584608125e6, -7.970572158810464e8], [2.2325282857764703e6, -7.754908323916273e8], [2.1353747210898534e6, -7.11163256261151e8], [2.1363450372115024e6, -7.138684548990561e8], [2.0837801583232493e6, -6.782251412553991e8], [2.0054090117212126e6, -6.299973077585466e8], [1.9655358231101618e6, -6.057492168910676e8]]  …  [[30.740804142214074, -0.3536318460363545], [29.98426764699045, -0.33038794904878555], [29.631363846122042, -0.3204190593580121], [28.597460276968388, -0.2913320062705558], [28.601972637572317, -0.29206082114657106], [28.038491599381857, -0.2764566779978113], [27.175408223714417, -0.2546677984916394], [26.73118006248059, -0.24384055555512008]], [[26.73118006248059, -0.24384055555512008], [26.053179764681353, -0.22775115723282635], [25.736937129280737, -0.22085505610707584], [24.81071916717544, -0.20074695705269718], [24.814729435528992, -0.20124983902948435], [24.310060982238287, -0.19047128670132318], [23.53708700562212, -0.1754291064804224], [23.139260789060824, -0.1679585958264348]], [[23.139260789060824, -0.1679585958264348], [22.53902994690077, -0.15698814788513044], [22.258731679744074, -0.15227747710673117], [21.437704291499866, -0.13855020895000916], [21.44110218261834, -0.13888075785589116], [20.99353115151624, -0.13152901641045395], [20.30717690856097, -0.12124108647808476], [19.953668250514326, -0.11613058941479774]], [[19.953668250514326, -0.11613058941479774], [19.41451764348263, -0.10854697719471933], [19.162513735602214, -0.10528888103516015], [18.424248693268247, -0.09580225739937226], [18.427196954000443, -0.09602533363476093], [18.02453163241435, -0.09095031835223687], [17.40633077333095, -0.08384022998723456], [17.087657180691984, -0.08030930086279715]], [[17.087657180691984, -0.08030930086279715], [16.601651544281516, -0.0750743012681005], [16.374089630195826, -0.07282222569164742], [15.70697888830421, -0.06627049764417767], [15.70949586564188, -0.06641859739796671], [15.34515594265678, -0.06291796507878107], [14.78453307462356, -0.05800185324858366], [14.495031119866715, -0.05556044451798206]], [[14.495031119866715, -0.05556044451798206], [14.050462129079717, -0.05192083255086128], [13.841760584838303, -0.05035299471465379], [13.22901144687729, -0.04579585679909399], [13.231162896707902, -0.0458942757746261], [12.895662394723965, -0.04346251804985131], [12.377492095109726, -0.04003781409791156], [12.10905846135993, -0.03833663185541511]], [[12.10905846135993, -0.03833663185541511], [11.694436386240127, -0.03579185620029109], [11.498904462522907, -0.03469300091910518], [10.922855356119237, -0.03150029924056693], [10.924672952256007, -0.03156476329336483], [10.60759825495812, -0.029862296933557304], [10.11442595404682, -0.02745194928956318], [9.857293720756582, -0.026252494039576413]], [[9.857293720756582, -0.026252494039576413], [9.455413145108663, -0.024443910297137408], [9.264276764251433, -0.023659070912213923], [8.69672263090384, -0.02137427602715574], [8.698245079019513, -0.021415851479096196], [8.382171604554786, -0.020194311166836745], [7.88326652521902, -0.018443477471116538], [7.61935229174262, -0.017565205865195985]], [[7.61935229174262, -0.017565205865195985], [7.1965019907781045, -0.016214530510195228], [6.991599143974538, -0.015619498658104903], [6.369995009218404, -0.013862488824981192], [6.371282281857758, -0.01388881727289781], [6.013891037049249, -0.01292869071178309], [5.426592507784542, -0.011489829747114235], [5.101859806771271, -0.010735678787475476]], [[5.101859806771271, -0.010735678787475476], [4.864256946413874, -0.010198964636589427], [4.744301553880693, -0.00993771779490392], [4.372118536289125, -0.00913604348880188], [4.372226573918654, -0.009137638861603202], [4.150750417364882, -0.008671069787983706], [3.773064798534283, -0.007893757323399638], [3.55790891935728, -0.0074575277680203125]]], true, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}([1961.0467079870948, 0.1286864146226903], [1958.0794820973697, 0.13489797231284562], [5.101859806771271, -0.010735678787475476], [4.864256946413874, -0.010198964636589427], [4.744301553880693, -0.00993771779490392], [4.372118536289125, -0.00913604348880188], [4.372226573918654, -0.009137638861603202], [4.150750417364882, -0.008671069787983706], [3.773064798534283, -0.007893757323399638], [3.55790891935728, -0.0074575277680203125], [0.0002466448746329543, -5.224994853889072e-7], [1960.7345802813652, 0.12934045373285338], [0.00012577199097625288, -0.0038447923577997235], OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}(0.16666666666666666, 0.0625, 0.1875, 0.25, -0.75, -0.75, 3.75, -3.0, 0.5, 0.26895043731778423, -0.7084548104956269, 0.8658892128279884, 0.15462307371928363, 0.06184922948771345, -0.02947695035460993, 0.18500664893617022, 0.4802345261121857, -0.5337849069148937, -0.013090093085106383, 0.7861107753062541, 0.08783068783068783, 0.3006060606060606, 0.22777777777777777, 0.027777777777777776, 0.06218596218596219, 0.2938217338217338, 0.16666666666666666, 0.25, 0.5, 0.5, 0.6428571428571429, 0.875, -0.19894179894179895, 0.9115151515151515, -1.9777777777777779, -0.1111111111111111, 1.67013727013727, -0.2938217338217338, 1.892063492063492, -6.067155067155067, 7.282458282458283, -4.0195360195360195, -7.214545454545455, 20.676923076923078, -20.31142191142191, 7.14965034965035, 7.866666666666666, -18.78205128205128, 13.508547008547009, -2.3653846153846154, 2.0, -5.294871794871795, 4.534188034188034, -1.2115384615384615, -1.4924630924630924, 1.5785667324128863, 1.1958838881915805, -1.219801565955412, -7.051721611721612, 16.273203719357564, -11.978886071193763, 3.0512256973795435, 4.0, -8.384615384615385, 5.769230769230769, -1.3846153846153846))), true, 0, DiffEqBase.DEStats
Number of function 1 evaluations:                  773
Number of function 2 evaluations:                  0
Number of W matrix evaluations:                    0
Number of linear solves:                           0
Number of Jacobians created:                       0
Number of nonlinear solver iterations:             0
Number of nonlinear solver convergence failures:   0
Number of rootfind condition calls:                0
Number of accepted steps:                          93
Number of rejected steps:                          17, :Success), SciMLBase.ODESolution{Float64, 2, Vector{Vector{Float64}}, Nothing, Nothing, Vector{Float64}, Vector{Vector{Vector{Float64}}}, SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}, OwrenZen5, OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}, DiffEqBase.DEStats}([[0.0, 0.0], [41.749574830596664, 209150.35596902767], [56.94840375388953, 285291.01948851615], [59.47460404836557, 297946.3737097875], [60.024205348362905, 300699.6783980094], [65.3519049350047, 290310.43107511615], [73.38568292772673, 274314.02928618906], [82.60561802375767, 255875.29305847763], [93.87758701488464, 233765.53814820576], [106.93791628832427, 209331.73003090502]  …  [1916.330100377079, 0.34571623964010656], [1926.3422412030566, 0.2930702735204862], [1936.527284861165, 0.2497502603024918], [1946.8598003254554, 0.21393838146670224], [1957.2795321134247, 0.184236492412908], [1967.6860130170917, 0.15953847339094684], [1977.894798332547, 0.13901250734129303], [1987.556875740274, 0.12210653460956829], [1995.9154499352064, 0.10875612641799198], [1998.0050633189985, 0.10546193153328894]], nothing, nothing, [0.0, 1.6507433443812502e-6, 2.251692383408796e-6, 2.3515762408670423e-6, 2.3733070189720428e-6, 2.5906148000220467e-6, 2.9444842262721403e-6, 3.3926958397204197e-6, 4.0083560065544935e-6, 4.826622371113294e-6  …  3.935040305042224, 4.357680436464596, 4.856161968805279, 5.446053561263353, 6.146049945932717, 6.979682777471354, 7.976476886482342, 9.175250217125019, 10.63790870231433, 11.18], [[[0.0, 0.0]], [[2.5291379438503448e7, 1.267007201247716e11], [2.5291379146163978e7, 1.267007171957403e11], [2.5291378999993835e7, 1.267007157312205e11], [2.52913785614842e7, 1.2670071133766934e11], [2.52913785614842e7, 1.2670071133766934e11], [2.529137831090726e7, 1.2670070882706866e11], [2.5291377903719738e7, 1.2670070474734262e11], [2.5291377684464913e7, 1.2670070255056706e11]], [[2.5291377684464913e7, 1.2670070255056706e11], [2.5291377578039337e7, 1.2670070148425935e11], [2.5291377524826553e7, 1.2670070095110555e11], [2.5291377365188196e7, 1.2670069935164412e11], [2.5291377365188196e7, 1.2670069935164412e11], [2.5291377273966275e7, 1.2670069843766612e11], [2.529137712573066e7, 1.2670069695245197e11], [2.529137704591148e7, 1.2670069615272124e11]], [[2.529137704591148e7, 1.2670069615272124e11], [2.5291377028222464e7, 1.2670069597549e11], [2.529137701937795e7, 1.2670069588687434e11], [2.529137699284443e7, 1.2670069562102757e11], [2.529137699284443e7, 1.2670069562102757e11], [2.529137697768242e7, 1.2670069546911514e11], [2.5291376953044146e7, 1.267006952222574e11], [2.5291376939777385e7, 1.26700695089334e11]], [[2.5291376939777385e7, 1.26700695089334e11], [2.5291376935928956e7, 1.2670069505077551e11], [2.5291376934004746e7, 1.267006950314963e11], [2.5291376928232096e7, 1.2670069497365851e11], [2.5291376928232096e7, 1.2670069497365851e11], [2.529137692493344e7, 1.2670069494060837e11], [2.5291376919573124e7, 1.2670069488690182e11], [2.528432153090573e7, -4.864197341421152e10]], [[2.528432153090573e7, -4.864197341421152e10], [2.5018923938054748e7, -4.8387579012490845e10], [2.4890431917835273e7, -4.825219751400029e10], [2.450887261973189e7, -4.7828606057244415e10], [2.450926817786812e7, -4.7826588080714035e10], [2.429624229589917e7, -4.757299829546486e10], [2.3958775152623363e7, -4.7139339988401566e10], [2.378096914445999e7, -4.689804983972127e10]], [[2.378096914445999e7, -4.689804983972127e10], [2.340114309088453e7, -4.635614361215076e10], [2.322035423728684e7, -4.607927835508734e10], [2.2685967365589146e7, -4.522253110981714e10], [2.2687278398755122e7, -4.52197273988916e10], [2.2391965850483082e7, -4.472012882309076e10], [2.193083717658301e7, -4.388952262106268e10], [2.1690348279777534e7, -4.3438014465832016e10]], [[2.1690348279777534e7, -4.3438014465832016e10], [2.1292796326519832e7, -4.266415036215059e10], [2.1104960885574687e7, -4.228628696222008e10], [2.0550762285932075e7, -4.113264809623694e10], [2.0552569201764766e7, -4.1135179396992035e10], [2.0247525071799975e7, -4.0477061377894104e10], [1.9774285705496725e7, -3.9421538070588196e10], [1.95285082376709e7, -3.885926251369017e10]], [[1.95285082376709e7, -3.885926251369017e10], [1.908958607406237e7, -3.782866589936577e10], [1.8884892749449562e7, -3.7343829066958176e10], [1.8282764680114843e7, -3.587390958347699e10], [1.828576361602873e7, -3.5887037320890755e10], [1.795643737413351e7, -3.505990339120749e10], [1.7451575703946844e7, -3.3779253305430145e10], [1.7191203604979787e7, -3.310864783879812e10]], [[1.7191203604979787e7, -3.310864783879812e10], [1.6743404933234937e7, -3.193451626320556e10], [1.65369217480769e7, -3.1400362097590775e10], [1.593095692033439e7, -2.978882547654094e10], [1.593506424494156e7, -2.9816704417026314e10], [1.5605223640846234e7, -2.89168494229461e10], [1.5104998077015443e7, -2.7573408904967995e10], [1.4848477583170185e7, -2.6879452122418594e10]]  …  [[29.374282748265568, -0.21428019788336977], [28.640987047312308, -0.20050646645794915], [28.29932500052956, -0.1945993882921079], [27.298795661705316, -0.17734647624273223], [27.303298977493387, -0.17778519602002962], [26.758390555065073, -0.16851696177885878], [25.92468684032771, -0.15557453492416268], [25.495879389352567, -0.14913707151689792]], [[25.495879389352567, -0.14913707151689792], [24.843353066908588, -0.13958656063763072], [24.5392280452202, -0.13548905975325726], [23.64881029609393, -0.12352739963687256], [23.65273820003828, -0.12382708479128351], [23.167826249271215, -0.11740565358049243], [22.42566836349129, -0.10843124689241074], [22.043887936111048, -0.10396806525961774]], [[22.043887936111048, -0.10396806525961774], [21.461978264669117, -0.09733698920150552], [21.190594660439913, -0.09449023378240427], [20.396090787738736, -0.08618473161627702], [20.399494899796608, -0.08638852385942553], [19.966733587738705, -0.08193355716923656], [19.303908841463333, -0.07569984438056016], [18.962782863746114, -0.07260005220230745]], [[18.962782863746114, -0.07260005220230745], [18.440966262903963, -0.06797990579099203], [18.197368874703116, -0.06599516945881459], [17.484090081942288, -0.060208704322711644], [17.487032811208458, -0.060347207497056264], [17.098294641082518, -0.057246577977813726], [16.50215179161375, -0.05290195581198359], [16.19506461830673, -0.05074189713188988]], [[16.19506461830673, -0.05074189713188988], [15.723697206733997, -0.04751393520526591], [15.503283942777939, -0.046126006197970554], [14.857454033951576, -0.04208267022626503], [14.859980527602676, -0.0421762833294545], [14.507534989208805, -0.04001225577011617], [13.965825645456517, -0.03697403587243764], [13.68627465121338, -0.03546357399780646]], [[13.68627465121338, -0.03546357399780646], [13.254999050860148, -0.033198241093066155], [13.052764717503921, -0.03222294887468319], [12.459200363741104, -0.029383721910416296], [12.461353501062307, -0.029446562512094702], [12.136523003785374, -0.027928773281247467], [11.635206263613656, -0.025791402319897072], [11.37558487771023, -0.024728356760887853]], [[11.37558487771023, -0.024728356760887853], [10.97219223735497, -0.023126672780424427], [10.78208344379727, -0.022435473625864052], [10.221940826064609, -0.020423319789910868], [10.223756294356942, -0.020465010553737718], [9.915387571214543, -0.019389732367404593], [9.43569288276118, -0.01786666230044697], [9.18544976919235, -0.017107351850862592]], [[9.18544976919235, -0.017107351850862592], [8.791734682966945, -0.01595348217521741], [8.604381669516345, -0.01545271759587473], [8.047235423739064, -0.013990059635386437], [8.048748703366723, -0.014017266317574419], [7.737800357120496, -0.013232189259816946], [7.245673354271843, -0.012103073687414954], [6.984500986183835, -0.011533882886073668]], [[6.984500986183835, -0.011533882886073668], [6.560434430592709, -0.010645032360692462], [6.35406622995811, -0.010251680762715216], [5.7237109935151524, -0.009077537445407478], [5.725007525192958, -0.009095247339086072], [5.358738418178216, -0.008443460837785889], [4.748186288207962, -0.007444572111070542], [4.404464187976074, -0.006905951447681094]], [[4.404464187976074, -0.006905951447681094], [4.228865743610989, -0.00663572319527962], [4.139881225189348, -0.006501665081090017], [3.8642888472504118, -0.006087478803723898], [3.86432539189366, -0.00608785948479389], [3.7006816820252655, -0.005844204941716428], [3.4229376630503547, -0.005434265194036467], [3.2659927074024826, -0.005203576149321833]]], SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [0.0, 0.0], (0.0, 11.18), Any[GasChromatographySimulator.Column(11.18, 0.000104, [0.000104], 1.04e-7, [1.04e-7], "FS5ms", "H2"), GasChromatographySimulator.Program{GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}}([0.0, 60.0, 1680.0, 60.0, 360.0, 60.0], [40.0, 40.0, 180.0, 180.0, 300.0, 300.0], [411564.0, 411564.0, 411564.0, 411564.0, 411564.0, 411564.0], [101300.0, 101300.0, 101300.0, 101300.0, 101300.0, 101300.0], GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}([0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0]), [0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0], 11181×6 extrapolate(interpolate((0.0:0.001:11.18,::Vector{Float64}), ::Matrix{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
   ⋮                                       ⋮
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0), GasChromatographySimulator.Substance("C24", "646-31-1", 575.2, 42.21, 188.53, 0.001, "Leppert2020b, alkane, alkanes", 7.518755251713027e-5, 0.0, 0.0), GasChromatographySimulator.Options(OwrenZen5(), 1.0e-6, 0.001, "inlet", true, true, "Blumberg", "Pressure")], Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}(), SciMLBase.StandardODEProblem()), OwrenZen5(), OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [[0.0, 0.0], [41.749574830596664, 209150.35596902767], [56.94840375388953, 285291.01948851615], [59.47460404836557, 297946.3737097875], [60.024205348362905, 300699.6783980094], [65.3519049350047, 290310.43107511615], [73.38568292772673, 274314.02928618906], [82.60561802375767, 255875.29305847763], [93.87758701488464, 233765.53814820576], [106.93791628832427, 209331.73003090502]  …  [1916.330100377079, 0.34571623964010656], [1926.3422412030566, 0.2930702735204862], [1936.527284861165, 0.2497502603024918], [1946.8598003254554, 0.21393838146670224], [1957.2795321134247, 0.184236492412908], [1967.6860130170917, 0.15953847339094684], [1977.894798332547, 0.13901250734129303], [1987.556875740274, 0.12210653460956829], [1995.9154499352064, 0.10875612641799198], [1998.0050633189985, 0.10546193153328894]], [0.0, 1.6507433443812502e-6, 2.251692383408796e-6, 2.3515762408670423e-6, 2.3733070189720428e-6, 2.5906148000220467e-6, 2.9444842262721403e-6, 3.3926958397204197e-6, 4.0083560065544935e-6, 4.826622371113294e-6  …  3.935040305042224, 4.357680436464596, 4.856161968805279, 5.446053561263353, 6.146049945932717, 6.979682777471354, 7.976476886482342, 9.175250217125019, 10.63790870231433, 11.18], [[[0.0, 0.0]], [[2.5291379438503448e7, 1.267007201247716e11], [2.5291379146163978e7, 1.267007171957403e11], [2.5291378999993835e7, 1.267007157312205e11], [2.52913785614842e7, 1.2670071133766934e11], [2.52913785614842e7, 1.2670071133766934e11], [2.529137831090726e7, 1.2670070882706866e11], [2.5291377903719738e7, 1.2670070474734262e11], [2.5291377684464913e7, 1.2670070255056706e11]], [[2.5291377684464913e7, 1.2670070255056706e11], [2.5291377578039337e7, 1.2670070148425935e11], [2.5291377524826553e7, 1.2670070095110555e11], [2.5291377365188196e7, 1.2670069935164412e11], [2.5291377365188196e7, 1.2670069935164412e11], [2.5291377273966275e7, 1.2670069843766612e11], [2.529137712573066e7, 1.2670069695245197e11], [2.529137704591148e7, 1.2670069615272124e11]], [[2.529137704591148e7, 1.2670069615272124e11], [2.5291377028222464e7, 1.2670069597549e11], [2.529137701937795e7, 1.2670069588687434e11], [2.529137699284443e7, 1.2670069562102757e11], [2.529137699284443e7, 1.2670069562102757e11], [2.529137697768242e7, 1.2670069546911514e11], [2.5291376953044146e7, 1.267006952222574e11], [2.5291376939777385e7, 1.26700695089334e11]], [[2.5291376939777385e7, 1.26700695089334e11], [2.5291376935928956e7, 1.2670069505077551e11], [2.5291376934004746e7, 1.267006950314963e11], [2.5291376928232096e7, 1.2670069497365851e11], [2.5291376928232096e7, 1.2670069497365851e11], [2.529137692493344e7, 1.2670069494060837e11], [2.5291376919573124e7, 1.2670069488690182e11], [2.528432153090573e7, -4.864197341421152e10]], [[2.528432153090573e7, -4.864197341421152e10], [2.5018923938054748e7, -4.8387579012490845e10], [2.4890431917835273e7, -4.825219751400029e10], [2.450887261973189e7, -4.7828606057244415e10], [2.450926817786812e7, -4.7826588080714035e10], [2.429624229589917e7, -4.757299829546486e10], [2.3958775152623363e7, -4.7139339988401566e10], [2.378096914445999e7, -4.689804983972127e10]], [[2.378096914445999e7, -4.689804983972127e10], [2.340114309088453e7, -4.635614361215076e10], [2.322035423728684e7, -4.607927835508734e10], [2.2685967365589146e7, -4.522253110981714e10], [2.2687278398755122e7, -4.52197273988916e10], [2.2391965850483082e7, -4.472012882309076e10], [2.193083717658301e7, -4.388952262106268e10], [2.1690348279777534e7, -4.3438014465832016e10]], [[2.1690348279777534e7, -4.3438014465832016e10], [2.1292796326519832e7, -4.266415036215059e10], [2.1104960885574687e7, -4.228628696222008e10], [2.0550762285932075e7, -4.113264809623694e10], [2.0552569201764766e7, -4.1135179396992035e10], [2.0247525071799975e7, -4.0477061377894104e10], [1.9774285705496725e7, -3.9421538070588196e10], [1.95285082376709e7, -3.885926251369017e10]], [[1.95285082376709e7, -3.885926251369017e10], [1.908958607406237e7, -3.782866589936577e10], [1.8884892749449562e7, -3.7343829066958176e10], [1.8282764680114843e7, -3.587390958347699e10], [1.828576361602873e7, -3.5887037320890755e10], [1.795643737413351e7, -3.505990339120749e10], [1.7451575703946844e7, -3.3779253305430145e10], [1.7191203604979787e7, -3.310864783879812e10]], [[1.7191203604979787e7, -3.310864783879812e10], [1.6743404933234937e7, -3.193451626320556e10], [1.65369217480769e7, -3.1400362097590775e10], [1.593095692033439e7, -2.978882547654094e10], [1.593506424494156e7, -2.9816704417026314e10], [1.5605223640846234e7, -2.89168494229461e10], [1.5104998077015443e7, -2.7573408904967995e10], [1.4848477583170185e7, -2.6879452122418594e10]]  …  [[29.374282748265568, -0.21428019788336977], [28.640987047312308, -0.20050646645794915], [28.29932500052956, -0.1945993882921079], [27.298795661705316, -0.17734647624273223], [27.303298977493387, -0.17778519602002962], [26.758390555065073, -0.16851696177885878], [25.92468684032771, -0.15557453492416268], [25.495879389352567, -0.14913707151689792]], [[25.495879389352567, -0.14913707151689792], [24.843353066908588, -0.13958656063763072], [24.5392280452202, -0.13548905975325726], [23.64881029609393, -0.12352739963687256], [23.65273820003828, -0.12382708479128351], [23.167826249271215, -0.11740565358049243], [22.42566836349129, -0.10843124689241074], [22.043887936111048, -0.10396806525961774]], [[22.043887936111048, -0.10396806525961774], [21.461978264669117, -0.09733698920150552], [21.190594660439913, -0.09449023378240427], [20.396090787738736, -0.08618473161627702], [20.399494899796608, -0.08638852385942553], [19.966733587738705, -0.08193355716923656], [19.303908841463333, -0.07569984438056016], [18.962782863746114, -0.07260005220230745]], [[18.962782863746114, -0.07260005220230745], [18.440966262903963, -0.06797990579099203], [18.197368874703116, -0.06599516945881459], [17.484090081942288, -0.060208704322711644], [17.487032811208458, -0.060347207497056264], [17.098294641082518, -0.057246577977813726], [16.50215179161375, -0.05290195581198359], [16.19506461830673, -0.05074189713188988]], [[16.19506461830673, -0.05074189713188988], [15.723697206733997, -0.04751393520526591], [15.503283942777939, -0.046126006197970554], [14.857454033951576, -0.04208267022626503], [14.859980527602676, -0.0421762833294545], [14.507534989208805, -0.04001225577011617], [13.965825645456517, -0.03697403587243764], [13.68627465121338, -0.03546357399780646]], [[13.68627465121338, -0.03546357399780646], [13.254999050860148, -0.033198241093066155], [13.052764717503921, -0.03222294887468319], [12.459200363741104, -0.029383721910416296], [12.461353501062307, -0.029446562512094702], [12.136523003785374, -0.027928773281247467], [11.635206263613656, -0.025791402319897072], [11.37558487771023, -0.024728356760887853]], [[11.37558487771023, -0.024728356760887853], [10.97219223735497, -0.023126672780424427], [10.78208344379727, -0.022435473625864052], [10.221940826064609, -0.020423319789910868], [10.223756294356942, -0.020465010553737718], [9.915387571214543, -0.019389732367404593], [9.43569288276118, -0.01786666230044697], [9.18544976919235, -0.017107351850862592]], [[9.18544976919235, -0.017107351850862592], [8.791734682966945, -0.01595348217521741], [8.604381669516345, -0.01545271759587473], [8.047235423739064, -0.013990059635386437], [8.048748703366723, -0.014017266317574419], [7.737800357120496, -0.013232189259816946], [7.245673354271843, -0.012103073687414954], [6.984500986183835, -0.011533882886073668]], [[6.984500986183835, -0.011533882886073668], [6.560434430592709, -0.010645032360692462], [6.35406622995811, -0.010251680762715216], [5.7237109935151524, -0.009077537445407478], [5.725007525192958, -0.009095247339086072], [5.358738418178216, -0.008443460837785889], [4.748186288207962, -0.007444572111070542], [4.404464187976074, -0.006905951447681094]], [[4.404464187976074, -0.006905951447681094], [4.228865743610989, -0.00663572319527962], [4.139881225189348, -0.006501665081090017], [3.8642888472504118, -0.006087478803723898], [3.86432539189366, -0.00608785948479389], [3.7006816820252655, -0.005844204941716428], [3.4229376630503547, -0.005434265194036467], [3.2659927074024826, -0.005203576149321833]]], true, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}([1998.0050633189985, 0.10546193153328894], [1995.9154499352064, 0.10875612641799198], [4.404464187976074, -0.006905951447681094], [4.228865743610989, -0.00663572319527962], [4.139881225189348, -0.006501665081090017], [3.8642888472504118, -0.006087478803723898], [3.86432539189366, -0.00608785948479389], [3.7006816820252655, -0.005844204941716428], [3.4229376630503547, -0.005434265194036467], [3.2659927074024826, -0.005203576149321833], [9.283825828529775e-5, -1.5935362630064966e-7], [1997.7783544373897, 0.10582259497144049], [4.6465453728943634e-5, -0.0014518882134539992], OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}(0.16666666666666666, 0.0625, 0.1875, 0.25, -0.75, -0.75, 3.75, -3.0, 0.5, 0.26895043731778423, -0.7084548104956269, 0.8658892128279884, 0.15462307371928363, 0.06184922948771345, -0.02947695035460993, 0.18500664893617022, 0.4802345261121857, -0.5337849069148937, -0.013090093085106383, 0.7861107753062541, 0.08783068783068783, 0.3006060606060606, 0.22777777777777777, 0.027777777777777776, 0.06218596218596219, 0.2938217338217338, 0.16666666666666666, 0.25, 0.5, 0.5, 0.6428571428571429, 0.875, -0.19894179894179895, 0.9115151515151515, -1.9777777777777779, -0.1111111111111111, 1.67013727013727, -0.2938217338217338, 1.892063492063492, -6.067155067155067, 7.282458282458283, -4.0195360195360195, -7.214545454545455, 20.676923076923078, -20.31142191142191, 7.14965034965035, 7.866666666666666, -18.78205128205128, 13.508547008547009, -2.3653846153846154, 2.0, -5.294871794871795, 4.534188034188034, -1.2115384615384615, -1.4924630924630924, 1.5785667324128863, 1.1958838881915805, -1.219801565955412, -7.051721611721612, 16.273203719357564, -11.978886071193763, 3.0512256973795435, 4.0, -8.384615384615385, 5.769230769230769, -1.3846153846153846))), true, 0, DiffEqBase.DEStats
Number of function 1 evaluations:                  1011
Number of function 2 evaluations:                  0
Number of W matrix evaluations:                    0
Number of linear solves:                           0
Number of Jacobians created:                       0
Number of nonlinear solver iterations:             0
Number of nonlinear solver convergence failures:   0
Number of rootfind condition calls:                0
Number of accepted steps:                          107
Number of rejected steps:                          37, :Success), SciMLBase.ODESolution{Float64, 2, Vector{Vector{Float64}}, Nothing, Nothing, Vector{Float64}, Vector{Vector{Vector{Float64}}}, SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}, OwrenZen5, OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}, DiffEqBase.DEStats}([[0.0, 0.0], [41.5898856647798, 498280.25699128234], [56.69650787798955, 679269.7290052036], [59.18911138990856, 709133.1216540977], [59.90377367513946, 717695.3499864102], [60.02775252207017, 718556.6934934852], [60.0848954000217, 718262.7763513111], [60.65419523583737, 715331.895936915], [64.97888186700739, 692945.4109462799], [72.6797995276503, 652902.7225138433]  …  [1941.404172577088, 0.29680875444656396], [1951.7685109722995, 0.25448622520997316], [1962.3549298899893, 0.21913015124078072], [1973.1331278515543, 0.18948391412134855], [1984.0489065445731, 0.1645393988465549], [1995.0071333996257, 0.14349338201645798], [2005.8385931338182, 0.1257221727728331], [2016.2273336443254, 0.11079078136566117], [2025.5174333373488, 0.09857258380497322], [2029.763501291202, 0.09305365987286494]], nothing, nothing, [0.0, 7.008770248144666e-7, 9.554553790239262e-7, 9.97460990520562e-7, 1.0095045530828565e-6, 1.0115939470568437e-6, 1.0125575710904678e-6, 1.0221938114267088e-6, 1.0975661477119695e-6, 1.2417390138585306e-6  …  3.370592750212601, 3.7910404676543488, 4.28944195655951, 4.881732221409847, 5.587541522351077, 6.431247064914716, 7.443515202226012, 8.664054916894319, 10.151223592778036, 11.18], [[[0.0, 0.0]], [[5.933977688613909e7, 7.109382302774656e11], [5.933977659491751e7, 7.109382232993287e11], [5.933977644930633e7, 7.109382198102504e11], [5.93397760124744e7, 7.109382093430552e11], [5.93397760124744e7, 7.109382093430552e11], [5.93397757628555e7, 7.10938203361785e11], [5.9339775357225865e7, 7.109381936422472e11], [5.933977513880969e7, 7.109381884086445e11]], [[5.933977513880969e7, 7.109381884086445e11], [5.9339775033029765e7, 7.109381858739875e11], [5.933977498013983e7, 7.109381846066597e11], [5.9339774821469955e7, 7.109381808046747e11], [5.9339774821469955e7, 7.109381808046747e11], [5.933977473080147e7, 7.109381786321118e11], [5.933977458346517e7, 7.109381751016974e11], [5.933977450413023e7, 7.109381732007048e11]], [[5.933977450413023e7, 7.109381732007048e11], [5.933977448667647e7, 7.109381727824846e11], [5.933977447794958e7, 7.109381725733744e11], [5.933977445176894e7, 7.109381719460442e11], [5.933977445176894e7, 7.109381719460442e11], [5.933977443680857e7, 7.109381715875696e11], [5.933977441249799e7, 7.10938171005049e11], [5.933977439940766e7, 7.109381706913838e11]], [[5.933977439940766e7, 7.109381706913838e11], [5.9339774394403435e7, 7.109381705714745e11], [5.933977439190133e7, 7.109381705115201e11], [5.933977438439564e7, 7.109381703316716e11], [5.933977438439564e7, 7.109381703316716e11], [5.933977438010566e7, 7.109381702288768e11], [5.933977437313549e7, 7.109381700618604e11], [5.933977436938232e7, 7.109381699719283e11]], [[5.933977436938232e7, 7.109381699719283e11], [5.9339774368514165e7, 7.109381699511259e11], [5.933977436808007e7, 7.109381699407242e11], [5.933977436677784e7, 7.109381699095208e11], [5.933977436677784e7, 7.109381699095208e11], [5.933977436603369e7, 7.109381698916897e11], [5.933110851065493e7, -3.056392951504114e11], [5.932015940720611e7, -3.05090059600426e11]], [[5.932015940720611e7, -3.05090059600426e11], [5.931342744397689e7, -3.0506413489281165e11], [5.9310062624389865e7, -3.0505117083397815e11], [5.929996937468996e7, -3.0501226749896606e11], [5.9299969375860296e7, -3.0501226749439197e11], [5.929420338928932e7, -3.049900304931692e11], [5.928483612179538e7, -3.049538852521791e11], [5.927979346871196e7, -3.049344172566665e11]], [[5.927979346871196e7, -3.049344172566665e11], [5.921260423109342e7, -3.046744497460394e11], [5.917912535600769e7, -3.045443034932633e11], [5.907880787233004e7, -3.0415277876482336e11], [5.9078809037969396e7, -3.0415277428423816e11], [5.9021640589516185e7, -3.039284288913491e11], [5.892898619029814e7, -3.035629158799199e11], [5.887921896737145e7, -3.033656258690082e11]], [[5.887921896737145e7, -3.033656258690082e11], [5.836305190606281e7, -3.0128520123693933e11], [5.81118067639919e7, -3.0023909629352954e11], [5.736455209334512e7, -2.9704733780254956e11], [5.7365088622671105e7, -2.970456605521172e11], [5.694641728222292e7, -2.9519896258241296e11], [5.628025403047765e7, -2.92164124311375e11], [5.592806532620749e7, -2.905171133720742e11]], [[5.592806532620749e7, -2.905171133720742e11], [5.504315338721591e7, -2.86256304995074e11], [5.4621746908176966e7, -2.841561697039585e11], [5.337593791249161e7, -2.7774237420063245e11], [5.337893548819241e7, -2.7774837239803284e11], [5.269027162882612e7, -2.7407454782897314e11], [5.1614454060434386e7, -2.6813217715282935e11], [5.105322282365747e7, -2.649490624232143e11]]  …  [[30.61698074548686, -0.1705522175038945], [29.845249330084815, -0.1598722409139286], [29.48624842195458, -0.15529207498891537], [28.435318604597906, -0.14189244583312965], [28.440283592881986, -0.1422416166709659], [27.868353557323907, -0.13502735502396546], [26.994609181015704, -0.1249539764956374], [26.54559110318237, -0.11993645614868986]], [[26.54559110318237, -0.11993645614868986], [25.85980667489523, -0.11245227117283058], [25.540753447839283, -0.10924207829771965], [24.607043456308904, -0.09985389931393734], [24.611391918742076, -0.10009610550875223], [24.103355736775242, -0.09504421164079555], [23.32713087479079, -0.08798644042723017], [22.928226806812695, -0.08447141322728442]], [[22.928226806812695, -0.08447141322728442], [22.31763502507153, -0.07921707196689312], [22.03345941022016, -0.07696265155050691], [21.201978332001566, -0.07037270608715825], [21.205766443924254, -0.07054029151684918], [20.753355755958093, -0.06699660416531936], [20.06180942632436, -0.06204197288091755], [19.706332075309927, -0.059574760781317904]], [[19.706332075309927, -0.059574760781317904], [19.160786062800543, -0.055878034996509014], [18.906689205378786, -0.05429122307001808], [18.16320012008485, -0.04965545263901096], [18.166479626917262, -0.04977101634193169], [17.76180531498316, -0.04728038239743766], [17.142619594675644, -0.04379419225098271], [16.82412062752984, -0.04205850627896361]], [[16.82412062752984, -0.04205850627896361], [16.333739390830868, -0.03945104209503371], [16.105018628796056, -0.03833108367854611], [15.435480963645643, -0.035061390616048904], [15.438299195611254, -0.035140699815871465], [15.073511937334157, -0.0333859259331146], [14.514304195593295, -0.03092577596922334], [14.226237433676562, -0.02970108146088653]], [[14.226237433676562, -0.02970108146088653], [13.78080875612172, -0.027855602230341413], [13.572546593508788, -0.027062161720734876], [12.962103588919277, -0.024747248322032404], [12.96450363286236, -0.02480129750398203], [12.63116101441157, -0.02356040214545648], [12.118359302769447, -0.02181629296020496], [11.85341989675143, -0.02094787772275008]], [[11.85341989675143, -0.02094787772275008], [11.441193023678142, -0.019633929867060064], [11.247613313751609, -0.019068021710401162], [10.678435644762956, -0.017417239178773542], [10.680456646663837, -0.017453697610367296], [10.368127216895594, -0.016569414121408464], [9.884401349871963, -0.015320624860469057], [9.63296497266416, -0.014697837932744436]], [[9.63296497266416, -0.014697837932744436], [9.237620281443661, -0.013748925980188795], [9.050426838410711, -0.013338528307539631], [8.495935944112079, -0.012138657739582767], [8.497615343483552, -0.012162899609914358], [8.189959892273428, -0.011518488655036348], [7.7066515585110675, -0.010597605106639754], [7.45194781051298, -0.01013473663691887]], [[7.45194781051298, -0.01013473663691887], [7.0417750232934395, -0.009415444878154183], [6.844015658051405, -0.009099969542871107], [6.246286743991629, -0.008163731267374345], [6.247687725643374, -0.008179716492687198], [5.9059167689462155, -0.007665705883629195], [5.348130532239865, -0.006897608187817532], [5.041763796725157, -0.006494191589766552]], [[5.041763796725157, -0.006494191589766552], [4.752229222716623, -0.006121689214742991], [4.606179773603322, -0.005941947359591757], [4.149587297375901, -0.005382317219612856], [4.149834384474731, -0.005384459038723436], [3.875041151954661, -0.005052717052241531], [3.3979850616420135, -0.00448648935109908], [3.118956197262473, -0.004155675468745649]]], SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [0.0, 0.0], (0.0, 11.18), Any[GasChromatographySimulator.Column(11.18, 0.000104, [0.000104], 1.04e-7, [1.04e-7], "FS5ms", "H2"), GasChromatographySimulator.Program{GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}}([0.0, 60.0, 1680.0, 60.0, 360.0, 60.0], [40.0, 40.0, 180.0, 180.0, 300.0, 300.0], [411564.0, 411564.0, 411564.0, 411564.0, 411564.0, 411564.0], [101300.0, 101300.0, 101300.0, 101300.0, 101300.0, 101300.0], GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}([0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0]), [0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0], 11181×6 extrapolate(interpolate((0.0:0.001:11.18,::Vector{Float64}), ::Matrix{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
   ⋮                                       ⋮
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0), GasChromatographySimulator.Substance("C25", "629-99-2", 583.8199999999999, 42.26, 189.51, 0.001, "Leppert2020b, alkane, alkanes", 7.354754525382887e-5, 0.0, 0.0), GasChromatographySimulator.Options(OwrenZen5(), 1.0e-6, 0.001, "inlet", true, true, "Blumberg", "Pressure")], Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}(), SciMLBase.StandardODEProblem()), OwrenZen5(), OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [[0.0, 0.0], [41.5898856647798, 498280.25699128234], [56.69650787798955, 679269.7290052036], [59.18911138990856, 709133.1216540977], [59.90377367513946, 717695.3499864102], [60.02775252207017, 718556.6934934852], [60.0848954000217, 718262.7763513111], [60.65419523583737, 715331.895936915], [64.97888186700739, 692945.4109462799], [72.6797995276503, 652902.7225138433]  …  [1941.404172577088, 0.29680875444656396], [1951.7685109722995, 0.25448622520997316], [1962.3549298899893, 0.21913015124078072], [1973.1331278515543, 0.18948391412134855], [1984.0489065445731, 0.1645393988465549], [1995.0071333996257, 0.14349338201645798], [2005.8385931338182, 0.1257221727728331], [2016.2273336443254, 0.11079078136566117], [2025.5174333373488, 0.09857258380497322], [2029.763501291202, 0.09305365987286494]], [0.0, 7.008770248144666e-7, 9.554553790239262e-7, 9.97460990520562e-7, 1.0095045530828565e-6, 1.0115939470568437e-6, 1.0125575710904678e-6, 1.0221938114267088e-6, 1.0975661477119695e-6, 1.2417390138585306e-6  …  3.370592750212601, 3.7910404676543488, 4.28944195655951, 4.881732221409847, 5.587541522351077, 6.431247064914716, 7.443515202226012, 8.664054916894319, 10.151223592778036, 11.18], [[[0.0, 0.0]], [[5.933977688613909e7, 7.109382302774656e11], [5.933977659491751e7, 7.109382232993287e11], [5.933977644930633e7, 7.109382198102504e11], [5.93397760124744e7, 7.109382093430552e11], [5.93397760124744e7, 7.109382093430552e11], [5.93397757628555e7, 7.10938203361785e11], [5.9339775357225865e7, 7.109381936422472e11], [5.933977513880969e7, 7.109381884086445e11]], [[5.933977513880969e7, 7.109381884086445e11], [5.9339775033029765e7, 7.109381858739875e11], [5.933977498013983e7, 7.109381846066597e11], [5.9339774821469955e7, 7.109381808046747e11], [5.9339774821469955e7, 7.109381808046747e11], [5.933977473080147e7, 7.109381786321118e11], [5.933977458346517e7, 7.109381751016974e11], [5.933977450413023e7, 7.109381732007048e11]], [[5.933977450413023e7, 7.109381732007048e11], [5.933977448667647e7, 7.109381727824846e11], [5.933977447794958e7, 7.109381725733744e11], [5.933977445176894e7, 7.109381719460442e11], [5.933977445176894e7, 7.109381719460442e11], [5.933977443680857e7, 7.109381715875696e11], [5.933977441249799e7, 7.10938171005049e11], [5.933977439940766e7, 7.109381706913838e11]], [[5.933977439940766e7, 7.109381706913838e11], [5.9339774394403435e7, 7.109381705714745e11], [5.933977439190133e7, 7.109381705115201e11], [5.933977438439564e7, 7.109381703316716e11], [5.933977438439564e7, 7.109381703316716e11], [5.933977438010566e7, 7.109381702288768e11], [5.933977437313549e7, 7.109381700618604e11], [5.933977436938232e7, 7.109381699719283e11]], [[5.933977436938232e7, 7.109381699719283e11], [5.9339774368514165e7, 7.109381699511259e11], [5.933977436808007e7, 7.109381699407242e11], [5.933977436677784e7, 7.109381699095208e11], [5.933977436677784e7, 7.109381699095208e11], [5.933977436603369e7, 7.109381698916897e11], [5.933110851065493e7, -3.056392951504114e11], [5.932015940720611e7, -3.05090059600426e11]], [[5.932015940720611e7, -3.05090059600426e11], [5.931342744397689e7, -3.0506413489281165e11], [5.9310062624389865e7, -3.0505117083397815e11], [5.929996937468996e7, -3.0501226749896606e11], [5.9299969375860296e7, -3.0501226749439197e11], [5.929420338928932e7, -3.049900304931692e11], [5.928483612179538e7, -3.049538852521791e11], [5.927979346871196e7, -3.049344172566665e11]], [[5.927979346871196e7, -3.049344172566665e11], [5.921260423109342e7, -3.046744497460394e11], [5.917912535600769e7, -3.045443034932633e11], [5.907880787233004e7, -3.0415277876482336e11], [5.9078809037969396e7, -3.0415277428423816e11], [5.9021640589516185e7, -3.039284288913491e11], [5.892898619029814e7, -3.035629158799199e11], [5.887921896737145e7, -3.033656258690082e11]], [[5.887921896737145e7, -3.033656258690082e11], [5.836305190606281e7, -3.0128520123693933e11], [5.81118067639919e7, -3.0023909629352954e11], [5.736455209334512e7, -2.9704733780254956e11], [5.7365088622671105e7, -2.970456605521172e11], [5.694641728222292e7, -2.9519896258241296e11], [5.628025403047765e7, -2.92164124311375e11], [5.592806532620749e7, -2.905171133720742e11]], [[5.592806532620749e7, -2.905171133720742e11], [5.504315338721591e7, -2.86256304995074e11], [5.4621746908176966e7, -2.841561697039585e11], [5.337593791249161e7, -2.7774237420063245e11], [5.337893548819241e7, -2.7774837239803284e11], [5.269027162882612e7, -2.7407454782897314e11], [5.1614454060434386e7, -2.6813217715282935e11], [5.105322282365747e7, -2.649490624232143e11]]  …  [[30.61698074548686, -0.1705522175038945], [29.845249330084815, -0.1598722409139286], [29.48624842195458, -0.15529207498891537], [28.435318604597906, -0.14189244583312965], [28.440283592881986, -0.1422416166709659], [27.868353557323907, -0.13502735502396546], [26.994609181015704, -0.1249539764956374], [26.54559110318237, -0.11993645614868986]], [[26.54559110318237, -0.11993645614868986], [25.85980667489523, -0.11245227117283058], [25.540753447839283, -0.10924207829771965], [24.607043456308904, -0.09985389931393734], [24.611391918742076, -0.10009610550875223], [24.103355736775242, -0.09504421164079555], [23.32713087479079, -0.08798644042723017], [22.928226806812695, -0.08447141322728442]], [[22.928226806812695, -0.08447141322728442], [22.31763502507153, -0.07921707196689312], [22.03345941022016, -0.07696265155050691], [21.201978332001566, -0.07037270608715825], [21.205766443924254, -0.07054029151684918], [20.753355755958093, -0.06699660416531936], [20.06180942632436, -0.06204197288091755], [19.706332075309927, -0.059574760781317904]], [[19.706332075309927, -0.059574760781317904], [19.160786062800543, -0.055878034996509014], [18.906689205378786, -0.05429122307001808], [18.16320012008485, -0.04965545263901096], [18.166479626917262, -0.04977101634193169], [17.76180531498316, -0.04728038239743766], [17.142619594675644, -0.04379419225098271], [16.82412062752984, -0.04205850627896361]], [[16.82412062752984, -0.04205850627896361], [16.333739390830868, -0.03945104209503371], [16.105018628796056, -0.03833108367854611], [15.435480963645643, -0.035061390616048904], [15.438299195611254, -0.035140699815871465], [15.073511937334157, -0.0333859259331146], [14.514304195593295, -0.03092577596922334], [14.226237433676562, -0.02970108146088653]], [[14.226237433676562, -0.02970108146088653], [13.78080875612172, -0.027855602230341413], [13.572546593508788, -0.027062161720734876], [12.962103588919277, -0.024747248322032404], [12.96450363286236, -0.02480129750398203], [12.63116101441157, -0.02356040214545648], [12.118359302769447, -0.02181629296020496], [11.85341989675143, -0.02094787772275008]], [[11.85341989675143, -0.02094787772275008], [11.441193023678142, -0.019633929867060064], [11.247613313751609, -0.019068021710401162], [10.678435644762956, -0.017417239178773542], [10.680456646663837, -0.017453697610367296], [10.368127216895594, -0.016569414121408464], [9.884401349871963, -0.015320624860469057], [9.63296497266416, -0.014697837932744436]], [[9.63296497266416, -0.014697837932744436], [9.237620281443661, -0.013748925980188795], [9.050426838410711, -0.013338528307539631], [8.495935944112079, -0.012138657739582767], [8.497615343483552, -0.012162899609914358], [8.189959892273428, -0.011518488655036348], [7.7066515585110675, -0.010597605106639754], [7.45194781051298, -0.01013473663691887]], [[7.45194781051298, -0.01013473663691887], [7.0417750232934395, -0.009415444878154183], [6.844015658051405, -0.009099969542871107], [6.246286743991629, -0.008163731267374345], [6.247687725643374, -0.008179716492687198], [5.9059167689462155, -0.007665705883629195], [5.348130532239865, -0.006897608187817532], [5.041763796725157, -0.006494191589766552]], [[5.041763796725157, -0.006494191589766552], [4.752229222716623, -0.006121689214742991], [4.606179773603322, -0.005941947359591757], [4.149587297375901, -0.005382317219612856], [4.149834384474731, -0.005384459038723436], [3.875041151954661, -0.005052717052241531], [3.3979850616420135, -0.00448648935109908], [3.118956197262473, -0.004155675468745649]]], true, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}([2029.763501291202, 0.09305365987286494], [2025.5174333373488, 0.09857258380497322], [5.041763796725157, -0.006494191589766552], [4.752229222716623, -0.006121689214742991], [4.606179773603322, -0.005941947359591757], [4.149587297375901, -0.005382317219612856], [4.149834384474731, -0.005384459038723436], [3.875041151954661, -0.005052717052241531], [3.3979850616420135, -0.00448648935109908], [3.118956197262473, -0.004155675468745649], [0.0010078207255851557, -1.45186924425148e-6], [2029.3439955368426, 0.09361062537072769], [0.0004965210126317841, -0.014581014057997813], OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}(0.16666666666666666, 0.0625, 0.1875, 0.25, -0.75, -0.75, 3.75, -3.0, 0.5, 0.26895043731778423, -0.7084548104956269, 0.8658892128279884, 0.15462307371928363, 0.06184922948771345, -0.02947695035460993, 0.18500664893617022, 0.4802345261121857, -0.5337849069148937, -0.013090093085106383, 0.7861107753062541, 0.08783068783068783, 0.3006060606060606, 0.22777777777777777, 0.027777777777777776, 0.06218596218596219, 0.2938217338217338, 0.16666666666666666, 0.25, 0.5, 0.5, 0.6428571428571429, 0.875, -0.19894179894179895, 0.9115151515151515, -1.9777777777777779, -0.1111111111111111, 1.67013727013727, -0.2938217338217338, 1.892063492063492, -6.067155067155067, 7.282458282458283, -4.0195360195360195, -7.214545454545455, 20.676923076923078, -20.31142191142191, 7.14965034965035, 7.866666666666666, -18.78205128205128, 13.508547008547009, -2.3653846153846154, 2.0, -5.294871794871795, 4.534188034188034, -1.2115384615384615, -1.4924630924630924, 1.5785667324128863, 1.1958838881915805, -1.219801565955412, -7.051721611721612, 16.273203719357564, -11.978886071193763, 3.0512256973795435, 4.0, -8.384615384615385, 5.769230769230769, -1.3846153846153846))), true, 0, DiffEqBase.DEStats
Number of function 1 evaluations:                  1375
Number of function 2 evaluations:                  0
Number of W matrix evaluations:                    0
Number of linear solves:                           0
Number of Jacobians created:                       0
Number of nonlinear solver iterations:             0
Number of nonlinear solver convergence failures:   0
Number of rootfind condition calls:                0
Number of accepted steps:                          127
Number of rejected steps:                          69, :Success), SciMLBase.ODESolution{Float64, 2, Vector{Vector{Float64}}, Nothing, Nothing, Vector{Float64}, Vector{Vector{Vector{Float64}}}, SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}, OwrenZen5, OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}, DiffEqBase.DEStats}([[0.0, 0.0], [36.4444862744329, 1.579268118627557e6], [51.5102531682474, 2.2321209270527777e6], [59.39548135566309, 2.5738156706214817e6], [59.96899626066168, 2.5986680938581103e6], [60.234408802257775, 2.594052747932799e6], [60.349101684023985, 2.5913870234995824e6], [61.48686174125368, 2.5649894614919503e6], [67.11243296152996, 2.4359367988508265e6], [76.020461285172, 2.238024520691209e6]  …  [1963.9891912125076, 0.27324662177989356], [1974.6768926588054, 0.23625439933833658], [1985.6166377180555, 0.20502783287737014], [1996.782354114574, 0.17857018547276354], [2008.1253357178794, 0.15607543159298384], [2019.5585056777036, 0.1368938103286856], [2030.9263167269653, 0.12051107733168197], [2041.9404558584677, 0.10655261382031742], [2052.0175116603677, 0.09486200869858916], [2058.4576940911807, 0.08748056334857417]], nothing, nothing, [0.0, 1.7298057351407088e-7, 2.444889216214274e-7, 2.819154693302915e-7, 2.8463760779751227e-7, 2.8589905198827165e-7, 2.8644546979184605e-7, 2.9190964782759027e-7, 3.2012620429042975e-7, 3.691556446083393e-7  …  2.940545044637546, 3.3550956202351676, 3.8482090601813295, 4.4361872044071555, 5.139107314004525, 5.981872890248213, 6.995726192435438, 8.220787491528966, 9.713308206568247, 11.18], [[[0.0, 0.0]], [[2.1068542938955063e8, 9.129742710538527e12], [2.106854291343598e8, 9.129742688421895e12], [2.1068542900676212e8, 9.129742677363377e12], [2.1068542862397364e8, 9.129742644188227e12], [2.1068542862397364e8, 9.129742644188227e12], [2.1068542840523884e8, 9.129742625231125e12], [2.1068542804979238e8, 9.129742594425629e12], [2.106854278583966e8, 9.129742577837918e12]], [[2.106854278583966e8, 9.129742577837918e12], [2.106854277529028e8, 9.129742568695082e12], [2.1068542770015585e8, 9.12974256412366e12], [2.106854275419151e8, 9.1297425504094e12], [2.106854275419151e8, 9.1297425504094e12], [2.1068542745149183e8, 9.129742542572686e12], [2.1068542730455402e8, 9.129742529838016e12], [2.1068542722543365e8, 9.129742522980885e12]], [[2.1068542722543365e8, 9.129742522980885e12], [2.106854271702195e8, 9.129742518195643e12], [2.1068542714261246e8, 9.129742515803018e12], [2.1068542705979133e8, 9.129742508625154e12], [2.1068542705979133e8, 9.129742508625154e12], [2.1068542701246494e8, 9.129742504523516e12], [2.1068542693555957e8, 9.129742497858354e12], [2.1068542689414898e8, 9.129742494269422e12]], [[2.1068542689414898e8, 9.129742494269422e12], [2.1068542689013466e8, 9.129742493921512e12], [2.1068542688812518e8, 9.12974249374736e12], [2.106854268821014e8, 9.129742493225291e12], [2.106854268821014e8, 9.129742493225291e12], [2.1068542687865916e8, 9.129742492926963e12], [2.1068542687306404e8, 9.12974249244205e12], [2.106854268700537e8, 9.129742492181154e12]], [[2.106854268700537e8, 9.129742492181154e12], [2.1064956234730455e8, -4.907154005514008e12], [2.1058983662627813e8, -4.895519868300539e12], [2.1041090851867533e8, -4.908447612780076e12], [2.1041062393797114e8, -4.812694014232162e12], [2.1030877893880403e8, -4.907388926844348e12], [2.1014294160537443e8, -4.874166354907842e12], [2.1005383474934492e8, -4.88289019527668e12]], [[2.1005383474934492e8, -4.88289019527668e12], [2.1000238014542374e8, -4.881441387472777e12], [2.0997667199742615e8, -4.880717474929564e12], [2.0989956740923056e8, -4.878545548328455e12], [2.0989956745091727e8, -4.878545550729561e12], [2.0985553374337646e8, -4.877304804873912e12], [2.097840194801313e8, -4.875289151953951e12], [2.0974553251446438e8, -4.874204084825922e12]], [[2.0974553251446438e8, -4.874204084825922e12], [2.0923312988274118e8, -4.859731754222953e12], [2.089788277220621e8, -4.852544966672877e12], [2.082178447003917e8, -4.830966333259906e12], [2.0821788601282728e8, -4.830968732537408e12], [2.0778555123156482e8, -4.818672861029773e12], [2.0708699833622494e8, -4.798754257488965e12], [2.0671284167621207e8, -4.78805842706214e12]], [[2.0671284167621207e8, -4.78805842706214e12], [2.0415824612021375e8, -4.714366494532878e12], [2.029284943336198e8, -4.678865306799398e12], [1.992824109512023e8, -4.571960727755437e12], [1.992876897085977e8, -4.572289441788356e12], [1.9725929785741428e8, -4.512012816438522e12], [1.940611688444919e8, -4.416397732679444e12], [1.9238201449517912e8, -4.3657660187809385e12]], [[1.9238201449517912e8, -4.3657660187809385e12], [1.8856718091927814e8, -4.2492159079584834e12], [1.867730668386579e8, -4.194873504999828e12], [1.814849903398357e8, -4.0312844009818496e12], [1.8150528513851148e8, -4.032855837290466e12], [1.78601226157403e8, -3.9414206059507705e12], [1.741144977903087e8, -3.8008977369646963e12], [1.7179010090236774e8, -3.727608763893374e12]]  …  [[32.10698626441984, -0.14969479236247532], [31.285377945330744, -0.14047544202791235], [30.903932488321974, -0.13652557186095193], [29.787909223141313, -0.12495364046963132], [29.79348440692801, -0.1252656188677973], [29.186739470055223, -0.11902314734627652], [28.261553233341047, -0.11031867341085921], [27.786618897268788, -0.10597896428811084]], [[27.786618897268788, -0.10597896428811084], [27.059336726753305, -0.09947924152280424], [26.721657713037448, -0.09669388927193706], [25.734015348628144, -0.08853596194175198], [25.738881644396084, -0.08875375880788511], [25.202065618145895, -0.08435489262787105], [24.38344771689112, -0.0782173264592691], [23.963236621620116, -0.07515755540393901]], [[23.963236621620116, -0.07515755540393901], [23.318381657380563, -0.07056481448293628], [23.01887615750398, -0.06859604841003955], [22.143099439823303, -0.0628320240664563], [22.147324189485698, -0.06298383360682543], [21.671347543643133, -0.0598777115051363], [20.945227886841636, -0.05554030815059207], [20.572429932900487, -0.053378222981727654]], [[20.572429932900487, -0.053378222981727654], [19.998928798145524, -0.05012543983495356], [19.732377498313546, -0.048730505216139836], [18.953010098985533, -0.044648566424458004], [18.956654673363232, -0.04475410898809976], [18.53297682182048, -0.04255626276438907], [17.886073937974643, -0.03948386342781819], [17.553758101696758, -0.037952608659665946]], [[17.553758101696758, -0.037952608659665946], [17.041007946674135, -0.03564315975383239], [16.80238670292516, -0.03465223869167955], [16.104470398905963, -0.031754332908856965], [16.10759082846268, -0.03182741397591998], [15.727884667046013, -0.030268750932387338], [15.147135718991535, -0.02808665571063616], [14.848428157484202, -0.026999309631600743]], [[14.848428157484202, -0.026999309631600743], [14.385743337482529, -0.02535472446495907], [14.169937983355775, -0.02464853697449589], [13.538092843661522, -0.02258465359820425], [13.540740286705786, -0.022634948447395668], [13.19632386607867, -0.021526233269887046], [12.66788646288765, -0.019970614377365282], [12.395389751961583, -0.01919542174969878]], [[12.395389751961583, -0.01919542174969878], [11.970952381104164, -0.01801870922318543], [11.772203734222545, -0.017512753625131963], [11.188785318656395, -0.016034524362694414], [11.191006504574739, -0.01606882607488705], [10.871662769143258, -0.01527548347796171], [10.378765944964606, -0.014157927968538367], [10.123266077981087, -0.013600445086388085]], [[10.123266077981087, -0.013600445086388085], [9.721654120567944, -0.012749197872002394], [9.532212955456256, -0.01238204230817755], [8.97268165250248, -0.011307699961662187], [8.974520369402757, -0.011330801415207963], [8.665394831261434, -0.010753424112514232], [8.182424137552621, -0.00993235322087847], [7.9291681977789805, -0.009520444097158857]], [[7.9291681977789805, -0.009520444097158857], [7.5233243268882735, -0.008881890744741962], [7.328938165248043, -0.008603612895620463], [6.745497097593427, -0.007780504480642467], [6.747010559444611, -0.007795907413866904], [6.416886661834147, -0.0073468327646605686], [5.8852806861732345, -0.00668656573512649], [5.597556773194193, -0.0063449596009297875]], [[5.597556773194193, -0.0063449596009297875], [5.214281656961501, -0.005902129038972106], [5.022855020583522, -0.005695473897142814], [4.423288991027299, -0.005051255670164644], [4.424003601855884, -0.005056877695849244], [4.0617469068646095, -0.004674691529468723], [3.425276780692582, -0.004021514909103419], [3.0433014773728733, -0.003627683578857116]]], SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [0.0, 0.0], (0.0, 11.18), Any[GasChromatographySimulator.Column(11.18, 0.000104, [0.000104], 1.04e-7, [1.04e-7], "FS5ms", "H2"), GasChromatographySimulator.Program{GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}}([0.0, 60.0, 1680.0, 60.0, 360.0, 60.0], [40.0, 40.0, 180.0, 180.0, 300.0, 300.0], [411564.0, 411564.0, 411564.0, 411564.0, 411564.0, 411564.0], [101300.0, 101300.0, 101300.0, 101300.0, 101300.0, 101300.0], GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}([0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0]), [0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0], 11181×6 extrapolate(interpolate((0.0:0.001:11.18,::Vector{Float64}), ::Matrix{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
   ⋮                                       ⋮
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0), GasChromatographySimulator.Substance("C26", "630-1-3", 593.5699999999999, 44.16, 216.77, 0.001, "Leppert2020b, alkane", 7.200161658208628e-5, 0.0, 0.0), GasChromatographySimulator.Options(OwrenZen5(), 1.0e-6, 0.001, "inlet", true, true, "Blumberg", "Pressure")], Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}(), SciMLBase.StandardODEProblem()), OwrenZen5(), OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [[0.0, 0.0], [36.4444862744329, 1.579268118627557e6], [51.5102531682474, 2.2321209270527777e6], [59.39548135566309, 2.5738156706214817e6], [59.96899626066168, 2.5986680938581103e6], [60.234408802257775, 2.594052747932799e6], [60.349101684023985, 2.5913870234995824e6], [61.48686174125368, 2.5649894614919503e6], [67.11243296152996, 2.4359367988508265e6], [76.020461285172, 2.238024520691209e6]  …  [1963.9891912125076, 0.27324662177989356], [1974.6768926588054, 0.23625439933833658], [1985.6166377180555, 0.20502783287737014], [1996.782354114574, 0.17857018547276354], [2008.1253357178794, 0.15607543159298384], [2019.5585056777036, 0.1368938103286856], [2030.9263167269653, 0.12051107733168197], [2041.9404558584677, 0.10655261382031742], [2052.0175116603677, 0.09486200869858916], [2058.4576940911807, 0.08748056334857417]], [0.0, 1.7298057351407088e-7, 2.444889216214274e-7, 2.819154693302915e-7, 2.8463760779751227e-7, 2.8589905198827165e-7, 2.8644546979184605e-7, 2.9190964782759027e-7, 3.2012620429042975e-7, 3.691556446083393e-7  …  2.940545044637546, 3.3550956202351676, 3.8482090601813295, 4.4361872044071555, 5.139107314004525, 5.981872890248213, 6.995726192435438, 8.220787491528966, 9.713308206568247, 11.18], [[[0.0, 0.0]], [[2.1068542938955063e8, 9.129742710538527e12], [2.106854291343598e8, 9.129742688421895e12], [2.1068542900676212e8, 9.129742677363377e12], [2.1068542862397364e8, 9.129742644188227e12], [2.1068542862397364e8, 9.129742644188227e12], [2.1068542840523884e8, 9.129742625231125e12], [2.1068542804979238e8, 9.129742594425629e12], [2.106854278583966e8, 9.129742577837918e12]], [[2.106854278583966e8, 9.129742577837918e12], [2.106854277529028e8, 9.129742568695082e12], [2.1068542770015585e8, 9.12974256412366e12], [2.106854275419151e8, 9.1297425504094e12], [2.106854275419151e8, 9.1297425504094e12], [2.1068542745149183e8, 9.129742542572686e12], [2.1068542730455402e8, 9.129742529838016e12], [2.1068542722543365e8, 9.129742522980885e12]], [[2.1068542722543365e8, 9.129742522980885e12], [2.106854271702195e8, 9.129742518195643e12], [2.1068542714261246e8, 9.129742515803018e12], [2.1068542705979133e8, 9.129742508625154e12], [2.1068542705979133e8, 9.129742508625154e12], [2.1068542701246494e8, 9.129742504523516e12], [2.1068542693555957e8, 9.129742497858354e12], [2.1068542689414898e8, 9.129742494269422e12]], [[2.1068542689414898e8, 9.129742494269422e12], [2.1068542689013466e8, 9.129742493921512e12], [2.1068542688812518e8, 9.12974249374736e12], [2.106854268821014e8, 9.129742493225291e12], [2.106854268821014e8, 9.129742493225291e12], [2.1068542687865916e8, 9.129742492926963e12], [2.1068542687306404e8, 9.12974249244205e12], [2.106854268700537e8, 9.129742492181154e12]], [[2.106854268700537e8, 9.129742492181154e12], [2.1064956234730455e8, -4.907154005514008e12], [2.1058983662627813e8, -4.895519868300539e12], [2.1041090851867533e8, -4.908447612780076e12], [2.1041062393797114e8, -4.812694014232162e12], [2.1030877893880403e8, -4.907388926844348e12], [2.1014294160537443e8, -4.874166354907842e12], [2.1005383474934492e8, -4.88289019527668e12]], [[2.1005383474934492e8, -4.88289019527668e12], [2.1000238014542374e8, -4.881441387472777e12], [2.0997667199742615e8, -4.880717474929564e12], [2.0989956740923056e8, -4.878545548328455e12], [2.0989956745091727e8, -4.878545550729561e12], [2.0985553374337646e8, -4.877304804873912e12], [2.097840194801313e8, -4.875289151953951e12], [2.0974553251446438e8, -4.874204084825922e12]], [[2.0974553251446438e8, -4.874204084825922e12], [2.0923312988274118e8, -4.859731754222953e12], [2.089788277220621e8, -4.852544966672877e12], [2.082178447003917e8, -4.830966333259906e12], [2.0821788601282728e8, -4.830968732537408e12], [2.0778555123156482e8, -4.818672861029773e12], [2.0708699833622494e8, -4.798754257488965e12], [2.0671284167621207e8, -4.78805842706214e12]], [[2.0671284167621207e8, -4.78805842706214e12], [2.0415824612021375e8, -4.714366494532878e12], [2.029284943336198e8, -4.678865306799398e12], [1.992824109512023e8, -4.571960727755437e12], [1.992876897085977e8, -4.572289441788356e12], [1.9725929785741428e8, -4.512012816438522e12], [1.940611688444919e8, -4.416397732679444e12], [1.9238201449517912e8, -4.3657660187809385e12]], [[1.9238201449517912e8, -4.3657660187809385e12], [1.8856718091927814e8, -4.2492159079584834e12], [1.867730668386579e8, -4.194873504999828e12], [1.814849903398357e8, -4.0312844009818496e12], [1.8150528513851148e8, -4.032855837290466e12], [1.78601226157403e8, -3.9414206059507705e12], [1.741144977903087e8, -3.8008977369646963e12], [1.7179010090236774e8, -3.727608763893374e12]]  …  [[32.10698626441984, -0.14969479236247532], [31.285377945330744, -0.14047544202791235], [30.903932488321974, -0.13652557186095193], [29.787909223141313, -0.12495364046963132], [29.79348440692801, -0.1252656188677973], [29.186739470055223, -0.11902314734627652], [28.261553233341047, -0.11031867341085921], [27.786618897268788, -0.10597896428811084]], [[27.786618897268788, -0.10597896428811084], [27.059336726753305, -0.09947924152280424], [26.721657713037448, -0.09669388927193706], [25.734015348628144, -0.08853596194175198], [25.738881644396084, -0.08875375880788511], [25.202065618145895, -0.08435489262787105], [24.38344771689112, -0.0782173264592691], [23.963236621620116, -0.07515755540393901]], [[23.963236621620116, -0.07515755540393901], [23.318381657380563, -0.07056481448293628], [23.01887615750398, -0.06859604841003955], [22.143099439823303, -0.0628320240664563], [22.147324189485698, -0.06298383360682543], [21.671347543643133, -0.0598777115051363], [20.945227886841636, -0.05554030815059207], [20.572429932900487, -0.053378222981727654]], [[20.572429932900487, -0.053378222981727654], [19.998928798145524, -0.05012543983495356], [19.732377498313546, -0.048730505216139836], [18.953010098985533, -0.044648566424458004], [18.956654673363232, -0.04475410898809976], [18.53297682182048, -0.04255626276438907], [17.886073937974643, -0.03948386342781819], [17.553758101696758, -0.037952608659665946]], [[17.553758101696758, -0.037952608659665946], [17.041007946674135, -0.03564315975383239], [16.80238670292516, -0.03465223869167955], [16.104470398905963, -0.031754332908856965], [16.10759082846268, -0.03182741397591998], [15.727884667046013, -0.030268750932387338], [15.147135718991535, -0.02808665571063616], [14.848428157484202, -0.026999309631600743]], [[14.848428157484202, -0.026999309631600743], [14.385743337482529, -0.02535472446495907], [14.169937983355775, -0.02464853697449589], [13.538092843661522, -0.02258465359820425], [13.540740286705786, -0.022634948447395668], [13.19632386607867, -0.021526233269887046], [12.66788646288765, -0.019970614377365282], [12.395389751961583, -0.01919542174969878]], [[12.395389751961583, -0.01919542174969878], [11.970952381104164, -0.01801870922318543], [11.772203734222545, -0.017512753625131963], [11.188785318656395, -0.016034524362694414], [11.191006504574739, -0.01606882607488705], [10.871662769143258, -0.01527548347796171], [10.378765944964606, -0.014157927968538367], [10.123266077981087, -0.013600445086388085]], [[10.123266077981087, -0.013600445086388085], [9.721654120567944, -0.012749197872002394], [9.532212955456256, -0.01238204230817755], [8.97268165250248, -0.011307699961662187], [8.974520369402757, -0.011330801415207963], [8.665394831261434, -0.010753424112514232], [8.182424137552621, -0.00993235322087847], [7.9291681977789805, -0.009520444097158857]], [[7.9291681977789805, -0.009520444097158857], [7.5233243268882735, -0.008881890744741962], [7.328938165248043, -0.008603612895620463], [6.745497097593427, -0.007780504480642467], [6.747010559444611, -0.007795907413866904], [6.416886661834147, -0.0073468327646605686], [5.8852806861732345, -0.00668656573512649], [5.597556773194193, -0.0063449596009297875]], [[5.597556773194193, -0.0063449596009297875], [5.214281656961501, -0.005902129038972106], [5.022855020583522, -0.005695473897142814], [4.423288991027299, -0.005051255670164644], [4.424003601855884, -0.005056877695849244], [4.0617469068646095, -0.004674691529468723], [3.425276780692582, -0.004021514909103419], [3.0433014773728733, -0.003627683578857116]]], true, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}([2058.4576940911807, 0.08748056334857417], [2052.0175116603677, 0.09486200869858916], [5.597556773194193, -0.0063449596009297875], [5.214281656961501, -0.005902129038972106], [5.022855020583522, -0.005695473897142814], [4.423288991027299, -0.005051255670164644], [4.424003601855884, -0.005056877695849244], [4.0617469068646095, -0.004674691529468723], [3.425276780692582, -0.004021514909103419], [3.0433014773728733, -0.003627683578857116], [0.0032794386326972977, -4.201526080027489e-6], [2057.8634719954694, 0.08818502248465862], [0.001593152508773165, -0.04382889673465944], OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}(0.16666666666666666, 0.0625, 0.1875, 0.25, -0.75, -0.75, 3.75, -3.0, 0.5, 0.26895043731778423, -0.7084548104956269, 0.8658892128279884, 0.15462307371928363, 0.06184922948771345, -0.02947695035460993, 0.18500664893617022, 0.4802345261121857, -0.5337849069148937, -0.013090093085106383, 0.7861107753062541, 0.08783068783068783, 0.3006060606060606, 0.22777777777777777, 0.027777777777777776, 0.06218596218596219, 0.2938217338217338, 0.16666666666666666, 0.25, 0.5, 0.5, 0.6428571428571429, 0.875, -0.19894179894179895, 0.9115151515151515, -1.9777777777777779, -0.1111111111111111, 1.67013727013727, -0.2938217338217338, 1.892063492063492, -6.067155067155067, 7.282458282458283, -4.0195360195360195, -7.214545454545455, 20.676923076923078, -20.31142191142191, 7.14965034965035, 7.866666666666666, -18.78205128205128, 13.508547008547009, -2.3653846153846154, 2.0, -5.294871794871795, 4.534188034188034, -1.2115384615384615, -1.4924630924630924, 1.5785667324128863, 1.1958838881915805, -1.219801565955412, -7.051721611721612, 16.273203719357564, -11.978886071193763, 3.0512256973795435, 4.0, -8.384615384615385, 5.769230769230769, -1.3846153846153846))), true, 0, DiffEqBase.DEStats
Number of function 1 evaluations:                  1326
Number of function 2 evaluations:                  0
Number of W matrix evaluations:                    0
Number of linear solves:                           0
Number of Jacobians created:                       0
Number of nonlinear solver iterations:             0
Number of nonlinear solver convergence failures:   0
Number of rootfind condition calls:                0
Number of accepted steps:                          132
Number of rejected steps:                          57, :Success), SciMLBase.ODESolution{Float64, 2, Vector{Vector{Float64}}, Nothing, Nothing, Vector{Float64}, Vector{Vector{Vector{Float64}}}, SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}, OwrenZen5, OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}, DiffEqBase.DEStats}([[0.0, 0.0], [25.794159430999528, 1.4903956704883403e6], [48.38103410428731, 2.79547328656596e6], [58.63742215444283, 3.3880910181560814e6], [59.74382867798106, 3.4520195786222178e6], [60.01307613797211, 3.4675767921403954e6], [62.660808647662655, 3.390997598672951e6], [69.58984592248531, 3.19252875685878e6], [78.80893466817422, 2.935730724883582e6], [89.78943262597996, 2.6451376771999e6]  …  [1992.2356999486292, 0.24628281003506447], [2003.3715092285142, 0.21393949211100086], [2014.7437166491877, 0.18642215278507954], [2026.3154379481373, 0.16293563119053517], [2038.0209438817963, 0.1428326882999334], [2049.744839492101, 0.1255900954977622], [2061.2803941976645, 0.11079995188778449], [2072.2345876948516, 0.09819669134584942], [2081.7591324697382, 0.08782033810017538], [2084.514579060352, 0.08474595786232589]], nothing, nothing, [0.0, 9.348436962863668e-8, 1.7534475178760253e-7, 2.12516421600279e-7, 2.165263106378246e-7, 2.1750212957539335e-7, 2.2726031895108073e-7, 2.54376105313814e-7, 2.942690430918181e-7, 3.4810669768039747e-7  …  2.928724830145856, 3.3824049477247042, 3.9234485187423185, 4.570176578373655, 5.345198299796014, 6.2766568363124735, 7.400118623735283, 8.762296708234569, 10.438918999243874, 11.18], [[[0.0, 0.0]], [[2.759194888313451e8, 1.5942725850990332e13], [2.759194886507287e8, 1.5942725830118176e13], [2.7591948856042045e8, 1.594272581968209e13], [2.7591948828949594e8, 1.5942725788373865e13], [2.7591948828949594e8, 1.5942725788373865e13], [2.759194881346829e8, 1.5942725770483555e13], [2.7591948788310903e8, 1.5942725741411504e13], [2.7591948774764663e8, 1.594272572575737e13]], [[2.7591948774764663e8, 1.594272572575737e13], [2.759194875894884e8, 1.5942725707480492e13], [2.759194875104093e8, 1.5942725698342057e13], [2.7591948727317286e8, 1.5942725670926848e13], [2.7591948727317286e8, 1.5942725670926848e13], [2.7591948713760763e8, 1.5942725655260832e13], [2.759194869173157e8, 1.5942725629803742e13], [2.75919486798697e8, 1.5942725616096078e13]], [[2.75919486798697e8, 1.5942725616096078e13], [2.7591948672687954e8, 1.5942725607796803e13], [2.759194866909708e8, 1.5942725603647158e13], [2.759194865832386e8, 1.594272559119755e13], [2.759194865832386e8, 1.594272559119755e13], [2.759194865216867e8, 1.594272558408457e13], [2.759194864216552e8, 1.5942725572524861e13], [2.75919486367792e8, 1.5942725566300398e13]], [[2.75919486367792e8, 1.5942725566300398e13], [2.759194863600447e8, 1.5942725565405113e13], [2.759194863561711e8, 1.5942725564957473e13], [2.7591948634455013e8, 1.5942725563614547e13], [2.7591948634455013e8, 1.5942725563614547e13], [2.759194863379106e8, 1.594272556284728e13], [2.7591948632711875e8, 1.5942725561600164e13], [2.759194863213082e8, 1.594272556092869e13]], [[2.759194863213082e8, 1.594272556092869e13], [2.759194863194229e8, 1.5942725560710826e13], [2.7591948631848127e8, 1.5942725560602014e13], [2.7591948631565225e8, 1.5942725560275086e13], [2.7591948631565225e8, 1.5942725560275086e13], [2.7591948631403035e8, 1.5942725560087656e13], [2.7591948631141025e8, 1.594272555978488e13], [2.7587436505641747e8, -7.991376137729678e12]], [[2.7587436505641747e8, -7.991376137729678e12], [2.743308482014357e8, -7.943152613034166e12], [2.7357216054405516e8, -7.919310964595955e12], [2.713088917875512e8, -7.847485729247865e12], [2.713095449901271e8, -7.8475144871849e12], [2.700328480666158e8, -7.806574795802928e12], [2.679854694005376e8, -7.740322667881738e12], [2.6689608107881635e8, -7.704767841440297e12]], [[2.6689608107881635e8, -7.704767841440297e12], [2.629084974763129e8, -7.572647838878639e12], [2.6100425569891447e8, -7.509000755138529e12], [2.553704510907681e8, -7.31655168253434e12], [2.553824955833921e8, -7.317240477464633e12], [2.5226317967154908e8, -7.208432271856311e12], [2.473783957630462e8, -7.035816422729664e12], [2.4482591374534798e8, -6.944356938248971e12]], [[2.4482591374534798e8, -6.944356938248971e12], [2.3992534444257975e8, -6.765817284137053e12], [2.3762195687085542e8, -6.682154952849443e12], [2.3083371921991926e8, -6.429781337697645e12], [2.3086028407767978e8, -6.432013844640516e12], [2.2713344799647152e8, -6.290590568649086e12], [2.213785902919938e8, -6.072190577668113e12], [2.1839816275311476e8, -5.958006148076064e12]], [[2.1839816275311476e8, -5.958006148076064e12], [2.1317815101427838e8, -5.755442157164383e12], [2.107544614432726e8, -5.663099117932252e12], [2.0363086714606974e8, -5.385313115646984e12], [2.0367119740017354e8, -5.389680493231892e12], [1.9978222312415692e8, -5.234953667992473e12], [1.9384484296995518e8, -5.003080114876476e12], [1.9078946680973372e8, -4.883257113256235e12]]  …  [[30.77130824258604, -0.11860394173061783], [29.959935495288498, -0.11140797935313063], [29.58387280378597, -0.10832686127873781], [28.48405239773447, -0.09928726916088992], [28.48980788191048, -0.09953769556549211], [27.89233756602983, -0.09465206403950747], [26.982695369276243, -0.08784534733068528], [26.51613295807781, -0.08444844983340616]], [[26.51613295807781, -0.08444844983340616], [25.800244567668717, -0.0793437770931746], [25.46837113091203, -0.07715739379243877], [24.49808914082673, -0.07074474949610282], [24.503078768658227, -0.07092033247353718], [23.976080189941577, -0.06745623124240567], [23.173557371693533, -0.06262624453570909], [22.76191993875521, -0.060216001105611296]], [[22.76191993875521, -0.060216001105611296], [22.128972332737575, -0.05658634124504633], [21.83540173608769, -0.055031133565847774], [20.977272807417243, -0.050471645108792054], [20.98157264423659, -0.05059453682447829], [20.515478137872613, -0.04813327651603161], [19.80527866050254, -0.04469820877964033], [19.44087953687074, -0.042984302089013215]], [[19.44087953687074, -0.042984302089013215], [18.879175153075106, -0.04039755182650475], [18.61839882676841, -0.03928869155478835], [17.856095873890496, -0.03603958650586973], [17.859774978122722, -0.03612533048820085], [17.44555489817186, -0.03437312328903092], [16.8136337670386, -0.03192456778705127], [16.48913597481707, -0.030703126375547386]], [[16.48913597481707, -0.030703126375547386], [15.987372575608578, -0.02885516049433386], [15.754032697566045, -0.02806251718303446], [15.071569255652193, -0.02574150168336388], [15.074690623388719, -0.025801030530739864], [14.703421117683277, -0.024550845344149242], [14.135744980577314, -0.022800761990946793], [13.843740597793335, -0.021927896798266483]], [[13.843740597793335, -0.021927896798266483], [13.390283227433452, -0.020603475174607176], [13.178794505801399, -0.020034873462556387], [12.559292860315507, -0.018370904014162387], [12.561913982568855, -0.018411924309927656], [12.224006523623116, -0.017516802351725272], [11.705183549724815, -0.01626026317292575], [11.437387063164012, -0.01563340622315477]], [[11.437387063164012, -0.01563340622315477], [11.01878150792764, -0.014678336197953723], [10.82253680103821, -0.014267564488197654], [10.245554614263034, -0.013065332972118784], [10.247728131844918, -0.013093295345867853], [9.931188517898754, -0.012446898304422055], [9.441243863984521, -0.011534435582156359], [9.186519659630589, -0.011078238338239042]], [[9.186519659630589, -0.011078238338239042], [8.783566141333234, -0.010377508916696608], [8.592773339555121, -0.010074628673640663], [8.026713159861465, -0.009184816254201401], [8.02849097003657, -0.009203619874873954], [7.713708988673121, -0.008723062083665283], [7.217886795021174, -0.008034043594872396], [6.955656064380171, -0.007685578728404354]], [[6.955656064380171, -0.007685578728404354], [6.5273109079091185, -0.007134646380183254], [6.319820953882714, -0.00689180543252196], [5.687589521348274, -0.006160868366436858], [5.689079491765033, -0.00617364217111904], [5.323062677762132, -0.0057642040642810815], [4.715582270359798, -0.005135236105887344], [4.3747513071274, -0.004792939751623829]], [[4.3747513071274, -0.004792939751623829], [4.166922925734744, -0.004586391879474687], [4.061432653558884, -0.0044838182276782535], [3.7325651053043574, -0.0041622082759375355], [3.732635555251449, -0.00416269816983687], [3.5355500768916843, -0.003970041139916266], [3.196751224512554, -0.0036386269738103417], [3.0020840817735213, -0.0034466511849334633]]], SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [0.0, 0.0], (0.0, 11.18), Any[GasChromatographySimulator.Column(11.18, 0.000104, [0.000104], 1.04e-7, [1.04e-7], "FS5ms", "H2"), GasChromatographySimulator.Program{GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}}([0.0, 60.0, 1680.0, 60.0, 360.0, 60.0], [40.0, 40.0, 180.0, 180.0, 300.0, 300.0], [411564.0, 411564.0, 411564.0, 411564.0, 411564.0, 411564.0], [101300.0, 101300.0, 101300.0, 101300.0, 101300.0, 101300.0], GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}([0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0]), [0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0], 11181×6 extrapolate(interpolate((0.0:0.001:11.18,::Vector{Float64}), ::Matrix{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
   ⋮                                       ⋮
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0), GasChromatographySimulator.Substance("C27", "593-49-7", 599.77, 41.9, 184.17, 0.001, "Leppert2020b, alkane, alkanes", 7.054117055654164e-5, 0.0, 0.0), GasChromatographySimulator.Options(OwrenZen5(), 1.0e-6, 0.001, "inlet", true, true, "Blumberg", "Pressure")], Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}(), SciMLBase.StandardODEProblem()), OwrenZen5(), OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [[0.0, 0.0], [25.794159430999528, 1.4903956704883403e6], [48.38103410428731, 2.79547328656596e6], [58.63742215444283, 3.3880910181560814e6], [59.74382867798106, 3.4520195786222178e6], [60.01307613797211, 3.4675767921403954e6], [62.660808647662655, 3.390997598672951e6], [69.58984592248531, 3.19252875685878e6], [78.80893466817422, 2.935730724883582e6], [89.78943262597996, 2.6451376771999e6]  …  [1992.2356999486292, 0.24628281003506447], [2003.3715092285142, 0.21393949211100086], [2014.7437166491877, 0.18642215278507954], [2026.3154379481373, 0.16293563119053517], [2038.0209438817963, 0.1428326882999334], [2049.744839492101, 0.1255900954977622], [2061.2803941976645, 0.11079995188778449], [2072.2345876948516, 0.09819669134584942], [2081.7591324697382, 0.08782033810017538], [2084.514579060352, 0.08474595786232589]], [0.0, 9.348436962863668e-8, 1.7534475178760253e-7, 2.12516421600279e-7, 2.165263106378246e-7, 2.1750212957539335e-7, 2.2726031895108073e-7, 2.54376105313814e-7, 2.942690430918181e-7, 3.4810669768039747e-7  …  2.928724830145856, 3.3824049477247042, 3.9234485187423185, 4.570176578373655, 5.345198299796014, 6.2766568363124735, 7.400118623735283, 8.762296708234569, 10.438918999243874, 11.18], [[[0.0, 0.0]], [[2.759194888313451e8, 1.5942725850990332e13], [2.759194886507287e8, 1.5942725830118176e13], [2.7591948856042045e8, 1.594272581968209e13], [2.7591948828949594e8, 1.5942725788373865e13], [2.7591948828949594e8, 1.5942725788373865e13], [2.759194881346829e8, 1.5942725770483555e13], [2.7591948788310903e8, 1.5942725741411504e13], [2.7591948774764663e8, 1.594272572575737e13]], [[2.7591948774764663e8, 1.594272572575737e13], [2.759194875894884e8, 1.5942725707480492e13], [2.759194875104093e8, 1.5942725698342057e13], [2.7591948727317286e8, 1.5942725670926848e13], [2.7591948727317286e8, 1.5942725670926848e13], [2.7591948713760763e8, 1.5942725655260832e13], [2.759194869173157e8, 1.5942725629803742e13], [2.75919486798697e8, 1.5942725616096078e13]], [[2.75919486798697e8, 1.5942725616096078e13], [2.7591948672687954e8, 1.5942725607796803e13], [2.759194866909708e8, 1.5942725603647158e13], [2.759194865832386e8, 1.594272559119755e13], [2.759194865832386e8, 1.594272559119755e13], [2.759194865216867e8, 1.594272558408457e13], [2.759194864216552e8, 1.5942725572524861e13], [2.75919486367792e8, 1.5942725566300398e13]], [[2.75919486367792e8, 1.5942725566300398e13], [2.759194863600447e8, 1.5942725565405113e13], [2.759194863561711e8, 1.5942725564957473e13], [2.7591948634455013e8, 1.5942725563614547e13], [2.7591948634455013e8, 1.5942725563614547e13], [2.759194863379106e8, 1.594272556284728e13], [2.7591948632711875e8, 1.5942725561600164e13], [2.759194863213082e8, 1.594272556092869e13]], [[2.759194863213082e8, 1.594272556092869e13], [2.759194863194229e8, 1.5942725560710826e13], [2.7591948631848127e8, 1.5942725560602014e13], [2.7591948631565225e8, 1.5942725560275086e13], [2.7591948631565225e8, 1.5942725560275086e13], [2.7591948631403035e8, 1.5942725560087656e13], [2.7591948631141025e8, 1.594272555978488e13], [2.7587436505641747e8, -7.991376137729678e12]], [[2.7587436505641747e8, -7.991376137729678e12], [2.743308482014357e8, -7.943152613034166e12], [2.7357216054405516e8, -7.919310964595955e12], [2.713088917875512e8, -7.847485729247865e12], [2.713095449901271e8, -7.8475144871849e12], [2.700328480666158e8, -7.806574795802928e12], [2.679854694005376e8, -7.740322667881738e12], [2.6689608107881635e8, -7.704767841440297e12]], [[2.6689608107881635e8, -7.704767841440297e12], [2.629084974763129e8, -7.572647838878639e12], [2.6100425569891447e8, -7.509000755138529e12], [2.553704510907681e8, -7.31655168253434e12], [2.553824955833921e8, -7.317240477464633e12], [2.5226317967154908e8, -7.208432271856311e12], [2.473783957630462e8, -7.035816422729664e12], [2.4482591374534798e8, -6.944356938248971e12]], [[2.4482591374534798e8, -6.944356938248971e12], [2.3992534444257975e8, -6.765817284137053e12], [2.3762195687085542e8, -6.682154952849443e12], [2.3083371921991926e8, -6.429781337697645e12], [2.3086028407767978e8, -6.432013844640516e12], [2.2713344799647152e8, -6.290590568649086e12], [2.213785902919938e8, -6.072190577668113e12], [2.1839816275311476e8, -5.958006148076064e12]], [[2.1839816275311476e8, -5.958006148076064e12], [2.1317815101427838e8, -5.755442157164383e12], [2.107544614432726e8, -5.663099117932252e12], [2.0363086714606974e8, -5.385313115646984e12], [2.0367119740017354e8, -5.389680493231892e12], [1.9978222312415692e8, -5.234953667992473e12], [1.9384484296995518e8, -5.003080114876476e12], [1.9078946680973372e8, -4.883257113256235e12]]  …  [[30.77130824258604, -0.11860394173061783], [29.959935495288498, -0.11140797935313063], [29.58387280378597, -0.10832686127873781], [28.48405239773447, -0.09928726916088992], [28.48980788191048, -0.09953769556549211], [27.89233756602983, -0.09465206403950747], [26.982695369276243, -0.08784534733068528], [26.51613295807781, -0.08444844983340616]], [[26.51613295807781, -0.08444844983340616], [25.800244567668717, -0.0793437770931746], [25.46837113091203, -0.07715739379243877], [24.49808914082673, -0.07074474949610282], [24.503078768658227, -0.07092033247353718], [23.976080189941577, -0.06745623124240567], [23.173557371693533, -0.06262624453570909], [22.76191993875521, -0.060216001105611296]], [[22.76191993875521, -0.060216001105611296], [22.128972332737575, -0.05658634124504633], [21.83540173608769, -0.055031133565847774], [20.977272807417243, -0.050471645108792054], [20.98157264423659, -0.05059453682447829], [20.515478137872613, -0.04813327651603161], [19.80527866050254, -0.04469820877964033], [19.44087953687074, -0.042984302089013215]], [[19.44087953687074, -0.042984302089013215], [18.879175153075106, -0.04039755182650475], [18.61839882676841, -0.03928869155478835], [17.856095873890496, -0.03603958650586973], [17.859774978122722, -0.03612533048820085], [17.44555489817186, -0.03437312328903092], [16.8136337670386, -0.03192456778705127], [16.48913597481707, -0.030703126375547386]], [[16.48913597481707, -0.030703126375547386], [15.987372575608578, -0.02885516049433386], [15.754032697566045, -0.02806251718303446], [15.071569255652193, -0.02574150168336388], [15.074690623388719, -0.025801030530739864], [14.703421117683277, -0.024550845344149242], [14.135744980577314, -0.022800761990946793], [13.843740597793335, -0.021927896798266483]], [[13.843740597793335, -0.021927896798266483], [13.390283227433452, -0.020603475174607176], [13.178794505801399, -0.020034873462556387], [12.559292860315507, -0.018370904014162387], [12.561913982568855, -0.018411924309927656], [12.224006523623116, -0.017516802351725272], [11.705183549724815, -0.01626026317292575], [11.437387063164012, -0.01563340622315477]], [[11.437387063164012, -0.01563340622315477], [11.01878150792764, -0.014678336197953723], [10.82253680103821, -0.014267564488197654], [10.245554614263034, -0.013065332972118784], [10.247728131844918, -0.013093295345867853], [9.931188517898754, -0.012446898304422055], [9.441243863984521, -0.011534435582156359], [9.186519659630589, -0.011078238338239042]], [[9.186519659630589, -0.011078238338239042], [8.783566141333234, -0.010377508916696608], [8.592773339555121, -0.010074628673640663], [8.026713159861465, -0.009184816254201401], [8.02849097003657, -0.009203619874873954], [7.713708988673121, -0.008723062083665283], [7.217886795021174, -0.008034043594872396], [6.955656064380171, -0.007685578728404354]], [[6.955656064380171, -0.007685578728404354], [6.5273109079091185, -0.007134646380183254], [6.319820953882714, -0.00689180543252196], [5.687589521348274, -0.006160868366436858], [5.689079491765033, -0.00617364217111904], [5.323062677762132, -0.0057642040642810815], [4.715582270359798, -0.005135236105887344], [4.3747513071274, -0.004792939751623829]], [[4.3747513071274, -0.004792939751623829], [4.166922925734744, -0.004586391879474687], [4.061432653558884, -0.0044838182276782535], [3.7325651053043574, -0.0041622082759375355], [3.732635555251449, -0.00416269816983687], [3.5355500768916843, -0.003970041139916266], [3.196751224512554, -0.0036386269738103417], [3.0020840817735213, -0.0034466511849334633]]], true, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}([2084.514579060352, 0.08474595786232589], [2081.7591324697382, 0.08782033810017538], [4.3747513071274, -0.004792939751623829], [4.166922925734744, -0.004586391879474687], [4.061432653558884, -0.0044838182276782535], [3.7325651053043574, -0.0041622082759375355], [3.732635555251449, -0.00416269816983687], [3.5355500768916843, -0.003970041139916266], [3.196751224512554, -0.0036386269738103417], [3.0020840817735213, -0.0034466511849334633], [0.0002918886758046514, -3.8026854838486575e-7], [2084.227288553582, 0.0850744891323977], [0.0001400271020935366, -0.004281322910029712], OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}(0.16666666666666666, 0.0625, 0.1875, 0.25, -0.75, -0.75, 3.75, -3.0, 0.5, 0.26895043731778423, -0.7084548104956269, 0.8658892128279884, 0.15462307371928363, 0.06184922948771345, -0.02947695035460993, 0.18500664893617022, 0.4802345261121857, -0.5337849069148937, -0.013090093085106383, 0.7861107753062541, 0.08783068783068783, 0.3006060606060606, 0.22777777777777777, 0.027777777777777776, 0.06218596218596219, 0.2938217338217338, 0.16666666666666666, 0.25, 0.5, 0.5, 0.6428571428571429, 0.875, -0.19894179894179895, 0.9115151515151515, -1.9777777777777779, -0.1111111111111111, 1.67013727013727, -0.2938217338217338, 1.892063492063492, -6.067155067155067, 7.282458282458283, -4.0195360195360195, -7.214545454545455, 20.676923076923078, -20.31142191142191, 7.14965034965035, 7.866666666666666, -18.78205128205128, 13.508547008547009, -2.3653846153846154, 2.0, -5.294871794871795, 4.534188034188034, -1.2115384615384615, -1.4924630924630924, 1.5785667324128863, 1.1958838881915805, -1.219801565955412, -7.051721611721612, 16.273203719357564, -11.978886071193763, 3.0512256973795435, 4.0, -8.384615384615385, 5.769230769230769, -1.3846153846153846))), true, 0, DiffEqBase.DEStats
Number of function 1 evaluations:                  1270
Number of function 2 evaluations:                  0
Number of W matrix evaluations:                    0
Number of linear solves:                           0
Number of Jacobians created:                       0
Number of nonlinear solver iterations:             0
Number of nonlinear solver convergence failures:   0
Number of rootfind condition calls:                0
Number of accepted steps:                          129
Number of rejected steps:                          52, :Success), SciMLBase.ODESolution{Float64, 2, Vector{Vector{Float64}}, Nothing, Nothing, Vector{Float64}, Vector{Vector{Vector{Float64}}}, SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}, OwrenZen5, OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}, DiffEqBase.DEStats}([[0.0, 0.0], [39.20413519851618, 5.083069919161066e6], [52.16962487312537, 6.764129585437992e6], [59.38992783597706, 7.7002886033623535e6], [59.95140480822078, 7.773087727372242e6], [60.21530872403701, 7.7592556250414895e6], [60.32940843271148, 7.751273457312373e6], [61.461307866459315, 7.672230157916223e6], [67.08001315826495, 7.284347772060995e6], [75.98752956664626, 6.689045662846668e6]  …  [2014.725458899351, 0.235417096160731], [2026.1757000793782, 0.2053636851388537], [2037.864395079801, 0.17960653077269012], [2049.7519643566266, 0.15747489417922195], [2061.7690608944586, 0.13841560813613907], [2073.7948609758587, 0.1219757471534179], [2085.613270134666, 0.10779902580116515], [2096.8125522527052, 0.095656900069775], [2106.4980220259276, 0.08561881915196241], [2109.0604852940355, 0.08287441784301582]], nothing, nothing, [0.0, 6.443422561125131e-8, 8.574374523535688e-8, 9.761072377974756e-8, 9.853354311556449e-8, 9.896777274301707e-8, 9.915595908683831e-8, 1.0103782252505072e-7, 1.1079431489655656e-7, 1.2777059469110027e-7  …  2.786113903959678, 3.246921178625437, 3.797694721296355, 4.45738835166793, 5.249393581975161, 6.202838963071345, 7.354570342388651, 8.75314311337818, 10.47922075002294, 11.18], [[[0.0, 0.0]], [[6.084365083877919e8, 7.888773217496178e13], [6.08436508113276e8, 7.888773210377628e13], [6.084365079760114e8, 7.888773206818177e13], [6.084365075642439e8, 7.888773196140512e13], [6.084365075642439e8, 7.888773196140512e13], [6.084365073289444e8, 7.888773190038894e13], [6.08436506946583e8, 7.888773180123766e13], [6.084365067406893e8, 7.888773174784673e13]], [[6.084365067406893e8, 7.888773174784673e13], [6.084365066499088e8, 7.888773172430619e13], [6.08436506604515e8, 7.8887731712535e13], [6.084365064683342e8, 7.888773167722156e13], [6.084365064683342e8, 7.888773167722156e13], [6.084365063905168e8, 7.888773165704248e13], [6.08436506264063e8, 7.888773162425139e13], [6.084365061959726e8, 7.888773160659466e13]], [[6.084365061959726e8, 7.888773160659466e13], [6.084365061454079e8, 7.888773159348258e13], [6.084365061201353e8, 7.888773158692908e13], [6.084365060442915e8, 7.888773156726178e13], [6.084365060442915e8, 7.888773156726178e13], [6.084365060009626e8, 7.888773155602605e13], [6.084365059305423e8, 7.888773153776516e13], [6.084365058926235e8, 7.888773152793233e13]], [[6.084365058926235e8, 7.888773152793233e13], [6.084365058886923e8, 7.888773152691288e13], [6.084365058867263e8, 7.888773152640308e13], [6.084365058808289e8, 7.88877315248738e13], [6.084365058808289e8, 7.88877315248738e13], [6.084365058774589e8, 7.888773152399995e13], [6.084365058719828e8, 7.88877315225799e13], [6.084365058690342e8, 7.888773152181528e13]], [[6.084365058690342e8, 7.888773152181528e13], [6.084365058671842e8, 7.888773152133558e13], [6.083001419938538e8, -4.271876228911408e13], [6.077848923924593e8, -4.205646667754441e13], [6.077841480257921e8, -4.4943532764422375e13], [6.074908221167163e8, -4.208114955506997e13], [6.070132558603408e8, -4.253183549340822e13], [6.067567008590299e8, -4.245410769626267e13]], [[6.067567008590299e8, -4.245410769626267e13], [6.066084621389997e8, -4.244149714301311e13], [6.065343977900921e8, -4.243519616776061e13], [6.063122616958413e8, -4.241629165893908e13], [6.063122618153096e8, -4.241629167991672e13], [6.061854017088019e8, -4.2405492243438266e13], [6.059793703354111e8, -4.238794810236442e13], [6.058684898324304e8, -4.237850377217961e13]], [[6.058684898324304e8, -4.237850377217961e13], [6.043922544454877e8, -4.225254007622028e13], [6.036595914055448e8, -4.218999036358694e13], [6.014671198320237e8, -4.2002187961540125e13], [6.014672382295414e8, -4.2002208921101984e13], [6.002216114492416e8, -4.189520042228355e13], [5.982089266013051e8, -4.172185981327695e13], [5.971308789564788e8, -4.162878331716158e13]], [[5.971308789564788e8, -4.162878331716158e13], [5.897410074296151e8, -4.098500297557019e13], [5.86183742667963e8, -4.067495653514466e13], [5.75636757398756e8, -3.9741403128420984e13], [5.75652071051652e8, -3.974430572659194e13], [5.697846124546565e8, -3.9218024982073266e13], [5.60533703096582e8, -3.838342663749766e13], [5.556766383305717e8, -3.794155067317474e13]], [[5.556766383305717e8, -3.794155067317474e13], [5.44627004756397e8, -3.692313365805294e13], [5.394311293582743e8, -3.644852428803698e13], [5.2411659868315864e8, -3.5019887104297266e13], [5.241757135669312e8, -3.5033764380421617e13], [5.15765818440455e8, -3.4235364274280883e13], [5.027742548887171e8, -3.300895662617317e13], [4.9604426569145614e8, -3.2369465922261188e13]]  …  [[31.279971853051652, -0.10760435560541355], [30.438696824676523, -0.10117794754234932], [30.049456599271632, -0.09842736452780992], [28.911572569535842, -0.09034515750103293], [28.917820994637744, -0.09057496715406797], [28.30016766931603, -0.08619783362171216], [27.361344910565105, -0.08010356689647279], [26.88024821790748, -0.07705886278954666]], [[26.88024821790748, -0.07705886278954666], [26.140755634533246, -0.07246849544158035], [25.79851999311055, -0.07050319617420023], [24.798364636731407, -0.06473027249170209], [24.803752853978306, -0.06489249069211184], [24.260960280386392, -0.06176775665836536], [23.435701862795536, -0.05741389853757602], [23.01277483324257, -0.05523896361102415]], [[23.01277483324257, -0.05523896361102415], [22.36145565789883, -0.051953774584321294], [22.0598528643834, -0.05054679785861888], [21.17861922257815, -0.04641577965760771], [21.183235628686088, -0.04653002787070707], [20.704966094105004, -0.04429578929307854], [19.977321338083105, -0.041179754279198615], [19.604288687911822, -0.0396234883863287]], [[19.604288687911822, -0.0396234883863287], [19.028490130799124, -0.03726814960683682], [18.761577888568564, -0.036258999475397], [17.9816680516025, -0.03329780573587837], [17.985593580758255, -0.03337797539652358], [17.56212910959831, -0.03177812766212251], [16.91702309024182, -0.02954411429626302], [16.586022830848613, -0.028428675512454187]], [[16.586022830848613, -0.028428675512454187], [16.073590515619998, -0.0267368135281758], [15.835624402893782, -0.026011543845770275], [15.13991667798966, -0.023884860873557283], [15.143225443695911, -0.02394080727809262], [14.765025568939398, -0.02279333690055976], [14.187500432495193, -0.021188254897808484], [13.890651612259257, -0.02038704213557146]], [[13.890651612259257, -0.02038704213557146], [13.429174211220964, -0.019168525968068745], [13.214215126541948, -0.018645732786658813], [12.584785390576421, -0.01711375900578805], [12.587545126208546, -0.017152489416658333], [12.244447081528941, -0.016327058227835006], [11.71823909583612, -0.01516922769517943], [11.446803840934582, -0.014591171622713818]], [[11.446803840934582, -0.014591171622713818], [11.022067854134404, -0.013708545459199582], [10.823155811303476, -0.013329205715019426], [10.238495025865463, -0.0122174651125817], [10.240767639132274, -0.012243978281372372], [9.920172688478136, -0.011645320116260635], [9.424349401806637, -0.010800788034706018], [9.166673696624551, -0.010378213290736817]], [[9.166673696624551, -0.010378213290736817], [8.75853734499503, -0.009727640494336859], [8.565417572801222, -0.009446623532878846], [7.992442926532645, -0.008619689626602079], [7.994289055889147, -0.008637597478275135], [7.6756698339791045, -0.008190179125475986], [7.173858502111052, -0.0075485856529005305], [6.908393171944192, -0.007223602550862444]], [[6.908393171944192, -0.007223602550862444], [6.473389582685617, -0.006707474245715189], [6.262602563672204, -0.006479858039739805], [5.61946584775536, -0.0057921065243411295], [5.621010310017039, -0.005804393529819846], [5.247894672534584, -0.005417119613662013], [4.626752458367954, -0.004818535972080755], [4.276766216544123, -0.00448987110081555]], [[4.276766216544123, -0.00448987110081555], [4.080376929724552, -0.004306795635516525], [3.980634060121082, -0.004215511250021924], [3.6698977107746797, -0.003928923830593871], [3.6699541904503756, -0.003929296109678315], [3.4839117837453246, -0.0037573002532797083], [3.164648388500825, -0.0034610681046587342], [2.981700041819988, -0.003289594540297232]]], SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [0.0, 0.0], (0.0, 11.18), Any[GasChromatographySimulator.Column(11.18, 0.000104, [0.000104], 1.04e-7, [1.04e-7], "FS5ms", "H2"), GasChromatographySimulator.Program{GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}}([0.0, 60.0, 1680.0, 60.0, 360.0, 60.0], [40.0, 40.0, 180.0, 180.0, 300.0, 300.0], [411564.0, 411564.0, 411564.0, 411564.0, 411564.0, 411564.0], [101300.0, 101300.0, 101300.0, 101300.0, 101300.0, 101300.0], GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}([0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0]), [0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0], 11181×6 extrapolate(interpolate((0.0:0.001:11.18,::Vector{Float64}), ::Matrix{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
   ⋮                                       ⋮
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0), GasChromatographySimulator.Substance("C28", "630-2-4", 607.3399999999999, 41.82, 183.91, 0.001, "Leppert2020b, alkane", 6.915867131183108e-5, 0.0, 0.0), GasChromatographySimulator.Options(OwrenZen5(), 1.0e-6, 0.001, "inlet", true, true, "Blumberg", "Pressure")], Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}(), SciMLBase.StandardODEProblem()), OwrenZen5(), OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [[0.0, 0.0], [39.20413519851618, 5.083069919161066e6], [52.16962487312537, 6.764129585437992e6], [59.38992783597706, 7.7002886033623535e6], [59.95140480822078, 7.773087727372242e6], [60.21530872403701, 7.7592556250414895e6], [60.32940843271148, 7.751273457312373e6], [61.461307866459315, 7.672230157916223e6], [67.08001315826495, 7.284347772060995e6], [75.98752956664626, 6.689045662846668e6]  …  [2014.725458899351, 0.235417096160731], [2026.1757000793782, 0.2053636851388537], [2037.864395079801, 0.17960653077269012], [2049.7519643566266, 0.15747489417922195], [2061.7690608944586, 0.13841560813613907], [2073.7948609758587, 0.1219757471534179], [2085.613270134666, 0.10779902580116515], [2096.8125522527052, 0.095656900069775], [2106.4980220259276, 0.08561881915196241], [2109.0604852940355, 0.08287441784301582]], [0.0, 6.443422561125131e-8, 8.574374523535688e-8, 9.761072377974756e-8, 9.853354311556449e-8, 9.896777274301707e-8, 9.915595908683831e-8, 1.0103782252505072e-7, 1.1079431489655656e-7, 1.2777059469110027e-7  …  2.786113903959678, 3.246921178625437, 3.797694721296355, 4.45738835166793, 5.249393581975161, 6.202838963071345, 7.354570342388651, 8.75314311337818, 10.47922075002294, 11.18], [[[0.0, 0.0]], [[6.084365083877919e8, 7.888773217496178e13], [6.08436508113276e8, 7.888773210377628e13], [6.084365079760114e8, 7.888773206818177e13], [6.084365075642439e8, 7.888773196140512e13], [6.084365075642439e8, 7.888773196140512e13], [6.084365073289444e8, 7.888773190038894e13], [6.08436506946583e8, 7.888773180123766e13], [6.084365067406893e8, 7.888773174784673e13]], [[6.084365067406893e8, 7.888773174784673e13], [6.084365066499088e8, 7.888773172430619e13], [6.08436506604515e8, 7.8887731712535e13], [6.084365064683342e8, 7.888773167722156e13], [6.084365064683342e8, 7.888773167722156e13], [6.084365063905168e8, 7.888773165704248e13], [6.08436506264063e8, 7.888773162425139e13], [6.084365061959726e8, 7.888773160659466e13]], [[6.084365061959726e8, 7.888773160659466e13], [6.084365061454079e8, 7.888773159348258e13], [6.084365061201353e8, 7.888773158692908e13], [6.084365060442915e8, 7.888773156726178e13], [6.084365060442915e8, 7.888773156726178e13], [6.084365060009626e8, 7.888773155602605e13], [6.084365059305423e8, 7.888773153776516e13], [6.084365058926235e8, 7.888773152793233e13]], [[6.084365058926235e8, 7.888773152793233e13], [6.084365058886923e8, 7.888773152691288e13], [6.084365058867263e8, 7.888773152640308e13], [6.084365058808289e8, 7.88877315248738e13], [6.084365058808289e8, 7.88877315248738e13], [6.084365058774589e8, 7.888773152399995e13], [6.084365058719828e8, 7.88877315225799e13], [6.084365058690342e8, 7.888773152181528e13]], [[6.084365058690342e8, 7.888773152181528e13], [6.084365058671842e8, 7.888773152133558e13], [6.083001419938538e8, -4.271876228911408e13], [6.077848923924593e8, -4.205646667754441e13], [6.077841480257921e8, -4.4943532764422375e13], [6.074908221167163e8, -4.208114955506997e13], [6.070132558603408e8, -4.253183549340822e13], [6.067567008590299e8, -4.245410769626267e13]], [[6.067567008590299e8, -4.245410769626267e13], [6.066084621389997e8, -4.244149714301311e13], [6.065343977900921e8, -4.243519616776061e13], [6.063122616958413e8, -4.241629165893908e13], [6.063122618153096e8, -4.241629167991672e13], [6.061854017088019e8, -4.2405492243438266e13], [6.059793703354111e8, -4.238794810236442e13], [6.058684898324304e8, -4.237850377217961e13]], [[6.058684898324304e8, -4.237850377217961e13], [6.043922544454877e8, -4.225254007622028e13], [6.036595914055448e8, -4.218999036358694e13], [6.014671198320237e8, -4.2002187961540125e13], [6.014672382295414e8, -4.2002208921101984e13], [6.002216114492416e8, -4.189520042228355e13], [5.982089266013051e8, -4.172185981327695e13], [5.971308789564788e8, -4.162878331716158e13]], [[5.971308789564788e8, -4.162878331716158e13], [5.897410074296151e8, -4.098500297557019e13], [5.86183742667963e8, -4.067495653514466e13], [5.75636757398756e8, -3.9741403128420984e13], [5.75652071051652e8, -3.974430572659194e13], [5.697846124546565e8, -3.9218024982073266e13], [5.60533703096582e8, -3.838342663749766e13], [5.556766383305717e8, -3.794155067317474e13]], [[5.556766383305717e8, -3.794155067317474e13], [5.44627004756397e8, -3.692313365805294e13], [5.394311293582743e8, -3.644852428803698e13], [5.2411659868315864e8, -3.5019887104297266e13], [5.241757135669312e8, -3.5033764380421617e13], [5.15765818440455e8, -3.4235364274280883e13], [5.027742548887171e8, -3.300895662617317e13], [4.9604426569145614e8, -3.2369465922261188e13]]  …  [[31.279971853051652, -0.10760435560541355], [30.438696824676523, -0.10117794754234932], [30.049456599271632, -0.09842736452780992], [28.911572569535842, -0.09034515750103293], [28.917820994637744, -0.09057496715406797], [28.30016766931603, -0.08619783362171216], [27.361344910565105, -0.08010356689647279], [26.88024821790748, -0.07705886278954666]], [[26.88024821790748, -0.07705886278954666], [26.140755634533246, -0.07246849544158035], [25.79851999311055, -0.07050319617420023], [24.798364636731407, -0.06473027249170209], [24.803752853978306, -0.06489249069211184], [24.260960280386392, -0.06176775665836536], [23.435701862795536, -0.05741389853757602], [23.01277483324257, -0.05523896361102415]], [[23.01277483324257, -0.05523896361102415], [22.36145565789883, -0.051953774584321294], [22.0598528643834, -0.05054679785861888], [21.17861922257815, -0.04641577965760771], [21.183235628686088, -0.04653002787070707], [20.704966094105004, -0.04429578929307854], [19.977321338083105, -0.041179754279198615], [19.604288687911822, -0.0396234883863287]], [[19.604288687911822, -0.0396234883863287], [19.028490130799124, -0.03726814960683682], [18.761577888568564, -0.036258999475397], [17.9816680516025, -0.03329780573587837], [17.985593580758255, -0.03337797539652358], [17.56212910959831, -0.03177812766212251], [16.91702309024182, -0.02954411429626302], [16.586022830848613, -0.028428675512454187]], [[16.586022830848613, -0.028428675512454187], [16.073590515619998, -0.0267368135281758], [15.835624402893782, -0.026011543845770275], [15.13991667798966, -0.023884860873557283], [15.143225443695911, -0.02394080727809262], [14.765025568939398, -0.02279333690055976], [14.187500432495193, -0.021188254897808484], [13.890651612259257, -0.02038704213557146]], [[13.890651612259257, -0.02038704213557146], [13.429174211220964, -0.019168525968068745], [13.214215126541948, -0.018645732786658813], [12.584785390576421, -0.01711375900578805], [12.587545126208546, -0.017152489416658333], [12.244447081528941, -0.016327058227835006], [11.71823909583612, -0.01516922769517943], [11.446803840934582, -0.014591171622713818]], [[11.446803840934582, -0.014591171622713818], [11.022067854134404, -0.013708545459199582], [10.823155811303476, -0.013329205715019426], [10.238495025865463, -0.0122174651125817], [10.240767639132274, -0.012243978281372372], [9.920172688478136, -0.011645320116260635], [9.424349401806637, -0.010800788034706018], [9.166673696624551, -0.010378213290736817]], [[9.166673696624551, -0.010378213290736817], [8.75853734499503, -0.009727640494336859], [8.565417572801222, -0.009446623532878846], [7.992442926532645, -0.008619689626602079], [7.994289055889147, -0.008637597478275135], [7.6756698339791045, -0.008190179125475986], [7.173858502111052, -0.0075485856529005305], [6.908393171944192, -0.007223602550862444]], [[6.908393171944192, -0.007223602550862444], [6.473389582685617, -0.006707474245715189], [6.262602563672204, -0.006479858039739805], [5.61946584775536, -0.0057921065243411295], [5.621010310017039, -0.005804393529819846], [5.247894672534584, -0.005417119613662013], [4.626752458367954, -0.004818535972080755], [4.276766216544123, -0.00448987110081555]], [[4.276766216544123, -0.00448987110081555], [4.080376929724552, -0.004306795635516525], [3.980634060121082, -0.004215511250021924], [3.6698977107746797, -0.003928923830593871], [3.6699541904503756, -0.003929296109678315], [3.4839117837453246, -0.0037573002532797083], [3.164648388500825, -0.0034610681046587342], [2.981700041819988, -0.003289594540297232]]], true, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}([2109.0604852940355, 0.08287441784301582], [2106.4980220259276, 0.08561881915196241], [4.276766216544123, -0.00448987110081555], [4.080376929724552, -0.004306795635516525], [3.980634060121082, -0.004215511250021924], [3.6698977107746797, -0.003928923830593871], [3.6699541904503756, -0.003929296109678315], [3.4839117837453246, -0.0037573002532797083], [3.164648388500825, -0.0034610681046587342], [2.981700041819988, -0.003289594540297232], [0.00023427485324104504, -2.962889877031132e-7], [2108.791135217852, 0.08317037263407433], [0.00011108014388133569, -0.0034206075608501363], OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}(0.16666666666666666, 0.0625, 0.1875, 0.25, -0.75, -0.75, 3.75, -3.0, 0.5, 0.26895043731778423, -0.7084548104956269, 0.8658892128279884, 0.15462307371928363, 0.06184922948771345, -0.02947695035460993, 0.18500664893617022, 0.4802345261121857, -0.5337849069148937, -0.013090093085106383, 0.7861107753062541, 0.08783068783068783, 0.3006060606060606, 0.22777777777777777, 0.027777777777777776, 0.06218596218596219, 0.2938217338217338, 0.16666666666666666, 0.25, 0.5, 0.5, 0.6428571428571429, 0.875, -0.19894179894179895, 0.9115151515151515, -1.9777777777777779, -0.1111111111111111, 1.67013727013727, -0.2938217338217338, 1.892063492063492, -6.067155067155067, 7.282458282458283, -4.0195360195360195, -7.214545454545455, 20.676923076923078, -20.31142191142191, 7.14965034965035, 7.866666666666666, -18.78205128205128, 13.508547008547009, -2.3653846153846154, 2.0, -5.294871794871795, 4.534188034188034, -1.2115384615384615, -1.4924630924630924, 1.5785667324128863, 1.1958838881915805, -1.219801565955412, -7.051721611721612, 16.273203719357564, -11.978886071193763, 3.0512256973795435, 4.0, -8.384615384615385, 5.769230769230769, -1.3846153846153846))), true, 0, DiffEqBase.DEStats
Number of function 1 evaluations:                  1305
Number of function 2 evaluations:                  0
Number of W matrix evaluations:                    0
Number of linear solves:                           0
Number of Jacobians created:                       0
Number of nonlinear solver iterations:             0
Number of nonlinear solver convergence failures:   0
Number of rootfind condition calls:                0
Number of accepted steps:                          135
Number of rejected steps:                          51, :Success), SciMLBase.ODESolution{Float64, 2, Vector{Vector{Float64}}, Nothing, Nothing, Vector{Float64}, Vector{Vector{Vector{Float64}}}, SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}, OwrenZen5, OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}, DiffEqBase.DEStats}([[0.0, 0.0], [58.13031728368686, 1.656211191360359e7], [59.6420957567333, 1.6992838002936915e7], [59.98244110122867, 1.7089806984746497e7], [60.243288308329696, 1.705712421212823e7], [60.35585017824354, 1.7038575189651486e7], [61.47239782722523, 1.6855090786812425e7], [67.26545747916583, 1.5919308746876398e7], [76.49447071967418, 1.4492900597373942e7], [86.76349470056364, 1.3011267092910632e7]  …  [2031.4160159693383, 0.2439267569481333], [2043.005791662981, 0.2130980645738528], [2054.8426059680246, 0.18657992355449246], [2066.8940251586837, 0.1637211605214768], [2079.1033368630856, 0.14397878294428101], [2091.3725426722385, 0.12690115645339034], [2103.529311080163, 0.1121208130714595], [2115.2555137183904, 0.09936855734824983], [2125.9039918703033, 0.08856043296492415], [2132.2412061397063, 0.08206054532704399]], nothing, nothing, [0.0, 4.422169617916659e-8, 4.5371757137250224e-8, 4.563066933897809e-8, 4.582940364326677e-8, 4.591537142236713e-8, 4.67750492133707e-8, 5.144346817780464e-8, 5.965190334035167e-8, 7.002222487468781e-8  …  2.5159693500268645, 2.9475796680712993, 3.4637440829679886, 4.082181550138978, 4.824697746284909, 5.7183340494297425, 6.797038378120862, 8.104556769663882, 9.703424235426914, 11.18], [[[0.0, 0.0]], [[1.314520300220256e9, 3.74524574481993e14], [1.3145202998132145e9, 3.7452457425004975e14], [1.3145202996096942e9, 3.745245741340784e14], [1.3145202989991324e9, 3.7452457378616375e14], [1.3145202989991324e9, 3.7452457378616375e14], [1.3145202986502397e9, 3.745245735873552e14], [1.3145202980832894e9, 3.745245732642917e14], [1.3145202977780082e9, 3.745245730903342e14]], [[1.3145202977780082e9, 3.745245730903342e14], [1.3145202977674224e9, 3.745245730843022e14], [1.3145202977621293e9, 3.745245730812861e14], [1.3145202977462509e9, 3.7452457307223806e14], [1.3145202977462509e9, 3.7452457307223806e14], [1.3145202977371776e9, 3.745245730670679e14], [1.3145202977224329e9, 3.745245730586659e14], [1.3145202977144935e9, 3.745245730541418e14]], [[1.3145202977144935e9, 3.745245730541418e14], [1.3145202977121103e9, 3.745245730527838e14], [1.3145202977109187e9, 3.745245730521048e14], [1.3145202977073438e9, 3.745245730500678e14], [1.3145202977073438e9, 3.745245730500678e14], [1.3145202977053013e9, 3.7452457304890375e14], [1.3145202977019818e9, 3.745245730470123e14], [1.3145202977001944e9, 3.7452457304599375e14]], [[1.3145202977001944e9, 3.7452457304599375e14], [1.314071006401997e9, -2.171270942670215e14], [1.313694951470765e9, -2.1662059329398756e14], [1.3125679839835455e9, -2.1713655959207912e14], [1.3125669426667204e9, -2.130616822573862e14], [1.3119248003549855e9, -2.1707203280369975e14], [1.3108806607531836e9, -2.1562666962444862e14], [1.310319426253952e9, -2.1598098089614406e14]], [[1.310319426253952e9, -2.1598098089614406e14], [1.3099958373137248e9, -2.159096507645227e14], [1.3098341641796677e9, -2.158740153510638e14], [1.3093492702590148e9, -2.1576710841348488e14], [1.309349270525452e9, -2.1576710856108694e14], [1.3090723532136679e9, -2.1570604508661244e14], [1.3086226190061557e9, -2.1560685805727712e14], [1.3083805855455394e9, -2.1555347058517094e14]], [[1.3083805855455394e9, -2.1555347058517094e14], [1.3051582570740726e9, -2.148417200719383e14], [1.303559122995885e9, -2.14488808258581e14], [1.298773873229636e9, -2.134299809830703e14], [1.2987741372743337e9, -2.13430128069972e14], [1.2960556084224615e9, -2.1282759342058944e14], [1.2916632609327903e9, -2.1185283360318812e14], [1.2893107255050766e9, -2.113300402117178e14]], [[1.2893107255050766e9, -2.113300402117178e14], [1.2724260120193431e9, -2.0755098640761888e14], [1.2643162238883984e9, -2.057476192140288e14], [1.2402855511071842e9, -2.0033199402426144e14], [1.2403247339583316e9, -2.003547951457943e14], [1.2269739332400358e9, -1.9731697554211075e14], [1.205963553004061e9, -1.92539460611031e14], [1.194947028603575e9, -1.900230692510838e14]], [[1.194947028603575e9, -1.900230692510838e14], [1.1696509566215785e9, -1.841880081979853e14], [1.1578035646352782e9, -1.8150488262069456e14], [1.1229150675409477e9, -1.734483048672564e14], [1.1230684331982899e9, -1.735500354635428e14], [1.1039463013264518e9, -1.6906634363550122e14], [1.0745142764137151e9, -1.6227552028143662e14], [1.0593001131263226e9, -1.5875595392463338e14]], [[1.0593001131263226e9, -1.5875595392463338e14], [1.0343681102159499e9, -1.529511453508834e14], [1.0227779855712384e9, -1.5033069162698828e14], [9.887022795117882e8, -1.4247752883287475e14], [9.888890867615842e8, -1.426154418474664e14], [9.70275519451986e8, -1.382601417490001e14], [9.418247833075871e8, -1.318007282801289e14], [9.271746148068929e8, -1.28478165438518e14]]  …  [[33.84182906977226, -0.11725408653834064], [32.92480507527683, -0.11032038839043752], [32.501126313092584, -0.10735381727927713], [31.262763701771963, -0.09862553283311755], [31.26986961671606, -0.0988797934093655], [30.598007274186816, -0.09414426118312691], [29.578165910094434, -0.08755636855650833], [29.055902884181567, -0.08426215204853403]], [[29.055902884181567, -0.08426215204853403], [28.2528803558647, -0.07928849261659691], [27.881789610543656, -0.07716000272734663], [26.797506538149406, -0.07089945041457889], [26.803618204699774, -0.07107987379892712], [26.21548445867367, -0.06768505743661568], [25.32254822686208, -0.06295911466617268], [24.86527094489386, -0.060596277824597145]], [[24.86527094489386, -0.060596277824597145], [24.161021436285285, -0.057023015173429475], [23.83541140399843, -0.05549340168142328], [22.88426168530474, -0.05099631980751197], [22.889485317602524, -0.05112406208516391], [22.373594241621834, -0.04868738451575261], [21.589906807476535, -0.04529242051743231], [21.188479993807075, -0.0435954324752128]], [[21.188479993807075, -0.0435954324752128], [20.569033807296623, -0.041024727358645686], [20.282371431548054, -0.03992391580000419], [19.44505519450186, -0.036689425168928876], [19.449487961953015, -0.03677955302628418], [18.9952213545422, -0.03502881208327729], [18.304399272047593, -0.03258692521803504], [17.950314352615628, -0.031366731349866575]], [[17.950314352615628, -0.031366731349866575], [17.402551319743672, -0.029514827364288666], [17.148673079839337, -0.028721480809960967], [16.406896704772127, -0.026392101900126013], [16.41062737553361, -0.026455365424807736], [16.007854374805564, -0.025196197682521713], [15.39414439930572, -0.0234373831909453], [15.079158479682718, -0.022558830129379124]], [[15.079158479682718, -0.022558830129379124], [14.590190969667498, -0.021222442475425003], [14.362986232721948, -0.020649583949288716], [13.698445063802561, -0.018968883579162488], [13.701554474859181, -0.01901296676071643], [13.340005980504456, -0.018105827249285385], [12.787190597660231, -0.01683592563730383], [12.502691811153756, -0.016201696628230785]], [[12.502691811153756, -0.016201696628230785], [12.05872263834656, -0.015233943160719217], [11.851530863606815, -0.014818618131875292], [11.24391018664567, -0.013600598993315394], [11.24647164216613, -0.013631006485595273], [10.914461841912402, -0.01297441133844889], [10.403533175374875, -0.012051488256548868], [10.139141738191382, -0.011590122146801567]], [[10.139141738191382, -0.011590122146801567], [9.722769610869248, -0.010882121953939181], [9.526915495345245, -0.010577347471601968], [8.948843839298124, -0.009682048772760656], [8.950924942513193, -0.009702749150844068], [8.63196677892979, -0.009219466848670617], [8.134663090491973, -0.008533205140411004], [7.874155251769764, -0.008188042172474755]], [[7.874155251769764, -0.008188042172474755], [7.4553710572742, -0.007649567184376324], [7.255108451287367, -0.007415178823263265], [6.65377940141269, -0.006718040134113153], [6.655463318205859, -0.006732033927522974], [6.315045614216252, -0.006349170491677573], [5.766512601105983, -0.005784470179626923], [5.469065385172277, -0.005490123198537752]], [[5.469065385172277, -0.005490123198537752], [5.096135969818015, -0.005128934270496601], [4.909529170237502, -0.004958815629319687], [4.324390510852745, -0.004423768218253702], [4.325042594086205, -0.004428129483795359], [3.9709040710805223, -0.004106972290325313], [3.3475086820919877, -0.0035501584704937493], [2.972716096968475, -0.003210094932516971]]], SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [0.0, 0.0], (0.0, 11.18), Any[GasChromatographySimulator.Column(11.18, 0.000104, [0.000104], 1.04e-7, [1.04e-7], "FS5ms", "H2"), GasChromatographySimulator.Program{GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}}([0.0, 60.0, 1680.0, 60.0, 360.0, 60.0], [40.0, 40.0, 180.0, 180.0, 300.0, 300.0], [411564.0, 411564.0, 411564.0, 411564.0, 411564.0, 411564.0], [101300.0, 101300.0, 101300.0, 101300.0, 101300.0, 101300.0], GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}([0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0]), [0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0], 11181×6 extrapolate(interpolate((0.0:0.001:11.18,::Vector{Float64}), ::Matrix{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
   ⋮                                       ⋮
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0), GasChromatographySimulator.Substance("C29", "630-3-5", 614.55, 41.67, 183.07, 0.001, "Leppert2020b, alkane", 6.784748059430345e-5, 0.0, 0.0), GasChromatographySimulator.Options(OwrenZen5(), 1.0e-6, 0.001, "inlet", true, true, "Blumberg", "Pressure")], Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}(), SciMLBase.StandardODEProblem()), OwrenZen5(), OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [[0.0, 0.0], [58.13031728368686, 1.656211191360359e7], [59.6420957567333, 1.6992838002936915e7], [59.98244110122867, 1.7089806984746497e7], [60.243288308329696, 1.705712421212823e7], [60.35585017824354, 1.7038575189651486e7], [61.47239782722523, 1.6855090786812425e7], [67.26545747916583, 1.5919308746876398e7], [76.49447071967418, 1.4492900597373942e7], [86.76349470056364, 1.3011267092910632e7]  …  [2031.4160159693383, 0.2439267569481333], [2043.005791662981, 0.2130980645738528], [2054.8426059680246, 0.18657992355449246], [2066.8940251586837, 0.1637211605214768], [2079.1033368630856, 0.14397878294428101], [2091.3725426722385, 0.12690115645339034], [2103.529311080163, 0.1121208130714595], [2115.2555137183904, 0.09936855734824983], [2125.9039918703033, 0.08856043296492415], [2132.2412061397063, 0.08206054532704399]], [0.0, 4.422169617916659e-8, 4.5371757137250224e-8, 4.563066933897809e-8, 4.582940364326677e-8, 4.591537142236713e-8, 4.67750492133707e-8, 5.144346817780464e-8, 5.965190334035167e-8, 7.002222487468781e-8  …  2.5159693500268645, 2.9475796680712993, 3.4637440829679886, 4.082181550138978, 4.824697746284909, 5.7183340494297425, 6.797038378120862, 8.104556769663882, 9.703424235426914, 11.18], [[[0.0, 0.0]], [[1.314520300220256e9, 3.74524574481993e14], [1.3145202998132145e9, 3.7452457425004975e14], [1.3145202996096942e9, 3.745245741340784e14], [1.3145202989991324e9, 3.7452457378616375e14], [1.3145202989991324e9, 3.7452457378616375e14], [1.3145202986502397e9, 3.745245735873552e14], [1.3145202980832894e9, 3.745245732642917e14], [1.3145202977780082e9, 3.745245730903342e14]], [[1.3145202977780082e9, 3.745245730903342e14], [1.3145202977674224e9, 3.745245730843022e14], [1.3145202977621293e9, 3.745245730812861e14], [1.3145202977462509e9, 3.7452457307223806e14], [1.3145202977462509e9, 3.7452457307223806e14], [1.3145202977371776e9, 3.745245730670679e14], [1.3145202977224329e9, 3.745245730586659e14], [1.3145202977144935e9, 3.745245730541418e14]], [[1.3145202977144935e9, 3.745245730541418e14], [1.3145202977121103e9, 3.745245730527838e14], [1.3145202977109187e9, 3.745245730521048e14], [1.3145202977073438e9, 3.745245730500678e14], [1.3145202977073438e9, 3.745245730500678e14], [1.3145202977053013e9, 3.7452457304890375e14], [1.3145202977019818e9, 3.745245730470123e14], [1.3145202977001944e9, 3.7452457304599375e14]], [[1.3145202977001944e9, 3.7452457304599375e14], [1.314071006401997e9, -2.171270942670215e14], [1.313694951470765e9, -2.1662059329398756e14], [1.3125679839835455e9, -2.1713655959207912e14], [1.3125669426667204e9, -2.130616822573862e14], [1.3119248003549855e9, -2.1707203280369975e14], [1.3108806607531836e9, -2.1562666962444862e14], [1.310319426253952e9, -2.1598098089614406e14]], [[1.310319426253952e9, -2.1598098089614406e14], [1.3099958373137248e9, -2.159096507645227e14], [1.3098341641796677e9, -2.158740153510638e14], [1.3093492702590148e9, -2.1576710841348488e14], [1.309349270525452e9, -2.1576710856108694e14], [1.3090723532136679e9, -2.1570604508661244e14], [1.3086226190061557e9, -2.1560685805727712e14], [1.3083805855455394e9, -2.1555347058517094e14]], [[1.3083805855455394e9, -2.1555347058517094e14], [1.3051582570740726e9, -2.148417200719383e14], [1.303559122995885e9, -2.14488808258581e14], [1.298773873229636e9, -2.134299809830703e14], [1.2987741372743337e9, -2.13430128069972e14], [1.2960556084224615e9, -2.1282759342058944e14], [1.2916632609327903e9, -2.1185283360318812e14], [1.2893107255050766e9, -2.113300402117178e14]], [[1.2893107255050766e9, -2.113300402117178e14], [1.2724260120193431e9, -2.0755098640761888e14], [1.2643162238883984e9, -2.057476192140288e14], [1.2402855511071842e9, -2.0033199402426144e14], [1.2403247339583316e9, -2.003547951457943e14], [1.2269739332400358e9, -1.9731697554211075e14], [1.205963553004061e9, -1.92539460611031e14], [1.194947028603575e9, -1.900230692510838e14]], [[1.194947028603575e9, -1.900230692510838e14], [1.1696509566215785e9, -1.841880081979853e14], [1.1578035646352782e9, -1.8150488262069456e14], [1.1229150675409477e9, -1.734483048672564e14], [1.1230684331982899e9, -1.735500354635428e14], [1.1039463013264518e9, -1.6906634363550122e14], [1.0745142764137151e9, -1.6227552028143662e14], [1.0593001131263226e9, -1.5875595392463338e14]], [[1.0593001131263226e9, -1.5875595392463338e14], [1.0343681102159499e9, -1.529511453508834e14], [1.0227779855712384e9, -1.5033069162698828e14], [9.887022795117882e8, -1.4247752883287475e14], [9.888890867615842e8, -1.426154418474664e14], [9.70275519451986e8, -1.382601417490001e14], [9.418247833075871e8, -1.318007282801289e14], [9.271746148068929e8, -1.28478165438518e14]]  …  [[33.84182906977226, -0.11725408653834064], [32.92480507527683, -0.11032038839043752], [32.501126313092584, -0.10735381727927713], [31.262763701771963, -0.09862553283311755], [31.26986961671606, -0.0988797934093655], [30.598007274186816, -0.09414426118312691], [29.578165910094434, -0.08755636855650833], [29.055902884181567, -0.08426215204853403]], [[29.055902884181567, -0.08426215204853403], [28.2528803558647, -0.07928849261659691], [27.881789610543656, -0.07716000272734663], [26.797506538149406, -0.07089945041457889], [26.803618204699774, -0.07107987379892712], [26.21548445867367, -0.06768505743661568], [25.32254822686208, -0.06295911466617268], [24.86527094489386, -0.060596277824597145]], [[24.86527094489386, -0.060596277824597145], [24.161021436285285, -0.057023015173429475], [23.83541140399843, -0.05549340168142328], [22.88426168530474, -0.05099631980751197], [22.889485317602524, -0.05112406208516391], [22.373594241621834, -0.04868738451575261], [21.589906807476535, -0.04529242051743231], [21.188479993807075, -0.0435954324752128]], [[21.188479993807075, -0.0435954324752128], [20.569033807296623, -0.041024727358645686], [20.282371431548054, -0.03992391580000419], [19.44505519450186, -0.036689425168928876], [19.449487961953015, -0.03677955302628418], [18.9952213545422, -0.03502881208327729], [18.304399272047593, -0.03258692521803504], [17.950314352615628, -0.031366731349866575]], [[17.950314352615628, -0.031366731349866575], [17.402551319743672, -0.029514827364288666], [17.148673079839337, -0.028721480809960967], [16.406896704772127, -0.026392101900126013], [16.41062737553361, -0.026455365424807736], [16.007854374805564, -0.025196197682521713], [15.39414439930572, -0.0234373831909453], [15.079158479682718, -0.022558830129379124]], [[15.079158479682718, -0.022558830129379124], [14.590190969667498, -0.021222442475425003], [14.362986232721948, -0.020649583949288716], [13.698445063802561, -0.018968883579162488], [13.701554474859181, -0.01901296676071643], [13.340005980504456, -0.018105827249285385], [12.787190597660231, -0.01683592563730383], [12.502691811153756, -0.016201696628230785]], [[12.502691811153756, -0.016201696628230785], [12.05872263834656, -0.015233943160719217], [11.851530863606815, -0.014818618131875292], [11.24391018664567, -0.013600598993315394], [11.24647164216613, -0.013631006485595273], [10.914461841912402, -0.01297441133844889], [10.403533175374875, -0.012051488256548868], [10.139141738191382, -0.011590122146801567]], [[10.139141738191382, -0.011590122146801567], [9.722769610869248, -0.010882121953939181], [9.526915495345245, -0.010577347471601968], [8.948843839298124, -0.009682048772760656], [8.950924942513193, -0.009702749150844068], [8.63196677892979, -0.009219466848670617], [8.134663090491973, -0.008533205140411004], [7.874155251769764, -0.008188042172474755]], [[7.874155251769764, -0.008188042172474755], [7.4553710572742, -0.007649567184376324], [7.255108451287367, -0.007415178823263265], [6.65377940141269, -0.006718040134113153], [6.655463318205859, -0.006732033927522974], [6.315045614216252, -0.006349170491677573], [5.766512601105983, -0.005784470179626923], [5.469065385172277, -0.005490123198537752]], [[5.469065385172277, -0.005490123198537752], [5.096135969818015, -0.005128934270496601], [4.909529170237502, -0.004958815629319687], [4.324390510852745, -0.004423768218253702], [4.325042594086205, -0.004428129483795359], [3.9709040710805223, -0.004106972290325313], [3.3475086820919877, -0.0035501584704937493], [2.972716096968475, -0.003210094932516971]]], true, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}([2132.2412061397063, 0.08206054532704399], [2125.9039918703033, 0.08856043296492415], [5.469065385172277, -0.005490123198537752], [5.096135969818015, -0.005128934270496601], [4.909529170237502, -0.004958815629319687], [4.324390510852745, -0.004423768218253702], [4.325042594086205, -0.004428129483795359], [3.9709040710805223, -0.004106972290325313], [3.3475086820919877, -0.0035501584704937493], [2.972716096968475, -0.003210094932516971], [0.0032851691683071266, -3.941723915554166e-6], [2131.6567221386663, 0.08268708831146762], [0.0015407110687742757, -0.04401188990564527], OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}(0.16666666666666666, 0.0625, 0.1875, 0.25, -0.75, -0.75, 3.75, -3.0, 0.5, 0.26895043731778423, -0.7084548104956269, 0.8658892128279884, 0.15462307371928363, 0.06184922948771345, -0.02947695035460993, 0.18500664893617022, 0.4802345261121857, -0.5337849069148937, -0.013090093085106383, 0.7861107753062541, 0.08783068783068783, 0.3006060606060606, 0.22777777777777777, 0.027777777777777776, 0.06218596218596219, 0.2938217338217338, 0.16666666666666666, 0.25, 0.5, 0.5, 0.6428571428571429, 0.875, -0.19894179894179895, 0.9115151515151515, -1.9777777777777779, -0.1111111111111111, 1.67013727013727, -0.2938217338217338, 1.892063492063492, -6.067155067155067, 7.282458282458283, -4.0195360195360195, -7.214545454545455, 20.676923076923078, -20.31142191142191, 7.14965034965035, 7.866666666666666, -18.78205128205128, 13.508547008547009, -2.3653846153846154, 2.0, -5.294871794871795, 4.534188034188034, -1.2115384615384615, -1.4924630924630924, 1.5785667324128863, 1.1958838881915805, -1.219801565955412, -7.051721611721612, 16.273203719357564, -11.978886071193763, 3.0512256973795435, 4.0, -8.384615384615385, 5.769230769230769, -1.3846153846153846))), true, 0, DiffEqBase.DEStats
Number of function 1 evaluations:                  1291
Number of function 2 evaluations:                  0
Number of W matrix evaluations:                    0
Number of linear solves:                           0
Number of Jacobians created:                       0
Number of nonlinear solver iterations:             0
Number of nonlinear solver convergence failures:   0
Number of rootfind condition calls:                0
Number of accepted steps:                          137
Number of rejected steps:                          47, :Success), SciMLBase.ODESolution{Float64, 2, Vector{Vector{Float64}}, Nothing, Nothing, Vector{Float64}, Vector{Vector{Vector{Float64}}}, SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}, OwrenZen5, OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}, DiffEqBase.DEStats}([[0.0, 0.0], [34.20269595878165, 2.160614339472559e7], [62.28848440244334, 3.934818258725053e7], [93.1382819637024, 2.7440883943874996e7], [103.58655257395502, 2.4222310687175818e7], [120.6150805728403, 1.973412751111418e7], [133.06373237677175, 1.6976403566312227e7], [147.2419709649057, 1.4297831015999509e7], [160.18216210683906, 1.2224338998228556e7], [173.5741370246344, 1.039752055365651e7]  …  [2054.8816743470143, 0.23245299453556106], [2066.7604987023255, 0.20356310595019586], [2078.8742246414495, 0.17860768839437596], [2091.1844605584, 0.15701638440217955], [2103.624987196683, 0.1383082533052479], [2116.081433830837, 0.122080266532152], [2128.350844560069, 0.10800610223274533], [2140.0509580856924, 0.09586222499408581], [2150.372168427802, 0.08566019544291648], [2154.3373913260766, 0.08161645769469376]], nothing, nothing, [0.0, 1.1930355918824205e-8, 2.1727053025696095e-8, 3.5464994054642934e-8, 4.15454947089049e-8, 5.342386350257024e-8, 6.392860839979808e-8, 7.813178793216227e-8, 9.353821767514382e-8, 1.123717922379736e-7  …  2.543775552601881, 2.998100019796116, 3.542231941746685, 4.195076623367371, 4.979939718874574, 5.925799745373713, 7.069216132062118, 8.45795003757146, 10.166246469416397, 11.18], [[[0.0, 0.0]], [[2.866863000573773e9, 1.8110225338260242e15], [2.8668630003342786e9, 1.811022533523443e15], [2.866863000214531e9, 1.8110225333721518e15], [2.866862999855289e9, 1.811022532918279e15], [2.866862999855289e9, 1.811022532918279e15], [2.8668629996500072e9, 1.8110225326589228e15], [2.8668629993164253e9, 1.8110225322374692e15], [2.866862999136804e9, 1.8110225320105322e15]], [[2.866862999136804e9, 1.8110225320105322e15], [2.866862998940141e9, 1.811022531762065e15], [2.8668629988418097e9, 1.8110225316378318e15], [2.866862998546816e9, 1.811022531265131e15], [2.866862998546816e9, 1.811022531265131e15], [2.866862998378279e9, 1.811022531052199e15], [2.866862998104324e9, 1.811022530706079e15], [2.7797725826090474e9, -1.246301907071039e15]], [[2.7797725826090474e9, -1.246301907071039e15], [2.551834548904026e9, -1.070817052885434e15], [2.4645969515239916e9, -1.0149266950273625e15], [2.2103134875563207e9, -8.29180159367992e14], [2.230532898380741e9, -8.867728593799065e14], [2.0893787157289627e9, -7.485303586538968e14], [1.9236812982894175e9, -6.539317554995688e14], [1.8421913815957654e9, -6.011949385841866e14]], [[1.8421913815957654e9, -6.011949385841866e14], [1.797365402041088e9, -5.742740107852835e14], [1.7765791208499122e9, -5.624048861778351e14], [1.7154965839900084e9, -5.270513777395431e14], [1.7158555438098996e9, -5.27874039249579e14], [1.6825246765958223e9, -5.084101488401095e14], [1.6316989338296154e9, -4.803306975733894e14], [1.605559806530983e9, -4.660434929786343e14]], [[1.605559806530983e9, -4.660434929786343e14], [1.5400751336980622e9, -4.304300545058329e14], [1.511268638146235e9, -4.1616419966352825e14], [1.427322185709511e9, -3.731808556323356e14], [1.4287896901657114e9, -3.763132442266278e14], [1.3836516621843262e9, -3.5183003342361775e14], [1.3185413151781132e9, -3.215430463607805e14], [1.2858008314605422e9, -3.0636644662624494e14]], [[1.2858008314605422e9, -3.0636644662624494e14], [1.2488253883779542e9, -2.895281233292185e14], [1.231918517150711e9, -2.823173128830472e14], [1.182370709896744e9, -2.608304249431395e14], [1.1827839497677674e9, -2.6157548144475675e14], [1.1558925265491023e9, -2.497145507378343e14], [1.1154459140212388e9, -2.3327400519301584e14], [1.0947846983282042e9, -2.2497896067849603e14]], [[1.0947846983282042e9, -2.2497896067849603e14], [1.058908664148032e9, -2.1072193670426166e14], [1.042713535751185e9, -2.0476635969953984e14], [9.9535448885748e8, -1.8698245374849434e14], [9.958747000923272e8, -1.878116021272552e14], [9.702737549327372e8, -1.7792597707751503e14], [9.322729703453811e8, -1.6473812689010906e14], [9.129712272264317e8, -1.581166896469451e14]], [[9.129712272264317e8, -1.581166896469451e14], [8.861049782038567e8, -1.490251544442763e14], [8.738468617022506e8, -1.4515780092046812e14], [8.379370603301126e8, -1.3363893082301912e14], [8.382514385556167e8, -1.3406820882160594e14], [8.187763342351569e8, -1.2770793825379855e14], [7.895478567974007e8, -1.1897553524485394e14], [7.74631953253732e8, -1.1457877962983458e14]], [[7.74631953253732e8, -1.1457877962983458e14], [7.511939072418003e8, -1.0775266290323083e14], [7.405282914339662e8, -1.0486595527429281e14], [7.092983038995924e8, -9.626622116366908e13], [7.095881988773484e8, -9.660926131119578e13], [6.926659177990146e8, -9.185531282937123e13], [6.673372415045927e8, -8.538539488247617e13], [6.544270010667733e8, -8.213231194937975e13]]  …  [[33.09489330283545, -0.10388093824858545], [32.18059904897515, -0.09779808924849721], [31.75872912413786, -0.09519610696848389], [30.52612808105413, -0.08753229436750684], [30.533429602866924, -0.08775928445787635], [29.86512275017146, -0.08359545462513127], [28.851929954350986, -0.07780519739733714], [28.33342393625049, -0.07490767080190465]], [[28.33342393625049, -0.07490767080190465], [27.535323766578628, -0.07052349147436221], [27.166929043826386, -0.06864771512841573], [26.090910653973097, -0.06312507615220588], [26.097145251351662, -0.06328666283057291], [25.51383375708734, -0.06028825530024033], [24.629167906788986, -0.05611573610198941], [24.17639394930312, -0.0540282362026966]], [[24.17639394930312, -0.0540282362026966], [23.47838101215403, -0.05086517156787023], [23.155963834105382, -0.04951150334286042], [22.214439162365053, -0.04552821884504411], [22.219728668557202, -0.045642899695356905], [21.70930992572568, -0.043482293459951235], [20.934608129529703, -0.040473007430891814], [20.53797091561812, -0.03896796678502099]], [[20.53797091561812, -0.03896796678502099], [19.925304694883437, -0.036683938065757836], [19.641986767754023, -0.03570615608488385], [18.81463685941047, -0.03283094445669977], [18.81909194519088, -0.03291198356940642], [18.370391047780966, -0.03135431356134021], [17.688438254647963, -0.029182323096970306], [17.339000566309892, -0.028096488854029173]], [[17.339000566309892, -0.028096488854029173], [16.79783445166648, -0.026445715904983423], [16.54711978040133, -0.025738730794016496], [15.81465176850235, -0.023661510210008035], [15.818372610549973, -0.02371843122129304], [15.420698243508884, -0.02259475783765895], [14.814873142727041, -0.0210254374505195], [14.503930279757041, -0.02024121897686766]], [[14.503930279757041, -0.02024121897686766], [14.020576561366438, -0.01904630452035002], [13.795972704929746, -0.018534210547728695], [13.138896608798255, -0.017030812717883797], [13.141973438570407, -0.017070462078281962], [12.784360709722094, -0.01625852613199562], [12.237302072492502, -0.01512172062705544], [11.955603418378852, -0.014553691597160261]], [[11.955603418378852, -0.014553691597160261], [11.515111672128272, -0.013685237509740137], [11.30937548722517, -0.013312532319144456], [10.7054844067312, -0.01221856471483902], [10.707998186955196, -0.012245874920666618], [10.377582150479757, -0.0116556829073737], [9.868201562062456, -0.010825207891933017], [9.60413701717171, -0.010409601922696663]], [[9.60413701717171, -0.010409601922696663], [9.186715028973449, -0.009769715232892292], [8.989893341332744, -0.009493985691540259], [8.40743829923433, -0.008682250828547854], [8.409464325514207, -0.008700809827647229], [8.086837533472254, -0.00826151721533008], [7.5813175605574825, -0.007634805900061432], [7.315150497287971, -0.007318174786318928]], [[7.315150497287971, -0.007318174786318928], [6.882449600458466, -0.00681857171969883], [6.674117537683221, -0.006599715889076468], [6.043064790819487, -0.005942160453465746], [6.044717668297786, -0.00595483730861575], [5.6826928277564, -0.005588238103687528], [5.089042585385844, -0.005033526913254087], [4.760472484808228, -0.0047358548215137184]], [[4.760472484808228, -0.0047358548215137184], [4.492877290754643, -0.004496221874327768], [4.3574115665532664, -0.0043787173040325455], [3.933164038661604, -0.004007563293656011], [3.933346024138561, -0.0040087130699515425], [3.677360546909661, -0.00378447944591193], [3.2319593150461907, -0.003393641971901756], [2.9711224563374286, -0.003161182343152591]]], SciMLBase.ODEProblem{Vector{Float64}, Tuple{Float64, Float64}, true, Vector{Any}, SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}, SciMLBase.StandardODEProblem}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [0.0, 0.0], (0.0, 11.18), Any[GasChromatographySimulator.Column(11.18, 0.000104, [0.000104], 1.04e-7, [1.04e-7], "FS5ms", "H2"), GasChromatographySimulator.Program{GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}}([0.0, 60.0, 1680.0, 60.0, 360.0, 60.0], [40.0, 40.0, 180.0, 180.0, 300.0, 300.0], [411564.0, 411564.0, 411564.0, 411564.0, 411564.0, 411564.0], [101300.0, 101300.0, 101300.0, 101300.0, 101300.0, 101300.0], GasChromatographySimulator.var"#gf#5"{Matrix{Float64}}([0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0]), [0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0; … ; 0.0 0.0 11.18 0.0; 0.0 0.0 11.18 0.0], 11181×6 extrapolate(interpolate((0.0:0.001:11.18,::Vector{Float64}), ::Matrix{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
   ⋮                                       ⋮
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15
 313.15  313.15  453.15  453.15  573.15  573.15, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0
 411564.0, 6-element extrapolate(interpolate((::Vector{Float64},), ::Vector{Float64}, Gridded(Linear())), Flat()) with element type Float64:
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0
 101300.0), GasChromatographySimulator.Substance("C30", "638-68-6", 621.54, 41.57, 183.28, 0.001, "Leppert2020b, alkane, alkanes", 6.660172475097402e-5, 0.0, 0.0), GasChromatographySimulator.Options(OwrenZen5(), 1.0e-6, 0.001, "inlet", true, true, "Blumberg", "Pressure")], Base.Pairs{Symbol, Union{}, Tuple{}, NamedTuple{(), Tuple{}}}(), SciMLBase.StandardODEProblem()), OwrenZen5(), OrdinaryDiffEq.InterpolationData{SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}, Vector{Vector{Float64}}, Vector{Float64}, Vector{Vector{Vector{Float64}}}, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}}(SciMLBase.ODEFunction{true, typeof(GasChromatographySimulator.odesystem_r!), LinearAlgebra.UniformScaling{Bool}, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, Nothing, typeof(SciMLBase.DEFAULT_OBSERVED), Nothing}(GasChromatographySimulator.odesystem_r!, LinearAlgebra.UniformScaling{Bool}(true), nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, nothing, SciMLBase.DEFAULT_OBSERVED, nothing), [[0.0, 0.0], [34.20269595878165, 2.160614339472559e7], [62.28848440244334, 3.934818258725053e7], [93.1382819637024, 2.7440883943874996e7], [103.58655257395502, 2.4222310687175818e7], [120.6150805728403, 1.973412751111418e7], [133.06373237677175, 1.6976403566312227e7], [147.2419709649057, 1.4297831015999509e7], [160.18216210683906, 1.2224338998228556e7], [173.5741370246344, 1.039752055365651e7]  …  [2054.8816743470143, 0.23245299453556106], [2066.7604987023255, 0.20356310595019586], [2078.8742246414495, 0.17860768839437596], [2091.1844605584, 0.15701638440217955], [2103.624987196683, 0.1383082533052479], [2116.081433830837, 0.122080266532152], [2128.350844560069, 0.10800610223274533], [2140.0509580856924, 0.09586222499408581], [2150.372168427802, 0.08566019544291648], [2154.3373913260766, 0.08161645769469376]], [0.0, 1.1930355918824205e-8, 2.1727053025696095e-8, 3.5464994054642934e-8, 4.15454947089049e-8, 5.342386350257024e-8, 6.392860839979808e-8, 7.813178793216227e-8, 9.353821767514382e-8, 1.123717922379736e-7  …  2.543775552601881, 2.998100019796116, 3.542231941746685, 4.195076623367371, 4.979939718874574, 5.925799745373713, 7.069216132062118, 8.45795003757146, 10.166246469416397, 11.18], [[[0.0, 0.0]], [[2.866863000573773e9, 1.8110225338260242e15], [2.8668630003342786e9, 1.811022533523443e15], [2.866863000214531e9, 1.8110225333721518e15], [2.866862999855289e9, 1.811022532918279e15], [2.866862999855289e9, 1.811022532918279e15], [2.8668629996500072e9, 1.8110225326589228e15], [2.8668629993164253e9, 1.8110225322374692e15], [2.866862999136804e9, 1.8110225320105322e15]], [[2.866862999136804e9, 1.8110225320105322e15], [2.866862998940141e9, 1.811022531762065e15], [2.8668629988418097e9, 1.8110225316378318e15], [2.866862998546816e9, 1.811022531265131e15], [2.866862998546816e9, 1.811022531265131e15], [2.866862998378279e9, 1.811022531052199e15], [2.866862998104324e9, 1.811022530706079e15], [2.7797725826090474e9, -1.246301907071039e15]], [[2.7797725826090474e9, -1.246301907071039e15], [2.551834548904026e9, -1.070817052885434e15], [2.4645969515239916e9, -1.0149266950273625e15], [2.2103134875563207e9, -8.29180159367992e14], [2.230532898380741e9, -8.867728593799065e14], [2.0893787157289627e9, -7.485303586538968e14], [1.9236812982894175e9, -6.539317554995688e14], [1.8421913815957654e9, -6.011949385841866e14]], [[1.8421913815957654e9, -6.011949385841866e14], [1.797365402041088e9, -5.742740107852835e14], [1.7765791208499122e9, -5.624048861778351e14], [1.7154965839900084e9, -5.270513777395431e14], [1.7158555438098996e9, -5.27874039249579e14], [1.6825246765958223e9, -5.084101488401095e14], [1.6316989338296154e9, -4.803306975733894e14], [1.605559806530983e9, -4.660434929786343e14]], [[1.605559806530983e9, -4.660434929786343e14], [1.5400751336980622e9, -4.304300545058329e14], [1.511268638146235e9, -4.1616419966352825e14], [1.427322185709511e9, -3.731808556323356e14], [1.4287896901657114e9, -3.763132442266278e14], [1.3836516621843262e9, -3.5183003342361775e14], [1.3185413151781132e9, -3.215430463607805e14], [1.2858008314605422e9, -3.0636644662624494e14]], [[1.2858008314605422e9, -3.0636644662624494e14], [1.2488253883779542e9, -2.895281233292185e14], [1.231918517150711e9, -2.823173128830472e14], [1.182370709896744e9, -2.608304249431395e14], [1.1827839497677674e9, -2.6157548144475675e14], [1.1558925265491023e9, -2.497145507378343e14], [1.1154459140212388e9, -2.3327400519301584e14], [1.0947846983282042e9, -2.2497896067849603e14]], [[1.0947846983282042e9, -2.2497896067849603e14], [1.058908664148032e9, -2.1072193670426166e14], [1.042713535751185e9, -2.0476635969953984e14], [9.9535448885748e8, -1.8698245374849434e14], [9.958747000923272e8, -1.878116021272552e14], [9.702737549327372e8, -1.7792597707751503e14], [9.322729703453811e8, -1.6473812689010906e14], [9.129712272264317e8, -1.581166896469451e14]], [[9.129712272264317e8, -1.581166896469451e14], [8.861049782038567e8, -1.490251544442763e14], [8.738468617022506e8, -1.4515780092046812e14], [8.379370603301126e8, -1.3363893082301912e14], [8.382514385556167e8, -1.3406820882160594e14], [8.187763342351569e8, -1.2770793825379855e14], [7.895478567974007e8, -1.1897553524485394e14], [7.74631953253732e8, -1.1457877962983458e14]], [[7.74631953253732e8, -1.1457877962983458e14], [7.511939072418003e8, -1.0775266290323083e14], [7.405282914339662e8, -1.0486595527429281e14], [7.092983038995924e8, -9.626622116366908e13], [7.095881988773484e8, -9.660926131119578e13], [6.926659177990146e8, -9.185531282937123e13], [6.673372415045927e8, -8.538539488247617e13], [6.544270010667733e8, -8.213231194937975e13]]  …  [[33.09489330283545, -0.10388093824858545], [32.18059904897515, -0.09779808924849721], [31.75872912413786, -0.09519610696848389], [30.52612808105413, -0.08753229436750684], [30.533429602866924, -0.08775928445787635], [29.86512275017146, -0.08359545462513127], [28.851929954350986, -0.07780519739733714], [28.33342393625049, -0.07490767080190465]], [[28.33342393625049, -0.07490767080190465], [27.535323766578628, -0.07052349147436221], [27.166929043826386, -0.06864771512841573], [26.090910653973097, -0.06312507615220588], [26.097145251351662, -0.06328666283057291], [25.51383375708734, -0.06028825530024033], [24.629167906788986, -0.05611573610198941], [24.17639394930312, -0.0540282362026966]], [[24.17639394930312, -0.0540282362026966], [23.47838101215403, -0.05086517156787023], [23.155963834105382, -0.04951150334286042], [22.214439162365053, -0.04552821884504411], [22.219728668557202, -0.045642899695356905], [21.70930992572568, -0.043482293459951235], [20.934608129529703, -0.040473007430891814], [20.53797091561812, -0.03896796678502099]], [[20.53797091561812, -0.03896796678502099], [19.925304694883437, -0.036683938065757836], [19.641986767754023, -0.03570615608488385], [18.81463685941047, -0.03283094445669977], [18.81909194519088, -0.03291198356940642], [18.370391047780966, -0.03135431356134021], [17.688438254647963, -0.029182323096970306], [17.339000566309892, -0.028096488854029173]], [[17.339000566309892, -0.028096488854029173], [16.79783445166648, -0.026445715904983423], [16.54711978040133, -0.025738730794016496], [15.81465176850235, -0.023661510210008035], [15.818372610549973, -0.02371843122129304], [15.420698243508884, -0.02259475783765895], [14.814873142727041, -0.0210254374505195], [14.503930279757041, -0.02024121897686766]], [[14.503930279757041, -0.02024121897686766], [14.020576561366438, -0.01904630452035002], [13.795972704929746, -0.018534210547728695], [13.138896608798255, -0.017030812717883797], [13.141973438570407, -0.017070462078281962], [12.784360709722094, -0.01625852613199562], [12.237302072492502, -0.01512172062705544], [11.955603418378852, -0.014553691597160261]], [[11.955603418378852, -0.014553691597160261], [11.515111672128272, -0.013685237509740137], [11.30937548722517, -0.013312532319144456], [10.7054844067312, -0.01221856471483902], [10.707998186955196, -0.012245874920666618], [10.377582150479757, -0.0116556829073737], [9.868201562062456, -0.010825207891933017], [9.60413701717171, -0.010409601922696663]], [[9.60413701717171, -0.010409601922696663], [9.186715028973449, -0.009769715232892292], [8.989893341332744, -0.009493985691540259], [8.40743829923433, -0.008682250828547854], [8.409464325514207, -0.008700809827647229], [8.086837533472254, -0.00826151721533008], [7.5813175605574825, -0.007634805900061432], [7.315150497287971, -0.007318174786318928]], [[7.315150497287971, -0.007318174786318928], [6.882449600458466, -0.00681857171969883], [6.674117537683221, -0.006599715889076468], [6.043064790819487, -0.005942160453465746], [6.044717668297786, -0.00595483730861575], [5.6826928277564, -0.005588238103687528], [5.089042585385844, -0.005033526913254087], [4.760472484808228, -0.0047358548215137184]], [[4.760472484808228, -0.0047358548215137184], [4.492877290754643, -0.004496221874327768], [4.3574115665532664, -0.0043787173040325455], [3.933164038661604, -0.004007563293656011], [3.933346024138561, -0.0040087130699515425], [3.677360546909661, -0.00378447944591193], [3.2319593150461907, -0.003393641971901756], [2.9711224563374286, -0.003161182343152591]]], true, OrdinaryDiffEq.OwrenZen5Cache{Vector{Float64}, Vector{Float64}, Vector{Float64}, OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}}([2154.3373913260766, 0.08161645769469376], [2150.372168427802, 0.08566019544291648], [4.760472484808228, -0.0047358548215137184], [4.492877290754643, -0.004496221874327768], [4.3574115665532664, -0.0043787173040325455], [3.933164038661604, -0.004007563293656011], [3.933346024138561, -0.0040087130699515425], [3.677360546909661, -0.00378447944591193], [3.2319593150461907, -0.003393641971901756], [2.9711224563374286, -0.003161182343152591], [0.0009162717533142529, -1.1150306316233684e-6], [2153.9439553612106, 0.08203256717940685], [0.00042531468454695876, -0.012866698787424786], OrdinaryDiffEq.OwrenZen5ConstantCache{Float64, Float64}(0.16666666666666666, 0.0625, 0.1875, 0.25, -0.75, -0.75, 3.75, -3.0, 0.5, 0.26895043731778423, -0.7084548104956269, 0.8658892128279884, 0.15462307371928363, 0.06184922948771345, -0.02947695035460993, 0.18500664893617022, 0.4802345261121857, -0.5337849069148937, -0.013090093085106383, 0.7861107753062541, 0.08783068783068783, 0.3006060606060606, 0.22777777777777777, 0.027777777777777776, 0.06218596218596219, 0.2938217338217338, 0.16666666666666666, 0.25, 0.5, 0.5, 0.6428571428571429, 0.875, -0.19894179894179895, 0.9115151515151515, -1.9777777777777779, -0.1111111111111111, 1.67013727013727, -0.2938217338217338, 1.892063492063492, -6.067155067155067, 7.282458282458283, -4.0195360195360195, -7.214545454545455, 20.676923076923078, -20.31142191142191, 7.14965034965035, 7.866666666666666, -18.78205128205128, 13.508547008547009, -2.3653846153846154, 2.0, -5.294871794871795, 4.534188034188034, -1.2115384615384615, -1.4924630924630924, 1.5785667324128863, 1.1958838881915805, -1.219801565955412, -7.051721611721612, 16.273203719357564, -11.978886071193763, 3.0512256973795435, 4.0, -8.384615384615385, 5.769230769230769, -1.3846153846153846))), true, 0, DiffEqBase.DEStats
Number of function 1 evaluations:                  1200
Number of function 2 evaluations:                  0
Number of W matrix evaluations:                    0
Number of linear solves:                           0
Number of Jacobians created:                       0
Number of nonlinear solver iterations:             0
Number of nonlinear solver convergence failures:   0
Number of rootfind condition calls:                0
Number of accepted steps:                          137
Number of rejected steps:                          34, :Success)])

We know can compare the simulation results with the measured chromatogram. The file Leppert2020b_measured_RT_progD.csv contains the retention times and peak widths (as standard deviations) from the measurement.

measurement_D = DataFrame(CSV.File("../../data/Leppert2020b/Leppert2020b_measured_RT_progD.csv", header=1, silencewarnings=true));
measurement_D[!, 2] = measurement_D[!, 2] .* 60.0; # conversion from min -> s
rename!(measurement_D, [:Name, :tR, :τR]);

The simulated and measured separations can be compared by comparing the peak lists:

compare = GasChromatographySimulator.compare_peaklist(measurement_D, peaklist)

Differences between measured and simulated retention times are in the range of some seconds, while the retention times are in minutes. Most differences are below 1%. The measured peak widths are 10 to 15% higher than the calculated peak widths.

The measured and simulated separation can also be compared by a plot of the chromatograms:

chrom_D = DataFrame(CSV.File("../../data/Leppert2020b/Leppert2020b_measured_Chrom_progD.csv", header=1, silencewarnings=true))
p_chrom, t, chrom = GasChromatographySimulator.plot_chromatogram(peaklist, (0.0, round(chrom_D[end,1];sigdigits=2)); annotation=false, number=true, mirror=true, offset=0.0)
plot!(p_chrom, chrom_D[!,1], chrom_D[!,2].*400.0.+0.1)
ylims!(-1.6,1.6)
xlims!(0.0,round(chrom_D[end,1];sigdigits=2))
p_chrom

The measured chromatogram is plotted in orange, while the simulated chromatogram is plotted in blue and mirrored.

Thermal gradient GC

The following example of a thermal gradient GC is the example medium gradient from [8].

Standard options are used (here the option ng has to be false):

opt_tg = GasChromatographySimulator.Options()

GasChromatographySimulator.Options(OwrenZen5(), 1.0e-6, 0.001, "inlet", true, false, "Blumberg", "Pressure")

And the column is 2.05 m long and has the same diameter, film thickness and stationary phase as in the example before. Here Helium is used as mobile phase.

col_tg = GasChromatographySimulator.Column(2.05, 0.104e-3, 0.104e-6, "FS5ms", "He");

GasChromatographySimulator.Column(2.05, 0.000104, [0.000104], 1.04e-7, [1.04e-7], "FS5ms", "He")

The program is taken from the measured temperatures and pressures during the GC run, stored in the file Leppert2020b_prog_settings_med_gradient_x90.csv.

prog_settings = DataFrame(CSV.File("../../data/Leppert2020b/Leppert2020b_prog_settings_med_gradient_x90.csv", header=1, silencewarnings=true));